Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics

The influence of temperature on microstructural, structural and ferroelectric evolution properties of multiferroic holmium manganese oxide (HoMnO3) ceramics were investigated. HoMnO3 ceramics were synthesized using a mechanochemical reaction of Ho2O3 and Mn2O3 powders in a high energy ball milling m...

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Main Authors: A. N., Hapishah, R. S., Azis, M., Hashim, I., Ismayadi, J., Hassan, M. M., Syazwan, R. I., Idza
Format: Article
Language:English
Published: Springer Science+Business Media, LLC 2017
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Online Access:http://ir.unimas.my/id/eprint/32267/1/A%20N%20Hapishah.pdf
http://ir.unimas.my/id/eprint/32267/
https://link.springer.com/article/10.1007/s10854-017-7505-2
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spelling my.unimas.ir.322672021-06-21T14:19:29Z http://ir.unimas.my/id/eprint/32267/ Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics A. N., Hapishah R. S., Azis M., Hashim I., Ismayadi J., Hassan M. M., Syazwan R. I., Idza Q Science (General) The influence of temperature on microstructural, structural and ferroelectric evolution properties of multiferroic holmium manganese oxide (HoMnO3) ceramics were investigated. HoMnO3 ceramics were synthesized using a mechanochemical reaction of Ho2O3 and Mn2O3 powders in a high energy ball milling machine. The powder were sintered from 600 to 1250 °C with 50 °C increments. The results shows the microstructural, structural and ferroelectric hysteresis loop were observed to be dependent on sintering temperatures. The XRD characterization suggests an improvement of crystallinity with increasing sintering temperature. The hexagonal HoMnO3 were observed at temperature ≥1200 °C with the grain size of around 1600 nm. SEM micrographs showed larger grain size as the sintering temperature increased. The SEM results revealed a transformation of crystal structure occurs from orthorhombic to hexagonal at larger grain size regime. Polarization P—electric field E ferroelectric properties were observed to be enhanced with the increase of grain size through sintering temperature. The ferroelectric behavior was observed to change with the change of microstructure along with the structure transformation from orthorhombic to hexagonal. A complete systematic studies of the micron-nanometer grain size on microstructure-properties evolution of HoMnO3 multiferrroic ceramics is higlighted. Springer Science+Business Media, LLC 2017 Article PeerReviewed text en http://ir.unimas.my/id/eprint/32267/1/A%20N%20Hapishah.pdf A. N., Hapishah and R. S., Azis and M., Hashim and I., Ismayadi and J., Hassan and M. M., Syazwan and R. I., Idza (2017) Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics. Journal of Materials Science Materials in Electronics, 28. pp. 16053-16061. https://link.springer.com/article/10.1007/s10854-017-7505-2 10.1007/s10854-017-7505-2
institution Universiti Malaysia Sarawak
building Centre for Academic Information Services (CAIS)
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Sarawak
content_source UNIMAS Institutional Repository
url_provider http://ir.unimas.my/
language English
topic Q Science (General)
spellingShingle Q Science (General)
A. N., Hapishah
R. S., Azis
M., Hashim
I., Ismayadi
J., Hassan
M. M., Syazwan
R. I., Idza
Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics
description The influence of temperature on microstructural, structural and ferroelectric evolution properties of multiferroic holmium manganese oxide (HoMnO3) ceramics were investigated. HoMnO3 ceramics were synthesized using a mechanochemical reaction of Ho2O3 and Mn2O3 powders in a high energy ball milling machine. The powder were sintered from 600 to 1250 °C with 50 °C increments. The results shows the microstructural, structural and ferroelectric hysteresis loop were observed to be dependent on sintering temperatures. The XRD characterization suggests an improvement of crystallinity with increasing sintering temperature. The hexagonal HoMnO3 were observed at temperature ≥1200 °C with the grain size of around 1600 nm. SEM micrographs showed larger grain size as the sintering temperature increased. The SEM results revealed a transformation of crystal structure occurs from orthorhombic to hexagonal at larger grain size regime. Polarization P—electric field E ferroelectric properties were observed to be enhanced with the increase of grain size through sintering temperature. The ferroelectric behavior was observed to change with the change of microstructure along with the structure transformation from orthorhombic to hexagonal. A complete systematic studies of the micron-nanometer grain size on microstructure-properties evolution of HoMnO3 multiferrroic ceramics is higlighted.
format Article
author A. N., Hapishah
R. S., Azis
M., Hashim
I., Ismayadi
J., Hassan
M. M., Syazwan
R. I., Idza
author_facet A. N., Hapishah
R. S., Azis
M., Hashim
I., Ismayadi
J., Hassan
M. M., Syazwan
R. I., Idza
author_sort A. N., Hapishah
title Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics
title_short Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics
title_full Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics
title_fullStr Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics
title_full_unstemmed Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics
title_sort influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic homno3 ceramics
publisher Springer Science+Business Media, LLC
publishDate 2017
url http://ir.unimas.my/id/eprint/32267/1/A%20N%20Hapishah.pdf
http://ir.unimas.my/id/eprint/32267/
https://link.springer.com/article/10.1007/s10854-017-7505-2
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score 13.211869