Oxidative addition of (bromoethynyl)benzene to κ2- acetylacetonatobis(trimethylphosphine)rhodium(I)
The reaction of (bromoethynyl)benzene with κ2-acetylacetonatobis(trimethylphosphine)rhodium(I), [Rh(acac)(PMe3)2] 1, was followed by in situ1H and 31P NMR spectroscopy. The kinetic product is that of cis-oxidative addition of the C–Br bond to Rh, and this species rearranges to the thermodynamically...
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| 主要な著者: | , , , , |
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| フォーマット: | E-Article |
| 言語: | English |
| 出版事項: |
Elsevier
2013
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| 主題: | |
| オンライン･アクセス: | http://ir.unimas.my/id/eprint/7404/1/Oxidative%20addition%20of%20%28bromoethynyl%29benzene%20to%202-acetylacetonato%20bis%28trimethylphosphine%29%20rhodium%28I%29%20-%20%28abstract%29.pdf http://ir.unimas.my/id/eprint/7404/ http://www.sciencedirect.com/science/article/pii/S0022328X12006778 |
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| 要約: | The reaction of (bromoethynyl)benzene with κ2-acetylacetonatobis(trimethylphosphine)rhodium(I), [Rh(acac)(PMe3)2] 1, was followed by in situ1H and 31P NMR spectroscopy. The kinetic product is that of cis-oxidative addition of the C–Br bond to Rh, and this species rearranges to the thermodynamically more stable trans-oxidative addition product trans-[Rh(acac)(Br)(CCPh)(PMe3)2] 3. The structures of both 1 and 3 have been determined by single-crystal X-ray diffraction. |
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