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n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV)

Two independent molecules comprise the asymmetric unit of the title compound, [Sn(C4H9)(C13H12N3O)Cl2]. The Sn atom in each is coordinated by the tridentate ligand via the phenoxide O, hydrazine N and pyridyl N atoms, forming fiveand six-membered chelate rings. The approximately octahedral coordi...

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Main Authors: Fasihuddin Badruddin, Ahmad, Md Abu, Affan, Dayang NA, Chee, Seik Weng, Ng, Edward R. T., Tiekink
Format: E-Article
Language:English
English
Published: International Union of Crystallography 2010
Subjects:
QD Chemistry
Online Access:http://ir.unimas.my/id/eprint/7358/1/n-Butyldichlorido%20%282-%7B%281E%29-1-%5B2-%28pyridin-2-yl%29%20hydrazin-1-ylidene%5D%20ethyl%7D%20phenolato%29%20tin%20%28IV%29%20%28abstract%29.pdf
http://ir.unimas.my/id/eprint/7358/2/n-Butyldichlorido%282-%7B%281E%29-1-%5B2-%28pyridin-%28OCR%29.pdf
http://ir.unimas.my/id/eprint/7358/
http://journals.iucr.org/e/issues/2010/11/00/hb5679/hb5679.pdf
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spelling my.unimas.ir.73582016-04-20T00:37:01Z http://ir.unimas.my/id/eprint/7358/ n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV) Fasihuddin Badruddin, Ahmad Md Abu, Affan Dayang NA, Chee Seik Weng, Ng Edward R. T., Tiekink QD Chemistry Two independent molecules comprise the asymmetric unit of the title compound, [Sn(C4H9)(C13H12N3O)Cl2]. The Sn atom in each is coordinated by the tridentate ligand via the phenoxide O, hydrazine N and pyridyl N atoms, forming fiveand six-membered chelate rings. The approximately octahedral coordination geometry is completed by the -C atom of the n-butyl group (which is trans to the hydrazine N atom) and two mutually trans Cl atoms. Differences between the molecules are evident in the relative planarity of the chelate rings and in the conformations of the n-butyl groups [C—C—C—C = 177.2 (5) and 64.4 (11)]. Significant differences in the Sn—Cl bond lengths are related to the formation of N—H���Cl hydrogen bonds, which link the molecules comprising the asymmetric unit into dimeric aggregates. These are consolidated in the crystal packing by C—H���Cl contacts. The structure was refined as an inversion twin; the minor twin component is 37 (3)%. International Union of Crystallography 2010 E-Article PeerReviewed text en http://ir.unimas.my/id/eprint/7358/1/n-Butyldichlorido%20%282-%7B%281E%29-1-%5B2-%28pyridin-2-yl%29%20hydrazin-1-ylidene%5D%20ethyl%7D%20phenolato%29%20tin%20%28IV%29%20%28abstract%29.pdf text en http://ir.unimas.my/id/eprint/7358/2/n-Butyldichlorido%282-%7B%281E%29-1-%5B2-%28pyridin-%28OCR%29.pdf Fasihuddin Badruddin, Ahmad and Md Abu, Affan and Dayang NA, Chee and Seik Weng, Ng and Edward R. T., Tiekink (2010) n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV). Acta Crystallographica Section E: Structure Reports Online, 66 (11). pp. 1412-1413. ISSN 1600-5368 http://journals.iucr.org/e/issues/2010/11/00/hb5679/hb5679.pdf
institution Universiti Malaysia Sarawak
building Centre for Academic Information Services (CAIS)
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Sarawak
content_source UNIMAS Institutional Repository
url_provider http://ir.unimas.my/
language English
English
topic QD Chemistry
spellingShingle QD Chemistry
Fasihuddin Badruddin, Ahmad
Md Abu, Affan
Dayang NA, Chee
Seik Weng, Ng
Edward R. T., Tiekink
n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV)
description Two independent molecules comprise the asymmetric unit of the title compound, [Sn(C4H9)(C13H12N3O)Cl2]. The Sn atom in each is coordinated by the tridentate ligand via the phenoxide O, hydrazine N and pyridyl N atoms, forming fiveand six-membered chelate rings. The approximately octahedral coordination geometry is completed by the -C atom of the n-butyl group (which is trans to the hydrazine N atom) and two mutually trans Cl atoms. Differences between the molecules are evident in the relative planarity of the chelate rings and in the conformations of the n-butyl groups [C—C—C—C = 177.2 (5) and 64.4 (11)]. Significant differences in the Sn—Cl bond lengths are related to the formation of N—H���Cl hydrogen bonds, which link the molecules comprising the asymmetric unit into dimeric aggregates. These are consolidated in the crystal packing by C—H���Cl contacts. The structure was refined as an inversion twin; the minor twin component is 37 (3)%.
format E-Article
author Fasihuddin Badruddin, Ahmad
Md Abu, Affan
Dayang NA, Chee
Seik Weng, Ng
Edward R. T., Tiekink
author_facet Fasihuddin Badruddin, Ahmad
Md Abu, Affan
Dayang NA, Chee
Seik Weng, Ng
Edward R. T., Tiekink
author_sort Fasihuddin Badruddin, Ahmad
title n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV)
title_short n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV)
title_full n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV)
title_fullStr n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV)
title_full_unstemmed n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV)
title_sort n-butyldichlorido (2-{(1e)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (iv)
publisher International Union of Crystallography
publishDate 2010
url http://ir.unimas.my/id/eprint/7358/1/n-Butyldichlorido%20%282-%7B%281E%29-1-%5B2-%28pyridin-2-yl%29%20hydrazin-1-ylidene%5D%20ethyl%7D%20phenolato%29%20tin%20%28IV%29%20%28abstract%29.pdf
http://ir.unimas.my/id/eprint/7358/2/n-Butyldichlorido%282-%7B%281E%29-1-%5B2-%28pyridin-%28OCR%29.pdf
http://ir.unimas.my/id/eprint/7358/
http://journals.iucr.org/e/issues/2010/11/00/hb5679/hb5679.pdf
_version_ 1644510265191956480
score 13.211869

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