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{4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate

Two independent diphenyl­tin mol­ecules and two independent methanol mol­ecules comprise the asymmetric unit of the title compound, [Sn(C6H5)2(C17H14N2O3)]·CH3OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents. The resulting C...

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Main Authors: Fasihuddin B, Ahmad, Md Abu, Affan, Norrihan B Sam, Sam, Fraser, White, Edward RT, Tiekink
Format: E-Article
Language:English
English
Published: International Union of Crystallography 2011
Subjects:
QD Chemistry
Online Access:http://ir.unimas.my/id/eprint/7357/1/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%28abstract%29.pdf
http://ir.unimas.my/id/eprint/7357/2/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%28OCR%29.pdf
http://ir.unimas.my/id/eprint/7357/
http://journals.iucr.org/e/issues/2011/07/00/hb5914/hb5914.pdf
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spelling my.unimas.ir.73572015-05-25T07:20:08Z http://ir.unimas.my/id/eprint/7357/ {4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate Fasihuddin B, Ahmad Md Abu, Affan Norrihan B Sam, Sam Fraser, White Edward RT, Tiekink QD Chemistry Two independent diphenyl­tin mol­ecules and two independent methanol mol­ecules comprise the asymmetric unit of the title compound, [Sn(C6H5)2(C17H14N2O3)]·CH3OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents. The resulting C2N2O donor set defines a coordination geometry that is inter­mediate between trigonal-bipyramidal (TP) and square-pyramidal (SP), with one mol­ecule slightly tending towards TP and the other slightly towards SP. The mol­ecules differ in terms of the relative orientations of the terminal benzene rings [dihedral angles = 45.71 (18) and 53.98 (17)°] and of the Sn-bound benzene substituents [dihedral angles = 59.5 (2) and 45.77 (18)°, respectively]. The most prominent feature of the crystal packing is the formation of four-mol­ecule aggregates via O-H...O and O-H...N hydrogen bonds, in which the hy­droxy group is connected to a methanol mol­ecule which, in turn, is linked to a non-coordinating N atom. Weak C-H...[pi] inter­actions also occur. International Union of Crystallography 2011 E-Article PeerReviewed text en http://ir.unimas.my/id/eprint/7357/1/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%28abstract%29.pdf text en http://ir.unimas.my/id/eprint/7357/2/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%28OCR%29.pdf Fasihuddin B, Ahmad and Md Abu, Affan and Norrihan B Sam, Sam and Fraser, White and Edward RT, Tiekink (2011) {4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate. Acta Crystallographica Section E: Structure Reports Online, 67 (7). m963-m964. ISSN 1600-5368 http://journals.iucr.org/e/issues/2011/07/00/hb5914/hb5914.pdf doi:10.1107/S1600536811023415
institution Universiti Malaysia Sarawak
building Centre for Academic Information Services (CAIS)
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Sarawak
content_source UNIMAS Institutional Repository
url_provider http://ir.unimas.my/
language English
English
topic QD Chemistry
spellingShingle QD Chemistry
Fasihuddin B, Ahmad
Md Abu, Affan
Norrihan B Sam, Sam
Fraser, White
Edward RT, Tiekink
{4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate
description Two independent diphenyl­tin mol­ecules and two independent methanol mol­ecules comprise the asymmetric unit of the title compound, [Sn(C6H5)2(C17H14N2O3)]·CH3OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents. The resulting C2N2O donor set defines a coordination geometry that is inter­mediate between trigonal-bipyramidal (TP) and square-pyramidal (SP), with one mol­ecule slightly tending towards TP and the other slightly towards SP. The mol­ecules differ in terms of the relative orientations of the terminal benzene rings [dihedral angles = 45.71 (18) and 53.98 (17)°] and of the Sn-bound benzene substituents [dihedral angles = 59.5 (2) and 45.77 (18)°, respectively]. The most prominent feature of the crystal packing is the formation of four-mol­ecule aggregates via O-H...O and O-H...N hydrogen bonds, in which the hy­droxy group is connected to a methanol mol­ecule which, in turn, is linked to a non-coordinating N atom. Weak C-H...[pi] inter­actions also occur.
format E-Article
author Fasihuddin B, Ahmad
Md Abu, Affan
Norrihan B Sam, Sam
Fraser, White
Edward RT, Tiekink
author_facet Fasihuddin B, Ahmad
Md Abu, Affan
Norrihan B Sam, Sam
Fraser, White
Edward RT, Tiekink
author_sort Fasihuddin B, Ahmad
title {4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate
title_short {4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate
title_full {4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate
title_fullStr {4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate
title_full_unstemmed {4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate
title_sort {4-hydroxy-n'-[(2e, 3z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (iv) methanol monosolvate
publisher International Union of Crystallography
publishDate 2011
url http://ir.unimas.my/id/eprint/7357/1/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%28abstract%29.pdf
http://ir.unimas.my/id/eprint/7357/2/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%28OCR%29.pdf
http://ir.unimas.my/id/eprint/7357/
http://journals.iucr.org/e/issues/2011/07/00/hb5914/hb5914.pdf
_version_ 1644510264899403776
score 13.211869

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