Preparation and characterization of TiO2 nanowire - Cu2O nanocube composite thin film

Composite of TiO2 nanowire and Cu2O nanocube has been prepared. TiO2 nanowire with ~240 nm in thickness and 20 nm in length were synthesized by using liquid phase deposition (LPD) method at 50�C for 4h on ITO substrate. The anatase phase of TiO2 nanowire was obtained by annealing the samples at 400�...

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Main Authors: Naumar F.Y., Umar A.A., Rahman M.Y.A., Salleh M.M., Umar M.I.A., Nafisah S., Saad S.K.M., Tan S.T.
Other Authors: 55754494400
Format: Conference paper
Published: Trans Tech Publications Ltd 2023
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spelling my.uniten.dspace-301442023-12-29T15:44:55Z Preparation and characterization of TiO2 nanowire - Cu2O nanocube composite thin film Naumar F.Y. Umar A.A. Rahman M.Y.A. Salleh M.M. Umar M.I.A. Nafisah S. Saad S.K.M. Tan S.T. 55754494400 9332520900 55347217400 55613229960 55366900800 57189290090 57204351265 57209466790 Composite thin film Nanocube Nanowire Ascorbic acid Copper oxides Film preparation Hybrid systems Light absorption Nanowires Optical properties Thin films Titanium dioxide Ultraviolet visible spectroscopy Absorption property Alkaline conditions Composite thin films Liquid phase deposition method (LPD) Nanocubes Photoelectrochemical applications Tri-sodium citrates UV-vis spectroscopy Nanocomposite films Composite of TiO2 nanowire and Cu2O nanocube has been prepared. TiO2 nanowire with ~240 nm in thickness and 20 nm in length were synthesized by using liquid phase deposition (LPD) method at 50�C for 4h on ITO substrate. The anatase phase of TiO2 nanowire was obtained by annealing the samples at 400�C for 1h in air. The Cu2O nanocubes were prepared by the reduction of Cu2+ ions with ascorbic acid in the present of trisodium citrate and sodium dodecil sulfat (SDS) surfactant under an alkaline condition. The SDS addition was added with various concentrations namely 10 mM, 18 mM, and 26 mM during the Cu2O preparation for spin-coated onto TiO2 nanowire at 3000 rpm for 30s. An optical property of TiO2 Nanowire - Cu2O Nanocube has been characterized by UV-Vis spectroscopy. The original TiO2 nanowire has single absorption peak at 318 nm, but it was shifted to 321 nm as Cu2O/SDS addition. A new peak at 440 nm was as the Cu2O nanocube absorption spectra. The Cu2O nanocube addition to the TiO2 nanostructure film caused increase in the optical absorption of the system in the region 400 - 800 nm. We also studied the absorption properties of the hybrid system when Cu2O nanocube preparation under SDS condition. It was that found the increase in the SDS concentration has caused the optical absorption of the hybrid in this region decreased. This is believed due to the decrease of Cu2O nanocube size as the SDS concentration increase. This could be due to change in the TiO2 nanowire-Cu2O nanocube hybrid-structure. This cooperate may find use in photoelectrochemical application. � (2013) Trans Tech Publications, Switzerland. Final 2023-12-29T07:44:55Z 2023-12-29T07:44:55Z 2013 Conference paper 10.4028/www.scientific.net/MSF.756.37 2-s2.0-84878516409 https://www.scopus.com/inward/record.uri?eid=2-s2.0-84878516409&doi=10.4028%2fwww.scientific.net%2fMSF.756.37&partnerID=40&md5=414a062064eced3fd85980de9a089092 https://irepository.uniten.edu.my/handle/123456789/30144 756 37 42 Trans Tech Publications Ltd Scopus
institution Universiti Tenaga Nasional
building UNITEN Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
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topic Composite thin film
Nanocube
Nanowire
Ascorbic acid
Copper oxides
Film preparation
Hybrid systems
Light absorption
Nanowires
Optical properties
Thin films
Titanium dioxide
Ultraviolet visible spectroscopy
Absorption property
Alkaline conditions
Composite thin films
Liquid phase deposition method (LPD)
Nanocubes
Photoelectrochemical applications
Tri-sodium citrates
UV-vis spectroscopy
Nanocomposite films
spellingShingle Composite thin film
Nanocube
Nanowire
Ascorbic acid
Copper oxides
Film preparation
Hybrid systems
Light absorption
Nanowires
Optical properties
Thin films
Titanium dioxide
Ultraviolet visible spectroscopy
Absorption property
Alkaline conditions
Composite thin films
Liquid phase deposition method (LPD)
Nanocubes
Photoelectrochemical applications
Tri-sodium citrates
UV-vis spectroscopy
Nanocomposite films
Naumar F.Y.
