Unlocking the potential of metal-organic frameworks-based mixed matrix membranes for hydrogen separation and purification
Membrane-based separation is a promising technology for hydrogen separation and purification due to its low energy consumption. Conventional membranes, such as polymeric membranes, often suffer from permeability-selectivity trade-offs weakening their potential for challenging gas separations. Metal-...
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Korean Society of Industrial Engineering Chemistry
2024
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my.uniten.dspace-338442024-10-14T11:17:20Z Unlocking the potential of metal-organic frameworks-based mixed matrix membranes for hydrogen separation and purification Ahmad N.N.R. Lee Y. Abdul Hamid M.R. Mohd Ghazi T.I. Nasir R. Leo C.P. Koh S.P. Pasupuleti J. Tiong S.K. 54408069300 58560629100 57201981848 36239011900 55669014300 57210845670 22951210700 11340187300 15128307800 Energy Hydrogen separation Membrane technology Metal�organic frameworks Mixed matrix membrane Economic and social effects Energy utilization Fabrication Fillers Gas permeable membranes Organometallics Purification 'current Energy Hydrogen purification Hydrogen separation Membrane fabrication Membrane performance Membrane-based Metalorganic frameworks (MOFs) Mixed-matrix membranes Separation and purification Membrane technology Membrane-based separation is a promising technology for hydrogen separation and purification due to its low energy consumption. Conventional membranes, such as polymeric membranes, often suffer from permeability-selectivity trade-offs weakening their potential for challenging gas separations. Metal-organic frameworks (MOFs) with uniform apertures, high porosities, large internal surface areas, and tunable functionalities make them excellent fillers in mixed matrix membranes (MMMs) fabrication for hydrogen separation. This review evaluates current state-of-the-art MMMs performances, explores the challenges in MMMs fabrication, and discusses current strategies in MOF-based MMMs fabrication and modification aspects to enhance the membrane performance, specifically for H2/CO2, H2/CH4, and H2/N2 separation. Moreover, the hydrogen separation performance of MOF-based MMMs at elevated temperatures and pressure and improvement in antiaging and antiplasticization properties are discussed in detail. The outlook and perspectives for MOF-based MMMs for hydrogen separation are also provided. This review offers insight into the potential of MOFs as porous fillers in MMMs fabrication for hydrogen separation application. � 2023 The Korean Society of Industrial and Engineering Chemistry Final 2024-10-14T03:17:20Z 2024-10-14T03:17:20Z 2023 Review 10.1016/j.jiec.2023.08.020 2-s2.0-85169547384 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85169547384&doi=10.1016%2fj.jiec.2023.08.020&partnerID=40&md5=93b5ec571510fdafb265a43b7995fed0 https://irepository.uniten.edu.my/handle/123456789/33844 128 143 160 Korean Society of Industrial Engineering Chemistry Scopus |
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Energy Hydrogen separation Membrane technology Metal�organic frameworks Mixed matrix membrane Economic and social effects Energy utilization Fabrication Fillers Gas permeable membranes Organometallics Purification 'current Energy Hydrogen purification Hydrogen separation Membrane fabrication Membrane performance Membrane-based Metalorganic frameworks (MOFs) Mixed-matrix membranes Separation and purification Membrane technology |
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Energy Hydrogen separation Membrane technology Metal�organic frameworks Mixed matrix membrane Economic and social effects Energy utilization Fabrication Fillers Gas permeable membranes Organometallics Purification 'current Energy Hydrogen purification Hydrogen separation Membrane fabrication Membrane performance Membrane-based Metalorganic frameworks (MOFs) Mixed-matrix membranes Separation and purification Membrane technology Ahmad N.N.R. Lee Y. Abdul Hamid M.R. Mohd Ghazi T.I. Nasir R. Leo C.P. Koh S.P. Pasupuleti J. Tiong S.K. Unlocking the potential of metal-organic frameworks-based mixed matrix membranes for hydrogen separation and purification |
| description |
Membrane-based separation is a promising technology for hydrogen separation and purification due to its low energy consumption. Conventional membranes, such as polymeric membranes, often suffer from permeability-selectivity trade-offs weakening their potential for challenging gas separations. Metal-organic frameworks (MOFs) with uniform apertures, high porosities, large internal surface areas, and tunable functionalities make them excellent fillers in mixed matrix membranes (MMMs) fabrication for hydrogen separation. This review evaluates current state-of-the-art MMMs performances, explores the challenges in MMMs fabrication, and discusses current strategies in MOF-based MMMs fabrication and modification aspects to enhance the membrane performance, specifically for H2/CO2, H2/CH4, and H2/N2 separation. Moreover, the hydrogen separation performance of MOF-based MMMs at elevated temperatures and pressure and improvement in antiaging and antiplasticization properties are discussed in detail. The outlook and perspectives for MOF-based MMMs for hydrogen separation are also provided. This review offers insight into the potential of MOFs as porous fillers in MMMs fabrication for hydrogen separation application. � 2023 The Korean Society of Industrial and Engineering Chemistry |
| author2 |
54408069300 |
| author_facet |
54408069300 Ahmad N.N.R. Lee Y. Abdul Hamid M.R. Mohd Ghazi T.I. Nasir R. Leo C.P. Koh S.P. Pasupuleti J. Tiong S.K. |
| format |
Review |
| author |
Ahmad N.N.R. Lee Y. Abdul Hamid M.R. Mohd Ghazi T.I. Nasir R. Leo C.P. Koh S.P. Pasupuleti J. Tiong S.K. |
| author_sort |
Ahmad N.N.R. |
| title |
Unlocking the potential of metal-organic frameworks-based mixed matrix membranes for hydrogen separation and purification |
| title_short |
Unlocking the potential of metal-organic frameworks-based mixed matrix membranes for hydrogen separation and purification |
| title_full |
Unlocking the potential of metal-organic frameworks-based mixed matrix membranes for hydrogen separation and purification |
| title_fullStr |
Unlocking the potential of metal-organic frameworks-based mixed matrix membranes for hydrogen separation and purification |
| title_full_unstemmed |
Unlocking the potential of metal-organic frameworks-based mixed matrix membranes for hydrogen separation and purification |
| title_sort |
unlocking the potential of metal-organic frameworks-based mixed matrix membranes for hydrogen separation and purification |
| publisher |
Korean Society of Industrial Engineering Chemistry |
| publishDate |
2024 |
| _version_ |
1814061091143024640 |
| score |
13.222552 |