Preparation and characterization of a solid polymer electrolyte PEO-ENR50 (80/20)-LiCF3SO3
The preparation and characterization of a polymer electrolyte films containing 80 wt % of poly (ethylene oxide) (PEO) and 20 wt % epoxidized natural rubber (ENR50) complexed with LiCF3SO3 has been reported. The ac impedance data showed good conducting properties of the solid polymer electrolyte (SPE...
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my.uniten.dspace-308922023-12-29T15:55:22Z Preparation and characterization of a solid polymer electrolyte PEO-ENR50 (80/20)-LiCF3SO3 Noor S.A.M. Ahmad A. Rahman M.Y.A. Talib I.A. 35386952000 16306307100 55347217400 7801465202 Crystallinity Ionic conductivity PEO/ENR50 Solid polymer electrolyte Conducting polymers Conductive films Differential scanning calorimetry Diffraction Electrolysis Ethylene Film preparation Ionic conductivity Ions Oxide films Polyelectrolytes Polyethylene oxides Polymer films Polymers Proton exchange membrane fuel cells (PEMFC) Rubber films Scanning X ray diffraction X ray diffraction analysis AC-impedance Conducting properties Crystallinity Differential scanning calorimeters Epoxidized natural rubber PEO/ENR50 Polymer electrolyte films Room temperature Semicrystalline Solid polymer electrolyte Solid polymer electrolytes crystallinity electrical conductivity electrolyte film natural rubber polyethylene oxide polymer Ionic conduction in solids The preparation and characterization of a polymer electrolyte films containing 80 wt % of poly (ethylene oxide) (PEO) and 20 wt % epoxidized natural rubber (ENR50) complexed with LiCF3SO3 has been reported. The ac impedance data showed good conducting properties of the solid polymer electrolyte (SPE) films. The greatest room temperature ionic conductivity of 7.5 � 10-5 S cm-1 was obtained at 25 wt % of LiCF 3SO3 salt. This result has been supported by differential scanning calorimeter and X-ray diffraction analysis. Analysis differential scanning calorimetry showed the relative percentage of crystallinity and T m of PEO decreased with the increasing wt % of LiCF 3SO3. Analysis with X- ray diffraction suggested that the semicrystalline nature of PEO turned to amorphous due to the presence of LiCF3SO3. � 2009 Wiley Periodicals, Inc. Final 2023-12-29T07:55:22Z 2023-12-29T07:55:22Z 2009 Article 10.1002/app.29951 2-s2.0-67149118042 https://www.scopus.com/inward/record.uri?eid=2-s2.0-67149118042&doi=10.1002%2fapp.29951&partnerID=40&md5=48bf2ba6d573c4f136d3e6101f0fb1b5 https://irepository.uniten.edu.my/handle/123456789/30892 113 2 855 859 Scopus |
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Crystallinity Ionic conductivity PEO/ENR50 Solid polymer electrolyte Conducting polymers Conductive films Differential scanning calorimetry Diffraction Electrolysis Ethylene Film preparation Ionic conductivity Ions Oxide films Polyelectrolytes Polyethylene oxides Polymer films Polymers Proton exchange membrane fuel cells (PEMFC) Rubber films Scanning X ray diffraction X ray diffraction analysis AC-impedance Conducting properties Crystallinity Differential scanning calorimeters Epoxidized natural rubber PEO/ENR50 Polymer electrolyte films Room temperature Semicrystalline Solid polymer electrolyte Solid polymer electrolytes crystallinity electrical conductivity electrolyte film natural rubber polyethylene oxide polymer Ionic conduction in solids |
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Crystallinity Ionic conductivity PEO/ENR50 Solid polymer electrolyte Conducting polymers Conductive films Differential scanning calorimetry Diffraction Electrolysis Ethylene Film preparation Ionic conductivity Ions Oxide films Polyelectrolytes Polyethylene oxides Polymer films Polymers Proton exchange membrane fuel cells (PEMFC) Rubber films Scanning X ray diffraction X ray diffraction analysis AC-impedance Conducting properties Crystallinity Differential scanning calorimeters Epoxidized natural rubber PEO/ENR50 Polymer electrolyte films Room temperature Semicrystalline Solid polymer electrolyte Solid polymer electrolytes crystallinity electrical conductivity electrolyte film natural rubber polyethylene oxide polymer Ionic conduction in solids Noor S.A.M. Ahmad A. Rahman M.Y.A. Talib I.A. Preparation and characterization of a solid polymer electrolyte PEO-ENR50 (80/20)-LiCF3SO3 |
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The preparation and characterization of a polymer electrolyte films containing 80 wt % of poly (ethylene oxide) (PEO) and 20 wt % epoxidized natural rubber (ENR50) complexed with LiCF3SO3 has been reported. The ac impedance data showed good conducting properties of the solid polymer electrolyte (SPE) films. The greatest room temperature ionic conductivity of 7.5 � 10-5 S cm-1 was obtained at 25 wt % of LiCF 3SO3 salt. This result has been supported by differential scanning calorimeter and X-ray diffraction analysis. Analysis differential scanning calorimetry showed the relative percentage of crystallinity and T m of PEO decreased with the increasing wt % of LiCF 3SO3. Analysis with X- ray diffraction suggested that the semicrystalline nature of PEO turned to amorphous due to the presence of LiCF3SO3. � 2009 Wiley Periodicals, Inc. |
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35386952000 |
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35386952000 Noor S.A.M. Ahmad A. Rahman M.Y.A. Talib I.A. |
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Noor S.A.M. Ahmad A. Rahman M.Y.A. Talib I.A. |
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Noor S.A.M. |
title |
Preparation and characterization of a solid polymer electrolyte PEO-ENR50 (80/20)-LiCF3SO3 |
title_short |
Preparation and characterization of a solid polymer electrolyte PEO-ENR50 (80/20)-LiCF3SO3 |
title_full |
Preparation and characterization of a solid polymer electrolyte PEO-ENR50 (80/20)-LiCF3SO3 |
title_fullStr |
Preparation and characterization of a solid polymer electrolyte PEO-ENR50 (80/20)-LiCF3SO3 |
title_full_unstemmed |
Preparation and characterization of a solid polymer electrolyte PEO-ENR50 (80/20)-LiCF3SO3 |
title_sort |
preparation and characterization of a solid polymer electrolyte peo-enr50 (80/20)-licf3so3 |
publishDate |
2023 |
_version_ |
1806425598661230592 |
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13.22586 |