Umar A.A.
Rahman M.Y.A.
Salleh M.M.
Umar M.I.A.
Nafisah S.
Saad S.K.M.
Tan S.T.
Preparation and characterization of TiO2 nanowire - Cu2O nanocube composite thin film
description Composite of TiO2 nanowire and Cu2O nanocube has been prepared. TiO2 nanowire with ~240 nm in thickness and 20 nm in length were synthesized by using liquid phase deposition (LPD) method at 50�C for 4h on ITO substrate. The anatase phase of TiO2 nanowire was obtained by annealing the samples at 400�C for 1h in air. The Cu2O nanocubes were prepared by the reduction of Cu2+ ions with ascorbic acid in the present of trisodium citrate and sodium dodecil sulfat (SDS) surfactant under an alkaline condition. The SDS addition was added with various concentrations namely 10 mM, 18 mM, and 26 mM during the Cu2O preparation for spin-coated onto TiO2 nanowire at 3000 rpm for 30s. An optical property of TiO2 Nanowire - Cu2O Nanocube has been characterized by UV-Vis spectroscopy. The original TiO2 nanowire has single absorption peak at 318 nm, but it was shifted to 321 nm as Cu2O/SDS addition. A new peak at 440 nm was as the Cu2O nanocube absorption spectra. The Cu2O nanocube addition to the TiO2 nanostructure film caused increase in the optical absorption of the system in the region 400 - 800 nm. We also studied the absorption properties of the hybrid system when Cu2O nanocube preparation under SDS condition. It was that found the increase in the SDS concentration has caused the optical absorption of the hybrid in this region decreased. This is believed due to the decrease of Cu2O nanocube size as the SDS concentration increase. This could be due to change in the TiO2 nanowire-Cu2O nanocube hybrid-structure. This cooperate may find use in photoelectrochemical application. � (2013) Trans Tech Publications, Switzerland.
author2 55754494400
author_facet 55754494400
Naumar F.Y.
Umar A.A.
Rahman M.Y.A.
Salleh M.M.
Umar M.I.A.
Nafisah S.
Saad S.K.M.
Tan S.T.
format Conference paper
author Naumar F.Y.
Umar A.A.
Rahman M.Y.A.
Salleh M.M.
Umar M.I.A.
Nafisah S.
Saad S.K.M.
Tan S.T.
author_sort Naumar F.Y.
title Preparation and characterization of TiO2 nanowire - Cu2O nanocube composite thin film
title_short Preparation and characterization of TiO2 nanowire - Cu2O nanocube composite thin film
title_full Preparation and characterization of TiO2 nanowire - Cu2O nanocube composite thin film
title_fullStr Preparation and characterization of TiO2 nanowire - Cu2O nanocube composite thin film
title_full_unstemmed Preparation and characterization of TiO2 nanowire - Cu2O nanocube composite thin film
title_sort preparation and characterization of tio2 nanowire - cu2o nanocube composite thin film
publisher Trans Tech Publications Ltd
publishDate 2023
_version_ 1806428380036333568
score 13.222552