Structural analyses of polyaniline�titanium oxide composite for acetone detection

Acetone; Aniline; Chemical sensors; Fourier transform infrared spectroscopy; Gas detectors; High resolution transmission electron microscopy; Magnetic semiconductors; Scanning electron microscopy; Temperature; Titanium dioxide; Composite pellets; Operating temperature; Polyanilines (PAni); Scanning...

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Main Authors: Bahru R., Zamri M.F.M.A., Shamsuddin A.H., Mohamed M.A.
Other Authors: 57195836029
Format: Article
Published: Springer 2023
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spelling my.uniten.dspace-258332023-05-29T16:15:00Z Structural analyses of polyaniline�titanium oxide composite for acetone detection Bahru R. Zamri M.F.M.A. Shamsuddin A.H. Mohamed M.A. 57195836029 57354218900 35779071900 57581478900 Acetone; Aniline; Chemical sensors; Fourier transform infrared spectroscopy; Gas detectors; High resolution transmission electron microscopy; Magnetic semiconductors; Scanning electron microscopy; Temperature; Titanium dioxide; Composite pellets; Operating temperature; Polyanilines (PAni); Scanning electrons; Semiconductor gas sensors; Sensing performance; Situ chemical polymerizations; Structural characterization; Polyaniline This study characterized the performance of polyaniline�titanium oxide (PANI�TiO2) composite to assess its use as potential acetone detector in semiconductor gas sensor. Aniline (ANI), which refers to a monomer, has been used for in situ chemical polymerization to produce polyaniline (PANI) and titanium oxide (TiO2) composite. PANI was varied in composition of 20, 30, and 40 wt% loading with TiO2. Inclusion of PANI in composite is meant to detect acetone at various concentrations (100�500�ppm) at selected operating temperatures (27, 35, 45, 55, and 65��C). The results signified that the best structure of PANI loading in TiO2 is at 30 wt% due to the molecular structure for gas sensor. The sensitivity of PANI�TiO2 composite pellet for various acetone vapor concentrations had been optimum at 300�ppm with 7.9% sensitivity. The optimum operating temperature was 45��C with 10.12% sensitivity. Structural characterizations via X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, and Brunauer�Emmet�Teller were conducted to correlate with the sensor sensing performance. Indeed, the 30 wt% of PANI�TiO2 composite has the potential to detect 300�ppm of acetone and displayed exceptional agreement with outcomes retrieved at 45��C detection temperature. � 2019, Springer Science+Business Media, LLC, part of Springer Nature. Final 2023-05-29T08:14:59Z 2023-05-29T08:14:59Z 2020 Article 10.1007/s10854-019-02674-2 2-s2.0-85076090693 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85076090693&doi=10.1007%2fs10854-019-02674-2&partnerID=40&md5=e30a2ebf202032bb514be960e05f6434 https://irepository.uniten.edu.my/handle/123456789/25833 31 2 1574 1584 Springer Scopus
institution Universiti Tenaga Nasional
building UNITEN Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
url_provider http://dspace.uniten.edu.my/
description Acetone; Aniline; Chemical sensors; Fourier transform infrared spectroscopy; Gas detectors; High resolution transmission electron microscopy; Magnetic semiconductors; Scanning electron microscopy; Temperature; Titanium dioxide; Composite pellets; Operating temperature; Polyanilines (PAni); Scanning electrons; Semiconductor gas sensors; Sensing performance; Situ chemical polymerizations; Structural characterization; Polyaniline
author2 57195836029
author_facet 57195836029
Bahru R.
Zamri M.F.M.A.
Shamsuddin A.H.
Mohamed M.A.
format Article
author Bahru R.
Zamri M.F.M.A.
Shamsuddin A.H.
Mohamed M.A.
spellingShingle Bahru R.
Zamri M.F.M.A.
Shamsuddin A.H.
Mohamed M.A.
Structural analyses of polyaniline�titanium oxide composite for acetone detection
author_sort Bahru R.
title Structural analyses of polyaniline�titanium oxide composite for acetone detection
title_short Structural analyses of polyaniline�titanium oxide composite for acetone detection
title_full Structural analyses of polyaniline�titanium oxide composite for acetone detection
title_fullStr Structural analyses of polyaniline�titanium oxide composite for acetone detection
title_full_unstemmed Structural analyses of polyaniline�titanium oxide composite for acetone detection
title_sort structural analyses of polyaniline�titanium oxide composite for acetone detection
publisher Springer
publishDate 2023
_version_ 1806423479044538368
score 13.222552