Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios
Metal-organic framework MOF-5 (i.e. IRMOF-1) with the chemical structure of Zn4O(BDC)3 were successfully synthesized using room temperature synthesis approach of direct-mixing method ans liquid-crystal templating method. The metal clusters organic linker used was benzenedicarboxylic acid (BDC). Dire...
Saved in:
| Main Authors: | , , , |
|---|---|
| Other Authors: | |
| Format: | Conference paper |
| Published: |
Trans Tech Publications Ltd
2023
|
| Subjects: | |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| id |
my.uniten.dspace-30587 |
|---|---|
| record_format |
dspace |
| spelling |
my.uniten.dspace-305872023-12-29T15:49:52Z Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios Misran H. Aminuddin A.M. Zini F.A.M. Singh R. 6506899840 36981327400 36982594200 41061958200 BDC Liquid-crystal Metal-organic framework MOF-5 Organic linker Coordination reactions Crystal structure Crystallinity Liquid crystals Mixing Organometallics Coordination Polymers Cubic structure Direct mixing method Liquid crystal templating Metal organic framework MOF-5 Organic linkers Room temperature synthesis Metals Metal-organic framework MOF-5 (i.e. IRMOF-1) with the chemical structure of Zn4O(BDC)3 were successfully synthesized using room temperature synthesis approach of direct-mixing method ans liquid-crystal templating method. The metal clusters organic linker used was benzenedicarboxylic acid (BDC). Direct-mixing approach resulted in MOF-5 with tetragonal cell while the liquid-crystal templating method resulted in cubic structure. The metal/linker ratios were varied from 0.1 to 1 to study the effect of metal linker on the formation of MOF-5 materials and their characteristics. The crystallinity of the evacuated framework MOF-5 materials were increased when the metal/organic linker ratios were increased from 0.3 to 0.5. However, the cubic structure of the evacuated framework was relatively disrupted at metal/linker ratio 0.7. � (2011) Trans Tech Publications. Final 2023-12-29T07:49:52Z 2023-12-29T07:49:52Z 2011 Conference paper 10.4028/www.scientific.net/KEM.462-463.1103 2-s2.0-79551469312 https://www.scopus.com/inward/record.uri?eid=2-s2.0-79551469312&doi=10.4028%2fwww.scientific.net%2fKEM.462-463.1103&partnerID=40&md5=2d310254e8535a0e8c508da331643b12 https://irepository.uniten.edu.my/handle/123456789/30587 462-463 1103 1108 Trans Tech Publications Ltd Scopus |
| institution |
Universiti Tenaga Nasional |
| building |
UNITEN Library |
| collection |
Institutional Repository |
| continent |
Asia |
| country |
Malaysia |
| content_provider |
Universiti Tenaga Nasional |
| content_source |
UNITEN Institutional Repository |
| url_provider |
http://dspace.uniten.edu.my/ |
| topic |
BDC Liquid-crystal Metal-organic framework MOF-5 Organic linker Coordination reactions Crystal structure Crystallinity Liquid crystals Mixing Organometallics Coordination Polymers Cubic structure Direct mixing method Liquid crystal templating Metal organic framework MOF-5 Organic linkers Room temperature synthesis Metals |
| spellingShingle |
BDC Liquid-crystal Metal-organic framework MOF-5 Organic linker Coordination reactions Crystal structure Crystallinity Liquid crystals Mixing Organometallics Coordination Polymers Cubic structure Direct mixing method Liquid crystal templating Metal organic framework MOF-5 Organic linkers Room temperature synthesis Metals Misran H. Aminuddin A.M. Zini F.A.M. Singh R. Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios |
| description |
Metal-organic framework MOF-5 (i.e. IRMOF-1) with the chemical structure of Zn4O(BDC)3 were successfully synthesized using room temperature synthesis approach of direct-mixing method ans liquid-crystal templating method. The metal clusters organic linker used was benzenedicarboxylic acid (BDC). Direct-mixing approach resulted in MOF-5 with tetragonal cell while the liquid-crystal templating method resulted in cubic structure. The metal/linker ratios were varied from 0.1 to 1 to study the effect of metal linker on the formation of MOF-5 materials and their characteristics. The crystallinity of the evacuated framework MOF-5 materials were increased when the metal/organic linker ratios were increased from 0.3 to 0.5. However, the cubic structure of the evacuated framework was relatively disrupted at metal/linker ratio 0.7. � (2011) Trans Tech Publications. |
| author2 |
6506899840 |
| author_facet |
6506899840 Misran H. Aminuddin A.M. Zini F.A.M. Singh R. |
| format |
Conference paper |
| author |
Misran H. Aminuddin A.M. Zini F.A.M. Singh R. |
| author_sort |
Misran H. |
| title |
Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios |
| title_short |
Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios |
| title_full |
Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios |
| title_fullStr |
Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios |
| title_full_unstemmed |
Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios |
| title_sort |
synthesis and structural consideration of metal-organic framework (mof) coordination polymer with various metal linker ratios |
| publisher |
Trans Tech Publications Ltd |
| publishDate |
2023 |
| _version_ |
1806427938233516032 |
| score |
13.222552 |