职员浏览: Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]

Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]

The reaction of 2-benzoylpyridine-N(4) cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) ha...

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Main Authors:	Md. Abu, Affan, M.A., Salam, Fasihuddin B., Ahmad, Ismail, Jusoh, Mustaffa B., Shamsuddin, Hapipah M., Ali
格式:	Article
语言:	English
出版:	Elsevier 2011
主题:	QK Botany SB Plant culture SD Forestry
在线阅读:	http://ir.unimas.my/id/eprint/7106/1/M.A.%20Affan.pdf http://ir.unimas.my/id/eprint/7106/
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id	my.unimas.ir.7106
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spelling	my.unimas.ir.71062022-03-22T07:03:06Z http://ir.unimas.my/id/eprint/7106/ Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)] Md. Abu, Affan M.A., Salam Fasihuddin B., Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Hapipah M., Ali QK Botany SB Plant culture SD Forestry The reaction of 2-benzoylpyridine-N(4) cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) have been synthesized and characterized by CHN analyses, molar conductivity, UV–Vis, FT-IR and 1 H NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) Å, b = 9.5970(2) Å,c = 9.4353(2) Å. Elsevier 2011 Article PeerReviewed text en http://ir.unimas.my/id/eprint/7106/1/M.A.%20Affan.pdf Md. Abu, Affan and M.A., Salam and Fasihuddin B., Ahmad and Ismail, Jusoh and Mustaffa B., Shamsuddin and Hapipah M., Ali (2011) Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]. Inorganica Chimica Acta, 366 (1). pp. 227-232. ISSN 0020-1693 doi:10.1016/j.ica.2010.11.002
institution	Universiti Malaysia Sarawak
building	Centre for Academic Information Services (CAIS)
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaysia Sarawak
content_source	UNIMAS Institutional Repository
url_provider	http://ir.unimas.my/
language	English
topic	QK Botany SB Plant culture SD Forestry
spellingShingle	QK Botany SB Plant culture SD Forestry Md. Abu, Affan M.A., Salam Fasihuddin B., Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Hapipah M., Ali Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
description	The reaction of 2-benzoylpyridine-N(4) cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) have been synthesized and characterized by CHN analyses, molar conductivity, UV–Vis, FT-IR and 1 H NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) Å, b = 9.5970(2) Å,c = 9.4353(2) Å.
format	Article
author	Md. Abu, Affan M.A., Salam Fasihuddin B., Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Hapipah M., Ali
author_facet	Md. Abu, Affan M.A., Salam Fasihuddin B., Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Hapipah M., Ali
author_sort	Md. Abu, Affan
title	Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
title_short	Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
title_full	Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
title_fullStr	Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
title_full_unstemmed	Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
title_sort	synthesis and spectroscopic characterization of organotin(iv) complexes with 2-benzoylpyridine-n(4)-cyclohexylthiosemicarbazone (hbpct): x-ray crystal structure of [phsncl2(bpct)]
publisher	Elsevier
publishDate	2011
url	http://ir.unimas.my/id/eprint/7106/1/M.A.%20Affan.pdf http://ir.unimas.my/id/eprint/7106/
_version_	1728055590582747136
score	13.251813

Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]

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