Role of salt concentration lithium perchlorate on ionic conductivity and structural of (glycidyl methacrylate -co-ethyl methacrylate) (70/30) based on a solid polymer electrolyte
A new solid polymer electrolytes (SPE) comprising copolymer of poly(glycidyl methacrylate, GMA) and (ethyl methacrylate, EMA) as polymer host and LiClO4 as dopant was prepared by solution-casting technique. The copolymer was prepared by photopolymerization method and was characterized using NMR. The...
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my.uniten.dspace-301202023-12-29T15:44:41Z Role of salt concentration lithium perchlorate on ionic conductivity and structural of (glycidyl methacrylate -co-ethyl methacrylate) (70/30) based on a solid polymer electrolyte Imperiyka M. Ahmad A. Hanifah S.A. Rahman M.Y.A. 55561781600 16306307100 25632177200 55347217400 Ethyl methacylate Glycidyl methacrylate Ionic conductivity Lithium ion battery Copolymers Electrochemical impedance spectroscopy Ethers Fourier transform infrared spectroscopy Fourier transforms Inorganic compounds Ionic conduction in solids Ionic conductivity Lithium Photopolymerization Polyelectrolytes X ray diffraction Coordination sites Crystallinities Epoxy group Ethyl methacrylates Ethyl methacylate FTIR Glycidyl methacrylate Lithium perchlorate Lithium-ion battery Room temperature Salt concentration Solid polymer electrolytes Solution-casting technique Acrylic monomers A new solid polymer electrolytes (SPE) comprising copolymer of poly(glycidyl methacrylate, GMA) and (ethyl methacrylate, EMA) as polymer host and LiClO4 as dopant was prepared by solution-casting technique. The copolymer was prepared by photopolymerization method and was characterized using NMR. The SPEs were characterized using electrochemical impedance spectroscopy (EIS), fourier transforms infrared (FTIR) and X-ray diffraction (XRD). The highest conductivity achieved was 4.0x10-4 at 373K with highest conductivity at room temperature (2.7x10-5 S cm-1 at 30 wt. % of LiClO4). The active coordination site for the cation (Li+), three electrons donating functional carbonyl, ether and epoxy group of the GMA-co-EMA host have been evaluated base on their properties that were recorded in (FTIR). The structural analysis showed reduction in copolymer crystallinity phases at its highest conductivity. � (2013) Trans Tech Publications, Switzerland. Final 2023-12-29T07:44:41Z 2023-12-29T07:44:41Z 2013 Conference paper 10.4028/www.scientific.net/AMR.626.454 2-s2.0-84872529226 https://www.scopus.com/inward/record.uri?eid=2-s2.0-84872529226&doi=10.4028%2fwww.scientific.net%2fAMR.626.454&partnerID=40&md5=75ee32d4ef407f12ca40baf64756edc6 https://irepository.uniten.edu.my/handle/123456789/30120 626 454 458 Scopus |
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Ethyl methacylate Glycidyl methacrylate Ionic conductivity Lithium ion battery Copolymers Electrochemical impedance spectroscopy Ethers Fourier transform infrared spectroscopy Fourier transforms Inorganic compounds Ionic conduction in solids Ionic conductivity Lithium Photopolymerization Polyelectrolytes X ray diffraction Coordination sites Crystallinities Epoxy group Ethyl methacrylates Ethyl methacylate FTIR Glycidyl methacrylate Lithium perchlorate Lithium-ion battery Room temperature Salt concentration Solid polymer electrolytes Solution-casting technique Acrylic monomers |
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Ethyl methacylate Glycidyl methacrylate Ionic conductivity Lithium ion battery Copolymers Electrochemical impedance spectroscopy Ethers Fourier transform infrared spectroscopy Fourier transforms Inorganic compounds Ionic conduction in solids Ionic conductivity Lithium Photopolymerization Polyelectrolytes X ray diffraction Coordination sites Crystallinities Epoxy group Ethyl methacrylates Ethyl methacylate FTIR Glycidyl methacrylate Lithium perchlorate Lithium-ion battery Room temperature Salt concentration Solid polymer electrolytes Solution-casting technique Acrylic monomers Imperiyka M. Ahmad A. Hanifah S.A. Rahman M.Y.A. Role of salt concentration lithium perchlorate on ionic conductivity and structural of (glycidyl methacrylate -co-ethyl methacrylate) (70/30) based on a solid polymer electrolyte |
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A new solid polymer electrolytes (SPE) comprising copolymer of poly(glycidyl methacrylate, GMA) and (ethyl methacrylate, EMA) as polymer host and LiClO4 as dopant was prepared by solution-casting technique. The copolymer was prepared by photopolymerization method and was characterized using NMR. The SPEs were characterized using electrochemical impedance spectroscopy (EIS), fourier transforms infrared (FTIR) and X-ray diffraction (XRD). The highest conductivity achieved was 4.0x10-4 at 373K with highest conductivity at room temperature (2.7x10-5 S cm-1 at 30 wt. % of LiClO4). The active coordination site for the cation (Li+), three electrons donating functional carbonyl, ether and epoxy group of the GMA-co-EMA host have been evaluated base on their properties that were recorded in (FTIR). The structural analysis showed reduction in copolymer crystallinity phases at its highest conductivity. � (2013) Trans Tech Publications, Switzerland. |
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55561781600 |
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55561781600 Imperiyka M. Ahmad A. Hanifah S.A. Rahman M.Y.A. |
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Conference paper |
author |
Imperiyka M. Ahmad A. Hanifah S.A. Rahman M.Y.A. |
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Imperiyka M. |
title |
Role of salt concentration lithium perchlorate on ionic conductivity and structural of (glycidyl methacrylate -co-ethyl methacrylate) (70/30) based on a solid polymer electrolyte |
title_short |
Role of salt concentration lithium perchlorate on ionic conductivity and structural of (glycidyl methacrylate -co-ethyl methacrylate) (70/30) based on a solid polymer electrolyte |
title_full |
Role of salt concentration lithium perchlorate on ionic conductivity and structural of (glycidyl methacrylate -co-ethyl methacrylate) (70/30) based on a solid polymer electrolyte |
title_fullStr |
Role of salt concentration lithium perchlorate on ionic conductivity and structural of (glycidyl methacrylate -co-ethyl methacrylate) (70/30) based on a solid polymer electrolyte |
title_full_unstemmed |
Role of salt concentration lithium perchlorate on ionic conductivity and structural of (glycidyl methacrylate -co-ethyl methacrylate) (70/30) based on a solid polymer electrolyte |
title_sort |
role of salt concentration lithium perchlorate on ionic conductivity and structural of (glycidyl methacrylate -co-ethyl methacrylate) (70/30) based on a solid polymer electrolyte |
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2023 |
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1806424477890772992 |
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13.226497 |