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Validation of a headspace solid-phase microextraction procedure with gas chromatography-electron capture detection of pesticide residues in fruits and vegetables

Headspace solid-phase microextraction (HS-SPME) was evaluated for the determination of pesticide residues in fruits and vegetables by gas chromatography with an electron capture detector (GC-ECD). The fibre used was coated with polydimethylsiloxane (100 ?m thickness) and the analytical conditions em...

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Main Authors:	Chai M.K., Tan G.H.
Other Authors:	24172523100
Format:	Article
Published:	2023
Subjects:	GC-ECD HS-SPME Organochlorine Organophosphorous organochlorine pesticide organophosphate pesticide analytic method analytical equipment article Brassica calibration cucumber electron capture detection food analysis fruit gas chromatography guava pesticide spraying solid phase microextraction strawberry tomato validation study vegetable
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id	my.uniten.dspace-30813
record_format	dspace
spelling	my.uniten.dspace-308132023-12-29T15:53:47Z Validation of a headspace solid-phase microextraction procedure with gas chromatography-electron capture detection of pesticide residues in fruits and vegetables Chai M.K. Tan G.H. 24172523100 7202393048 GC-ECD HS-SPME Organochlorine Organophosphorous organochlorine pesticide organophosphate pesticide analytic method analytical equipment article Brassica calibration cucumber electron capture detection food analysis fruit gas chromatography guava pesticide spraying solid phase microextraction strawberry tomato validation study vegetable Headspace solid-phase microextraction (HS-SPME) was evaluated for the determination of pesticide residues in fruits and vegetables by gas chromatography with an electron capture detector (GC-ECD). The fibre used was coated with polydimethylsiloxane (100 ?m thickness) and the analytical conditions employed have been developed and optimised in a previous work [Chai, M. K., Tan, G. H., & Asha, L. (2008). Optimisation of headspace solid-phase microextraction for the determination of pesticide residues in vegetables and fruits. Analytical Sciences, 24 (2), 273-276]. The results show that the HS-SPME procedure gave a better linear range, accuracy, precision, detection and quantification limits and is adequate for analysing pesticide residues in fruits and vegetables. The average recoveries obtained for each pesticide ranged between 71% and 98% at three fortification levels with the relative standard deviation of less than 5%. Repeatability (0.3-3.7%) and intermediate precision (0.8-2.5%) were shown to be satisfactory. The limits of detection (0.01-1 ?g L-1) and the limits of quantification (0.05-5 ?g L-1) of these pesticides were much lower than the maximum residue levels (MRL), allowed for fruits and vegetables in Malaysia. � 2009. Final 2023-12-29T07:53:47Z 2023-12-29T07:53:47Z 2009 Article 10.1016/j.foodchem.2009.04.034 2-s2.0-67349228156 https://www.scopus.com/inward/record.uri?eid=2-s2.0-67349228156&doi=10.1016%2fj.foodchem.2009.04.034&partnerID=40&md5=45b2fff1b59ccc6238103b8bc5f63121 https://irepository.uniten.edu.my/handle/123456789/30813 117 3 561 567 Scopus
institution	Universiti Tenaga Nasional
building	UNITEN Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Tenaga Nasional
content_source	UNITEN Institutional Repository
url_provider	http://dspace.uniten.edu.my/
topic	GC-ECD HS-SPME Organochlorine Organophosphorous organochlorine pesticide organophosphate pesticide analytic method analytical equipment article Brassica calibration cucumber electron capture detection food analysis fruit gas chromatography guava pesticide spraying solid phase microextraction strawberry tomato validation study vegetable
spellingShingle	GC-ECD HS-SPME Organochlorine Organophosphorous organochlorine pesticide organophosphate pesticide analytic method analytical equipment article Brassica calibration cucumber electron capture detection food analysis fruit gas chromatography guava pesticide spraying solid phase microextraction strawberry tomato validation study vegetable Chai M.K. Tan G.H. Validation of a headspace solid-phase microextraction procedure with gas chromatography-electron capture detection of pesticide residues in fruits and vegetables
description	Headspace solid-phase microextraction (HS-SPME) was evaluated for the determination of pesticide residues in fruits and vegetables by gas chromatography with an electron capture detector (GC-ECD). The fibre used was coated with polydimethylsiloxane (100 ?m thickness) and the analytical conditions employed have been developed and optimised in a previous work [Chai, M. K., Tan, G. H., & Asha, L. (2008). Optimisation of headspace solid-phase microextraction for the determination of pesticide residues in vegetables and fruits. Analytical Sciences, 24 (2), 273-276]. The results show that the HS-SPME procedure gave a better linear range, accuracy, precision, detection and quantification limits and is adequate for analysing pesticide residues in fruits and vegetables. The average recoveries obtained for each pesticide ranged between 71% and 98% at three fortification levels with the relative standard deviation of less than 5%. Repeatability (0.3-3.7%) and intermediate precision (0.8-2.5%) were shown to be satisfactory. The limits of detection (0.01-1 ?g L-1) and the limits of quantification (0.05-5 ?g L-1) of these pesticides were much lower than the maximum residue levels (MRL), allowed for fruits and vegetables in Malaysia. � 2009.
author2	24172523100
author_facet	24172523100 Chai M.K. Tan G.H.
format	Article
author	Chai M.K. Tan G.H.
author_sort	Chai M.K.
title	Validation of a headspace solid-phase microextraction procedure with gas chromatography-electron capture detection of pesticide residues in fruits and vegetables
title_short	Validation of a headspace solid-phase microextraction procedure with gas chromatography-electron capture detection of pesticide residues in fruits and vegetables
title_full	Validation of a headspace solid-phase microextraction procedure with gas chromatography-electron capture detection of pesticide residues in fruits and vegetables
title_fullStr	Validation of a headspace solid-phase microextraction procedure with gas chromatography-electron capture detection of pesticide residues in fruits and vegetables
title_full_unstemmed	Validation of a headspace solid-phase microextraction procedure with gas chromatography-electron capture detection of pesticide residues in fruits and vegetables
title_sort	validation of a headspace solid-phase microextraction procedure with gas chromatography-electron capture detection of pesticide residues in fruits and vegetables
publishDate	2023
_version_	1806428453189189632
score	13.222552

Validation of a headspace solid-phase microextraction procedure with gas chromatography-electron capture detection of pesticide residues in fruits and vegetables

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