Oxidative addition of (bromoethynyl) benzene to κ 2-acetylacetonatobis (trimethylphosphine) rhodium (I)
The reaction of (bromoethynyl)benzene with κ2-acetylacetonatobis(trimethylphosphine)rhodium(I), [Rh(acac)(PMe3)2] 1, was followed by in situ1H and 31P NMR spectroscopy. The kinetic product is that of cis-oxidative addition of the C–Br bond to Rh, and this species rearranges to the thermodynamically...
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| Main Authors: | , , , , |
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| Format: | E-Article |
| Published: |
Elsevier
2013
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| Subjects: | |
| Online Access: | http://ir.unimas.my/id/eprint/7403/ http://www.sciencedirect.com/science/article/pii/S0022328X12006778 |
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