n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV)
Two independent molecules comprise the asymmetric unit of the title compound, [Sn(C4H9)(C13H12N3O)Cl2]. The Sn atom in each is coordinated by the tridentate ligand via the phenoxide O, hydrazine N and pyridyl N atoms, forming fiveand six-membered chelate rings. The approximately octahedral coordi...
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| المؤلفون الرئيسيون: | , , , , |
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| التنسيق: | E-Article |
| اللغة: | English English |
| منشور في: |
International Union of Crystallography
2010
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| الموضوعات: | |
| الوصول للمادة أونلاين: | http://ir.unimas.my/id/eprint/7358/1/n-Butyldichlorido%20%282-%7B%281E%29-1-%5B2-%28pyridin-2-yl%29%20hydrazin-1-ylidene%5D%20ethyl%7D%20phenolato%29%20tin%20%28IV%29%20%28abstract%29.pdf http://ir.unimas.my/id/eprint/7358/2/n-Butyldichlorido%282-%7B%281E%29-1-%5B2-%28pyridin-%28OCR%29.pdf http://ir.unimas.my/id/eprint/7358/ http://journals.iucr.org/e/issues/2010/11/00/hb5679/hb5679.pdf |
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| الملخص: | Two independent molecules comprise the asymmetric unit of
the title compound, [Sn(C4H9)(C13H12N3O)Cl2]. The Sn atom
in each is coordinated by the tridentate ligand via the
phenoxide O, hydrazine N and pyridyl N atoms, forming fiveand six-membered chelate rings. The approximately octahedral coordination geometry is completed by the -C atom of the n-butyl group (which is trans to the hydrazine N atom) and two mutually trans Cl atoms. Differences between the molecules are evident in the relative planarity of the chelate rings and in the conformations of the n-butyl groups [C—C—C—C = 177.2 (5) and 64.4 (11)]. Significant differences in the Sn—Cl bond lengths are related to the formation of N—H���Cl hydrogen bonds, which link the molecules comprising the asymmetric unit into dimeric aggregates. These are consolidated in the crystal packing by C—H���Cl contacts. The structure was refined as an inversion twin; the minor twin component is 37 (3)%. |
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