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Adsorption characteristics of organosilica based mesoporous materials

Hybrid organosilica mesoporous materials with pores of ordered three-dimensional hexagonal structure were prepared by the hydrolysis and co-condensation of 1,2-bis(triethoxysilyl)ethane with various concentrations of a surfactant as structure directing agents. The materials had high pore volume of 1...

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Main Authors:	Matsumoto A., Misran H., Tsutsumi K.
Other Authors:	14525231700
Format:	Article
Published:	2023
Subjects:	Adsorption Calorimetry Catalysts Condensation Hydrolysis Metalorganics Silica Water Repellence Hydrophobicity Mesoporous materials Co-condensation Dynamic adsorption Hexagonal structures Reaction catalysts Organometallics
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id	my.uniten.dspace-29931
record_format	dspace
spelling	my.uniten.dspace-299312023-12-28T16:58:19Z Adsorption characteristics of organosilica based mesoporous materials Matsumoto A. Misran H. Tsutsumi K. 14525231700 6506899840 7202827226 Adsorption Calorimetry Catalysts Condensation Hydrolysis Metalorganics Silica Water Repellence Adsorption Calorimetry Catalysts Condensation Hydrolysis Hydrophobicity Mesoporous materials Silica Co-condensation Dynamic adsorption Hexagonal structures Reaction catalysts Organometallics Hybrid organosilica mesoporous materials with pores of ordered three-dimensional hexagonal structure were prepared by the hydrolysis and co-condensation of 1,2-bis(triethoxysilyl)ethane with various concentrations of a surfactant as structure directing agents. The materials had high pore volume of 1-1.5 mL/g and high surface area from 1057 to 1445 m2/g. Adsorption measurement and adsorption calorimetry revealed that the prepared materials exhibited high hydrophobicity and high affinity toward nonpolar organic vapor such as n-hexane. The dynamic adsorption properties of the materials for n-hexane in the presence of water vapor showed that these hybrid organosilica materials preferentially adsorbed n-hexane vapor and were stable in the presence of water compared to the siliceous MCM48. Final 2023-12-28T08:58:19Z 2023-12-28T08:58:19Z 2004 Article 10.1021/la0360409 2-s2.0-4344594950 https://www.scopus.com/inward/record.uri?eid=2-s2.0-4344594950&doi=10.1021%2fla0360409&partnerID=40&md5=b50f910d8385ab678ecc80bb1d96fbf2 https://irepository.uniten.edu.my/handle/123456789/29931 20 17 7139 7145 Scopus
institution	Universiti Tenaga Nasional
building	UNITEN Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Tenaga Nasional
content_source	UNITEN Institutional Repository
url_provider	http://dspace.uniten.edu.my/
topic	Adsorption Calorimetry Catalysts Condensation Hydrolysis Metalorganics Silica Water Repellence Adsorption Calorimetry Catalysts Condensation Hydrolysis Hydrophobicity Mesoporous materials Silica Co-condensation Dynamic adsorption Hexagonal structures Reaction catalysts Organometallics
spellingShingle	Adsorption Calorimetry Catalysts Condensation Hydrolysis Metalorganics Silica Water Repellence Adsorption Calorimetry Catalysts Condensation Hydrolysis Hydrophobicity Mesoporous materials Silica Co-condensation Dynamic adsorption Hexagonal structures Reaction catalysts Organometallics Matsumoto A. Misran H. Tsutsumi K. Adsorption characteristics of organosilica based mesoporous materials
description	Hybrid organosilica mesoporous materials with pores of ordered three-dimensional hexagonal structure were prepared by the hydrolysis and co-condensation of 1,2-bis(triethoxysilyl)ethane with various concentrations of a surfactant as structure directing agents. The materials had high pore volume of 1-1.5 mL/g and high surface area from 1057 to 1445 m2/g. Adsorption measurement and adsorption calorimetry revealed that the prepared materials exhibited high hydrophobicity and high affinity toward nonpolar organic vapor such as n-hexane. The dynamic adsorption properties of the materials for n-hexane in the presence of water vapor showed that these hybrid organosilica materials preferentially adsorbed n-hexane vapor and were stable in the presence of water compared to the siliceous MCM48.
author2	14525231700
author_facet	14525231700 Matsumoto A. Misran H. Tsutsumi K.
format	Article
author	Matsumoto A. Misran H. Tsutsumi K.
author_sort	Matsumoto A.
title	Adsorption characteristics of organosilica based mesoporous materials
title_short	Adsorption characteristics of organosilica based mesoporous materials
title_full	Adsorption characteristics of organosilica based mesoporous materials
title_fullStr	Adsorption characteristics of organosilica based mesoporous materials
title_full_unstemmed	Adsorption characteristics of organosilica based mesoporous materials
title_sort	adsorption characteristics of organosilica based mesoporous materials
publishDate	2023
_version_	1806428379115683840
score	13.222552

Adsorption characteristics of organosilica based mesoporous materials

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