Effect of Sr2+ substitution on structural, morphological, electrical and dielectric properties of Ca2MgSi2O7 ceramic

Despite the excellent properties of ceramic materials for electronic devices, this study systematically investigates the significant effects of strontium (Sr2?) substitution on the structural, morphological, electrical, and dielectric behavior of Ca2-xSrxMgSi2O7 (x = 0, 0.2, 0.4, 0.6) ceramics. The...

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Main Authors: Ahmadipour M., Sarafbidabad M., Ali S.M.A., Pang A.L., Mohd Razip Wee M.F., Pal U., Satgunam M.
Other Authors: 55533484700
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Published: Elsevier Ltd 2025
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spelling my.uniten.dspace-361532025-03-03T15:41:27Z Effect of Sr2+ substitution on structural, morphological, electrical and dielectric properties of Ca2MgSi2O7 ceramic Ahmadipour M. Sarafbidabad M. Ali S.M.A. Pang A.L. Mohd Razip Wee M.F. Pal U. Satgunam M. 55533484700 56486136100 57225860186 55937339700 58956706300 8908351700 48561725600 Antennas Crystallinity Dielectric losses Dielectric properties of solids Grain size and shape Sintering Ca2-xsrxmgsi2O7 ceramic Dielectric characteristics Dielectric permittivities Electrical and dielectric properties Electrical resistivity Electronics devices Morphological properties Sr substitutions Structural behaviors Permittivity Despite the excellent properties of ceramic materials for electronic devices, this study systematically investigates the significant effects of strontium (Sr2?) substitution on the structural, morphological, electrical, and dielectric behavior of Ca2-xSrxMgSi2O7 (x = 0, 0.2, 0.4, 0.6) ceramics. The composite was prepared via a solid-state route and characterized using techniques such as FESEM-EDAX, BET, XRD, Hall Effect measurements, and an LCR meter, respectively. The surface morphology of the structure was initiated to be smooth, compact, dense, island-shaped and porous. It is noted that the grain size reduced (from 1.10 ?m to 0.72 ?m) while the surface area enlarged (from 90 m2/g to 122 m2/g) with Sr substitution. XRD study showed that all the ceramics samples, after sintering at 1250 �C for 5 h. Higher amount of Sr, enhanced the crystallinity, as validated by the peak intensification. Correspondingly, the electrical resistivity and dielectric permittivity of Ca2-xSrxMgSi2O7 was decreased with Sr substitution. Particularly, the Ca1.6Sr0.4MgSi2O7 unveiled the lowermost electrical resistivity (76 � cm) and dielectric permittivity (�r = 848) but the uppermost dielectric loss (tan � = 1.06) at 1 kHz. The attained outcomes exhibited the appropriateness of these samples for use in capacitor and antennas design. ? 2024 Elsevier Ltd and Techna Group S.r.l. Final 2025-03-03T07:41:27Z 2025-03-03T07:41:27Z 2024 Article 10.1016/j.ceramint.2024.10.431 2-s2.0-85207962621 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85207962621&doi=10.1016%2fj.ceramint.2024.10.431&partnerID=40&md5=9b57b14d005a26b4116b008712a4f740 https://irepository.uniten.edu.my/handle/123456789/36153 50 24 56131 56134 Elsevier Ltd Scopus
institution Universiti Tenaga Nasional
building UNITEN Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
url_provider http://dspace.uniten.edu.my/
topic Antennas
Crystallinity
Dielectric losses
Dielectric properties of solids
Grain size and shape
Sintering
Ca2-xsrxmgsi2O7 ceramic
Dielectric characteristics
Dielectric permittivities
Electrical and dielectric properties
Electrical resistivity
Electronics devices
Morphological properties
Sr substitutions
Structural behaviors
Permittivity
spellingShingle Antennas
Crystallinity
Dielectric losses
Dielectric properties of solids
Grain size and shape
Sintering
Ca2-xsrxmgsi2O7 ceramic
Dielectric characteristics
Dielectric permittivities
Electrical and dielectric properties
Electrical resistivity
Electronics devices
Morphological properties
Sr substitutions
Structural behaviors
Permittivity
Ahmadipour M.
Sarafbidabad M.
Ali S.M.A.
Pang A.L.
Mohd Razip Wee M.F.
Pal U.
Satgunam M.
Effect of Sr2+ substitution on structural, morphological, electrical and dielectric properties of Ca2MgSi2O7 ceramic
description Despite the excellent properties of ceramic materials for electronic devices, this study systematically investigates the significant effects of strontium (Sr2?) substitution on the structural, morphological, electrical, and dielectric behavior of Ca2-xSrxMgSi2O7 (x = 0, 0.2, 0.4, 0.6) ceramics. The composite was prepared via a solid-state route and characterized using techniques such as FESEM-EDAX, BET, XRD, Hall Effect measurements, and an LCR meter, respectively. The surface morphology of the structure was initiated to be smooth, compact, dense, island-shaped and porous. It is noted that the grain size reduced (from 1.10 ?m to 0.72 ?m) while the surface area enlarged (from 90 m2/g to 122 m2/g) with Sr substitution. XRD study showed that all the ceramics samples, after sintering at 1250 �C for 5 h. Higher amount of Sr, enhanced the crystallinity, as validated by the peak intensification. Correspondingly, the electrical resistivity and dielectric permittivity of Ca2-xSrxMgSi2O7 was decreased with Sr substitution. Particularly, the Ca1.6Sr0.4MgSi2O7 unveiled the lowermost electrical resistivity (76 � cm) and dielectric permittivity (�r = 848) but the uppermost dielectric loss (tan � = 1.06) at 1 kHz. The attained outcomes exhibited the appropriateness of these samples for use in capacitor and antennas design. ? 2024 Elsevier Ltd and Techna Group S.r.l.
author2 55533484700
author_facet 55533484700
Ahmadipour M.
Sarafbidabad M.
Ali S.M.A.
Pang A.L.
Mohd Razip Wee M.F.
Pal U.
Satgunam M.
format Article
author Ahmadipour M.
Sarafbidabad M.
Ali S.M.A.
Pang A.L.
Mohd Razip Wee M.F.
Pal U.
Satgunam M.
author_sort Ahmadipour M.
title Effect of Sr2+ substitution on structural, morphological, electrical and dielectric properties of Ca2MgSi2O7 ceramic
title_short Effect of Sr2+ substitution on structural, morphological, electrical and dielectric properties of Ca2MgSi2O7 ceramic
title_full Effect of Sr2+ substitution on structural, morphological, electrical and dielectric properties of Ca2MgSi2O7 ceramic
title_fullStr Effect of Sr2+ substitution on structural, morphological, electrical and dielectric properties of Ca2MgSi2O7 ceramic
title_full_unstemmed Effect of Sr2+ substitution on structural, morphological, electrical and dielectric properties of Ca2MgSi2O7 ceramic
title_sort effect of sr2+ substitution on structural, morphological, electrical and dielectric properties of ca2mgsi2o7 ceramic
publisher Elsevier Ltd
publishDate 2025
_version_ 1825816014696218624
score 13.244413