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Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones

This paper evaluates the feasibility of using fusion waste chicken and fish bones as the reusable and low cost solid catalyst for synthesis of biodiesel from used cooking oil via two-step transesterification. A catalyst characterization of the prepared fusion waste chicken and fish bones catalyst wa...

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Main Authors:	Tan Y, Y.H, Abdullah, M.O., Kansedo, J., Mubarak, N.M., Chan, Y.S., Nolasco-Hipolito, C.
Format:	E-Article
Published:	Elsevier Ltd 2019
Subjects:	TA Engineering (General). Civil engineering (General)
Online Access:	http://ir.unimas.my/id/eprint/29656/ https://www.scopus.com/record/display.uri?eid=2-s2.0-85062734826&doi=10.1016%2fj.renene.2019.02.110&origin=inward&txGid=8671195a54c15f04047e430e63ea509e
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spelling	my.unimas.ir.296562020-06-04T08:00:01Z http://ir.unimas.my/id/eprint/29656/ Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones Tan Y, Y.H Abdullah, M.O. Kansedo, J. Mubarak, N.M. Chan, Y.S. Nolasco-Hipolito, C. TA Engineering (General). Civil engineering (General) This paper evaluates the feasibility of using fusion waste chicken and fish bones as the reusable and low cost solid catalyst for synthesis of biodiesel from used cooking oil via two-step transesterification. A catalyst characterization of the prepared fusion waste chicken and fish bones catalyst was made in order to study their catalytic performance through various techniques such as Scanning Electron Microscopy (SEM), Brunauer–Emmett–Teller (BET), Particle Size Analysis (PSA), Thermal Gravimetric Analysis (TGA), Fourier Transform Infrared spectra (FTIR), Carbon Dioxide-Temperature Programmed Desorption (TPD-CO2) and X-Ray Diffraction (XRD). The used cooking oil transesterification was optimized using a response surface methodology (RSM) based on five level three variables central composite design (CCD). The RSM results revealed that the optimal operational condition for the transesterification has defined as: catalyst loading, 1.98%w/v, reaction temperature, 65 °C and time, 1.54 h, whereas the alcohol/oil molar ratio, 10:1 is a fixed variable in this study. The actual biodiesel yield of 89.5% was achieved under the predicted optimal conditions and fulfilled the ASTM D6751 biodiesel fuel standards. The promising features of the chicken and fish bones catalyst are inexpensive, easily obtained, simple work-up, simple recovery, reusability without significant drop in catalytic activity for up to four consecutive runs. Elsevier Ltd 2019-08 E-Article PeerReviewed Tan Y, Y.H and Abdullah, M.O. and Kansedo, J. and Mubarak, N.M. and Chan, Y.S. and Nolasco-Hipolito, C. (2019) Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones. Renewable Energy, 139. pp. 696-706. ISSN 9601481 https://www.scopus.com/record/display.uri?eid=2-s2.0-85062734826&doi=10.1016%2fj.renene.2019.02.110&origin=inward&txGid=8671195a54c15f04047e430e63ea509e 10.1016/j.renene.2019.02.110
institution	Universiti Malaysia Sarawak
building	Centre for Academic Information Services (CAIS)
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaysia Sarawak
content_source	UNIMAS Institutional Repository
url_provider	http://ir.unimas.my/
topic	TA Engineering (General). Civil engineering (General)
spellingShingle	TA Engineering (General). Civil engineering (General) Tan Y, Y.H Abdullah, M.O. Kansedo, J. Mubarak, N.M. Chan, Y.S. Nolasco-Hipolito, C. Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones
description	This paper evaluates the feasibility of using fusion waste chicken and fish bones as the reusable and low cost solid catalyst for synthesis of biodiesel from used cooking oil via two-step transesterification. A catalyst characterization of the prepared fusion waste chicken and fish bones catalyst was made in order to study their catalytic performance through various techniques such as Scanning Electron Microscopy (SEM), Brunauer–Emmett–Teller (BET), Particle Size Analysis (PSA), Thermal Gravimetric Analysis (TGA), Fourier Transform Infrared spectra (FTIR), Carbon Dioxide-Temperature Programmed Desorption (TPD-CO2) and X-Ray Diffraction (XRD). The used cooking oil transesterification was optimized using a response surface methodology (RSM) based on five level three variables central composite design (CCD). The RSM results revealed that the optimal operational condition for the transesterification has defined as: catalyst loading, 1.98%w/v, reaction temperature, 65 °C and time, 1.54 h, whereas the alcohol/oil molar ratio, 10:1 is a fixed variable in this study. The actual biodiesel yield of 89.5% was achieved under the predicted optimal conditions and fulfilled the ASTM D6751 biodiesel fuel standards. The promising features of the chicken and fish bones catalyst are inexpensive, easily obtained, simple work-up, simple recovery, reusability without significant drop in catalytic activity for up to four consecutive runs.
format	E-Article
author	Tan Y, Y.H Abdullah, M.O. Kansedo, J. Mubarak, N.M. Chan, Y.S. Nolasco-Hipolito, C.
author_facet	Tan Y, Y.H Abdullah, M.O. Kansedo, J. Mubarak, N.M. Chan, Y.S. Nolasco-Hipolito, C.
author_sort	Tan Y, Y.H
title	Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones
title_short	Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones
title_full	Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones
title_fullStr	Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones
title_full_unstemmed	Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones
title_sort	biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones
publisher	Elsevier Ltd
publishDate	2019
url	http://ir.unimas.my/id/eprint/29656/ https://www.scopus.com/record/display.uri?eid=2-s2.0-85062734826&doi=10.1016%2fj.renene.2019.02.110&origin=inward&txGid=8671195a54c15f04047e430e63ea509e
_version_	1669010445535543296
score	13.211869

Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones

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