Effect of Copper Oxide and Manganese Oxide on Properties and Low Temperature Degradation of Sintered Y-TZP Ceramic

The effect of copper oxide (CuO) and manganese oxide (MnO2) co-dopant on the densification behavior of 3 mol% yttria-stabilized zirconia was investigated. Green samples were prepared and sintered in air at temperatures ranging from 1250 to 1500 °C with a short holding time of 12 min. Sintered bodies...

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Main Authors: Khan M.M., Ramesh S., Bang L.T., Wong Y.H., Ubenthiran S., Tan C.Y., Purbolaksono J., Misran H.
Other Authors: 56431598700
Format: Article
Published: Springer Science and Business Media, LLC 2023
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spelling my.uniten.dspace-218282023-05-16T10:45:36Z Effect of Copper Oxide and Manganese Oxide on Properties and Low Temperature Degradation of Sintered Y-TZP Ceramic Khan M.M. Ramesh S. Bang L.T. Wong Y.H. Ubenthiran S. Tan C.Y. Purbolaksono J. Misran H. 56431598700 41061958200 36241434700 36605495300 55886142900 16029485400 8621252500 6506899840 The effect of copper oxide (CuO) and manganese oxide (MnO2) co-dopant on the densification behavior of 3 mol% yttria-stabilized zirconia was investigated. Green samples were prepared and sintered in air at temperatures ranging from 1250 to 1500 °C with a short holding time of 12 min. Sintered bodies were characterized to determine the phase stability, bulk density, hardness, fracture toughness, Young’s modulus and grain size. In addition, the aging-induced tetragonal to monoclinic phase transformation of the sintered zirconia was evaluated. It was revealed that the addition of CuO-MnO2 co-dopant was beneficial in enhancing the densification and mechanical properties of the ceramic particularly at low temperatures. A high fracture toughness of 5.5 MPam1/2 coupled with high hardness of 14.5 GPa was obtained for co-doped samples sintered at 1350 °C. However, the undoped ceramic exhibited better properties when sintered above 1350 °C. The study also found that the dopants did not prevent grain coarsening and hence did not suppress the aging-induced phase transformation particularly for samples sintered above 1350 °C. © 2014, ASM International. Final 2023-05-16T02:45:36Z 2023-05-16T02:45:36Z 2014 Article 10.1007/s11665-014-1231-1 2-s2.0-84913589868 https://www.scopus.com/inward/record.uri?eid=2-s2.0-84913589868&doi=10.1007%2fs11665-014-1231-1&partnerID=40&md5=f2a026c2fa3ac705d95b924ecffe7c92 https://irepository.uniten.edu.my/handle/123456789/21828 23 12 4328 4335 Springer Science and Business Media, LLC Scopus
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country Malaysia
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description The effect of copper oxide (CuO) and manganese oxide (MnO2) co-dopant on the densification behavior of 3 mol% yttria-stabilized zirconia was investigated. Green samples were prepared and sintered in air at temperatures ranging from 1250 to 1500 °C with a short holding time of 12 min. Sintered bodies were characterized to determine the phase stability, bulk density, hardness, fracture toughness, Young’s modulus and grain size. In addition, the aging-induced tetragonal to monoclinic phase transformation of the sintered zirconia was evaluated. It was revealed that the addition of CuO-MnO2 co-dopant was beneficial in enhancing the densification and mechanical properties of the ceramic particularly at low temperatures. A high fracture toughness of 5.5 MPam1/2 coupled with high hardness of 14.5 GPa was obtained for co-doped samples sintered at 1350 °C. However, the undoped ceramic exhibited better properties when sintered above 1350 °C. The study also found that the dopants did not prevent grain coarsening and hence did not suppress the aging-induced phase transformation particularly for samples sintered above 1350 °C. © 2014, ASM International.
author2 56431598700
author_facet 56431598700
Khan M.M.
Ramesh S.
Bang L.T.
Wong Y.H.
Ubenthiran S.
Tan C.Y.
Purbolaksono J.
Misran H.
format Article
author Khan M.M.
Ramesh S.
Bang L.T.
Wong Y.H.
Ubenthiran S.
Tan C.Y.
Purbolaksono J.
Misran H.
spellingShingle Khan M.M.
Ramesh S.
Bang L.T.
Wong Y.H.
Ubenthiran S.
Tan C.Y.
Purbolaksono J.
Misran H.
Effect of Copper Oxide and Manganese Oxide on Properties and Low Temperature Degradation of Sintered Y-TZP Ceramic
author_sort Khan M.M.
title Effect of Copper Oxide and Manganese Oxide on Properties and Low Temperature Degradation of Sintered Y-TZP Ceramic
title_short Effect of Copper Oxide and Manganese Oxide on Properties and Low Temperature Degradation of Sintered Y-TZP Ceramic
title_full Effect of Copper Oxide and Manganese Oxide on Properties and Low Temperature Degradation of Sintered Y-TZP Ceramic
title_fullStr Effect of Copper Oxide and Manganese Oxide on Properties and Low Temperature Degradation of Sintered Y-TZP Ceramic
title_full_unstemmed Effect of Copper Oxide and Manganese Oxide on Properties and Low Temperature Degradation of Sintered Y-TZP Ceramic
title_sort effect of copper oxide and manganese oxide on properties and low temperature degradation of sintered y-tzp ceramic
publisher Springer Science and Business Media, LLC
publishDate 2023
_version_ 1806425824997408768
score 13.222552