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Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]

The reaction of 2-benzoylpyridine-N(4) cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) ha...

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Main Authors: Md. Abu, Affan, M.A., Salam, Fasihuddin B., Ahmad, Ismail, Jusoh, Mustaffa B., Shamsuddin, Hapipah M., Ali
Format: Article
Language:English
Published: Elsevier 2011
Subjects:
QK Botany
SB Plant culture
SD Forestry
Online Access:http://ir.unimas.my/id/eprint/7106/1/M.A.%20Affan.pdf
http://ir.unimas.my/id/eprint/7106/
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spelling my.unimas.ir.71062022-03-22T07:03:06Z http://ir.unimas.my/id/eprint/7106/ Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)] Md. Abu, Affan M.A., Salam Fasihuddin B., Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Hapipah M., Ali QK Botany SB Plant culture SD Forestry The reaction of 2-benzoylpyridine-N(4) cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) have been synthesized and characterized by CHN analyses, molar conductivity, UV–Vis, FT-IR and 1 H NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) Å, b = 9.5970(2) Å,c = 9.4353(2) Å. Elsevier 2011 Article PeerReviewed text en http://ir.unimas.my/id/eprint/7106/1/M.A.%20Affan.pdf Md. Abu, Affan and M.A., Salam and Fasihuddin B., Ahmad and Ismail, Jusoh and Mustaffa B., Shamsuddin and Hapipah M., Ali (2011) Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]. Inorganica Chimica Acta, 366 (1). pp. 227-232. ISSN 0020-1693 doi:10.1016/j.ica.2010.11.002
institution Universiti Malaysia Sarawak
building Centre for Academic Information Services (CAIS)
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Sarawak
content_source UNIMAS Institutional Repository
url_provider http://ir.unimas.my/
language English
topic QK Botany
SB Plant culture
SD Forestry
spellingShingle QK Botany
SB Plant culture
SD Forestry
Md. Abu, Affan
M.A., Salam
Fasihuddin B., Ahmad
Ismail, Jusoh
Mustaffa B., Shamsuddin
Hapipah M., Ali
Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
description The reaction of 2-benzoylpyridine-N(4) cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) have been synthesized and characterized by CHN analyses, molar conductivity, UV–Vis, FT-IR and 1 H NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) Å, b = 9.5970(2) Å,c = 9.4353(2) Å.
format Article
author Md. Abu, Affan
M.A., Salam
Fasihuddin B., Ahmad
Ismail, Jusoh
Mustaffa B., Shamsuddin
Hapipah M., Ali
author_facet Md. Abu, Affan
M.A., Salam
Fasihuddin B., Ahmad
Ismail, Jusoh
Mustaffa B., Shamsuddin
Hapipah M., Ali
author_sort Md. Abu, Affan
title Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
title_short Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
title_full Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
title_fullStr Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
title_full_unstemmed Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
title_sort synthesis and spectroscopic characterization of organotin(iv) complexes with 2-benzoylpyridine-n(4)-cyclohexylthiosemicarbazone (hbpct): x-ray crystal structure of [phsncl2(bpct)]
publisher Elsevier
publishDate 2011
url http://ir.unimas.my/id/eprint/7106/1/M.A.%20Affan.pdf
http://ir.unimas.my/id/eprint/7106/
_version_ 1728055590582747136
score 13.250246

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