An Elucidative Review of the Nanomaterial Effect on the Durability and Calcium-Silicate-Hydrate (C-S-H) Gel Development of Concrete

Concrete as a building material is susceptible to degradation by environmental threats such as thermal diffusion, acid and sulphate infiltration, and chloride penetration. Hence, the inclusion of nanomaterials in concrete has a positive effect in terms of promoting its mechanical strength and durabi...

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Main Authors: Al-saffar F.Y., Wong L.S., Paul S.C.
Other Authors: 58554482100
Format: Review
Published: Multidisciplinary Digital Publishing Institute (MDPI) 2024
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spelling my.uniten.dspace-340682024-10-14T11:17:50Z An Elucidative Review of the Nanomaterial Effect on the Durability and Calcium-Silicate-Hydrate (C-S-H) Gel Development of Concrete Al-saffar F.Y. Wong L.S. Paul S.C. 58554482100 55504782500 58975844300 C-S-H gel concrete durability energy savings nanomaterial Concrete as a building material is susceptible to degradation by environmental threats such as thermal diffusion, acid and sulphate infiltration, and chloride penetration. Hence, the inclusion of nanomaterials in concrete has a positive effect in terms of promoting its mechanical strength and durability performance, as well as resulting in energy savings due to reduced cement consumption in concrete production. This review article discussed the novel advances in research regarding C-S-H gel promotion and concrete durability improvement using nanomaterials. Basically, this review deals with topics relevant to the influence of nanomaterials on concrete�s resistance to heat, acid, sulphate, chlorides, and wear deterioration, as well as the impact on concrete microstructure and chemical bonding. The significance of this review is a critical discussion on the cementation mechanism of nanoparticles in enhancing durability properties owing to their nanofiller effect, pozzolanic reactivity, and nucleation effect. The utilization of nanoparticles enhanced the hydrolysis of cement, leading to a rise in the production of C-S-H gel. Consequently, this improvement in concrete microstructure led to a reduction in the number of capillary pores and pore connectivity, thereby improving the concrete�s water resistance. Microstructural and chemical evidence obtained using SEM and XRD indicated that nanomaterials facilitated the formation of cement gel either by reacting pozzolanically with portlandite to generate more C-S-H gel or by functioning as nucleation sites. Due to an increased rate of C-S-H gel formation, concrete enhanced with nanoparticles exhibited greater durability against heat damage, external attack by acids and sulphates, chloride diffusion, and surface abrasion. The durability improvement following nanomaterial incorporation into concrete can be summarised as enhanced residual mechanical strength, reduced concrete mass loss, reduced diffusion coefficients for thermal and chloride, improved performance against sulphates and acid attack, and increased surface resistance to abrasion. � 2023 by the authors. Final 2024-10-14T03:17:50Z 2024-10-14T03:17:50Z 2023 Review 10.3390/gels9080613 2-s2.0-85169145072 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85169145072&doi=10.3390%2fgels9080613&partnerID=40&md5=0616f86369b4c9544f5fe7c022f51133 https://irepository.uniten.edu.my/handle/123456789/34068 9 8 613 All Open Access Gold Open Access Multidisciplinary Digital Publishing Institute (MDPI) Scopus
institution Universiti Tenaga Nasional
building UNITEN Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
url_provider http://dspace.uniten.edu.my/
topic C-S-H gel
concrete
durability
energy savings
nanomaterial
spellingShingle C-S-H gel
concrete
durability
energy savings
nanomaterial
Al-saffar F.Y.
Wong L.S.
Paul S.C.
An Elucidative Review of the Nanomaterial Effect on the Durability and Calcium-Silicate-Hydrate (C-S-H) Gel Development of Concrete
description Concrete as a building material is susceptible to degradation by environmental threats such as thermal diffusion, acid and sulphate infiltration, and chloride penetration. Hence, the inclusion of nanomaterials in concrete has a positive effect in terms of promoting its mechanical strength and durability performance, as well as resulting in energy savings due to reduced cement consumption in concrete production. This review article discussed the novel advances in research regarding C-S-H gel promotion and concrete durability improvement using nanomaterials. Basically, this review deals with topics relevant to the influence of nanomaterials on concrete�s resistance to heat, acid, sulphate, chlorides, and wear deterioration, as well as the impact on concrete microstructure and chemical bonding. The significance of this review is a critical discussion on the cementation mechanism of nanoparticles in enhancing durability properties owing to their nanofiller effect, pozzolanic reactivity, and nucleation effect. The utilization of nanoparticles enhanced the hydrolysis of cement, leading to a rise in the production of C-S-H gel. Consequently, this improvement in concrete microstructure led to a reduction in the number of capillary pores and pore connectivity, thereby improving the concrete�s water resistance. Microstructural and chemical evidence obtained using SEM and XRD indicated that nanomaterials facilitated the formation of cement gel either by reacting pozzolanically with portlandite to generate more C-S-H gel or by functioning as nucleation sites. Due to an increased rate of C-S-H gel formation, concrete enhanced with nanoparticles exhibited greater durability against heat damage, external attack by acids and sulphates, chloride diffusion, and surface abrasion. The durability improvement following nanomaterial incorporation into concrete can be summarised as enhanced residual mechanical strength, reduced concrete mass loss, reduced diffusion coefficients for thermal and chloride, improved performance against sulphates and acid attack, and increased surface resistance to abrasion. � 2023 by the authors.
author2 58554482100
author_facet 58554482100
Al-saffar F.Y.
Wong L.S.
Paul S.C.
format Review
author Al-saffar F.Y.
Wong L.S.
Paul S.C.
author_sort Al-saffar F.Y.
title An Elucidative Review of the Nanomaterial Effect on the Durability and Calcium-Silicate-Hydrate (C-S-H) Gel Development of Concrete
title_short An Elucidative Review of the Nanomaterial Effect on the Durability and Calcium-Silicate-Hydrate (C-S-H) Gel Development of Concrete
title_full An Elucidative Review of the Nanomaterial Effect on the Durability and Calcium-Silicate-Hydrate (C-S-H) Gel Development of Concrete
title_fullStr An Elucidative Review of the Nanomaterial Effect on the Durability and Calcium-Silicate-Hydrate (C-S-H) Gel Development of Concrete
title_full_unstemmed An Elucidative Review of the Nanomaterial Effect on the Durability and Calcium-Silicate-Hydrate (C-S-H) Gel Development of Concrete
title_sort elucidative review of the nanomaterial effect on the durability and calcium-silicate-hydrate (c-s-h) gel development of concrete
publisher Multidisciplinary Digital Publishing Institute (MDPI)
publishDate 2024
_version_ 1814061039860318208
score 13.211869