Cover Image

Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)]

The reaction of 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) hav...

Full description

Saved in:
Bibliographic Details
Main Authors: M.A., Affan, M.A., Salam, Fasihuddin Badruddin, Ahmad, Ismail, Jusoh, Mustaffa B., Shamsuddin, Hapipah M., Ali
Format: Article
Language:English
Published: Elsevier B.V. 2011
Subjects:
AC Collections. Series. Collected works
Online Access:http://ir.unimas.my/id/eprint/2370/1/Synthesis%20and%20spectroscopic.pdf
http://ir.unimas.my/id/eprint/2370/
http://www.sciencedirect.com/science/article/pii/S0020169310007425
Tags: Add Tag
No Tags, Be the first to tag this record!
id my.unimas.ir.2370
record_format eprints
spelling my.unimas.ir.23702023-03-29T03:27:56Z http://ir.unimas.my/id/eprint/2370/ Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)] M.A., Affan M.A., Salam Fasihuddin Badruddin, Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Hapipah M., Ali AC Collections. Series. Collected works The reaction of 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) have been synthesized and characterized by CHN analyses, molar conductivity, UV–Vis, FT-IR and 1H NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) Å, b = 9.5970(2) Å, c = 9.4353(2) Å. Elsevier B.V. 2011 Article NonPeerReviewed text en http://ir.unimas.my/id/eprint/2370/1/Synthesis%20and%20spectroscopic.pdf M.A., Affan and M.A., Salam and Fasihuddin Badruddin, Ahmad and Ismail, Jusoh and Mustaffa B., Shamsuddin and Hapipah M., Ali (2011) Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)]. Inorganica Chimica Acta Pages 227–232, 366 (1). pp. 277-232. ISSN 0020-1693 http://www.sciencedirect.com/science/article/pii/S0020169310007425 doi:10.1016/j.ica.2010.11.002
institution Universiti Malaysia Sarawak
building Centre for Academic Information Services (CAIS)
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Sarawak
content_source UNIMAS Institutional Repository
url_provider http://ir.unimas.my/
language English
topic AC Collections. Series. Collected works
spellingShingle AC Collections. Series. Collected works
M.A., Affan
M.A., Salam
Fasihuddin Badruddin, Ahmad
Ismail, Jusoh
Mustaffa B., Shamsuddin
Hapipah M., Ali
Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)]
description The reaction of 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) have been synthesized and characterized by CHN analyses, molar conductivity, UV–Vis, FT-IR and 1H NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) Å, b = 9.5970(2) Å, c = 9.4353(2) Å.
format Article
author M.A., Affan
M.A., Salam
Fasihuddin Badruddin, Ahmad
Ismail, Jusoh
Mustaffa B., Shamsuddin
Hapipah M., Ali
author_facet M.A., Affan
M.A., Salam
Fasihuddin Badruddin, Ahmad
Ismail, Jusoh
Mustaffa B., Shamsuddin
Hapipah M., Ali
author_sort M.A., Affan
title Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)]
title_short Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)]
title_full Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)]
title_fullStr Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)]
title_full_unstemmed Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)]
title_sort synthesis and spectroscopiccharacterization of organotin(iv) complexes with 2-benzoylpyridine-n(4)-cyclohexylthiosemicarbazone (hbpct) : x-ray crystal structure of [phsncl2(bpct)]
publisher Elsevier B.V.
publishDate 2011
url http://ir.unimas.my/id/eprint/2370/1/Synthesis%20and%20spectroscopic.pdf
http://ir.unimas.my/id/eprint/2370/
http://www.sciencedirect.com/science/article/pii/S0020169310007425
_version_ 1761675228219441152
score 13.211869

Similar Items