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Characterization and properties of calcium carbonate filled polypropylene (PP) / ethylene propylene diene terpolymer (EPDM) composites

Composites of thermoplastic elastomer blend of polypropylene (PP) and ethylene propylene diene terpolymer (EPDM) reinforced calcium carbonate (CaCO3) was investigated. All the composites were prepared by using Z-blade mixer at 180oC and rotor speed 50 rpm. The effect of filler loading of calcium...

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Main Author:	Siti Rohana, Ahmad
Format:	Thesis
Language:	English
Published:	Universiti Malaysia Perlis 2010
Subjects:	Ethylene propylene diene terpolymer (EPDM) Polypropylene (PP) Polymer Calcium carbonate (CaCO3) Dynamic vulcanization (DV) composites Composite materials
Online Access:	http://dspace.unimap.edu.my/xmlui/handle/123456789/9884
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spelling	my.unimap-98842010-10-19T04:05:12Z Characterization and properties of calcium carbonate filled polypropylene (PP) / ethylene propylene diene terpolymer (EPDM) composites Siti Rohana, Ahmad Ethylene propylene diene terpolymer (EPDM) Polypropylene (PP) Polymer Calcium carbonate (CaCO3) Dynamic vulcanization (DV) composites Composite materials Composites of thermoplastic elastomer blend of polypropylene (PP) and ethylene propylene diene terpolymer (EPDM) reinforced calcium carbonate (CaCO3) was investigated. All the composites were prepared by using Z-blade mixer at 180oC and rotor speed 50 rpm. The effect of filler loading of calcium carbonate filled PP/EPDM composites on mechanical properties, water absorption, morphology and thermal properties were studied. In general, increased of calcium carbonate loading have increased the value of modulus of elasticity, water absorption, thermal stability, whereas tensile strength, elongation at break and crystallinity of composites reduced. A compatibilizer, (MAPP) or coupling agent, (3-APE) was used to improve the mechanical properties of composites. The presence of MAPP or 3-APE improved the tensile strength, modulus of elasticity, thermal stability and crystallinity composites, whereas elongation at break and water absorption reduced. Results from scanning electron microscope (SEM) show that fillermatrix interaction was improved with incorporation of MAPP or 3-APE. The effect chemical modification of calcium carbonate with acrylic acid (AA) in PP/EPDM composites increased the tensile strength, elongation at break, modulus of elasticity, thermal stability and crystallinity composite but water absorption reduced. The micrograph SEM showed the treated composites with acrylic acid has better dispersion in PP/EPDM matrix. Effects of dynamic vulcanization on the properties of PP/EPDM/CaCO3 composites exhibit higher tensile strength, elongation at break and modulus of elasticity but lower water absorption. The SEM study of tensile fracture surface of dynamic vulcanized composites show interfacial interaction between calcium carbonate and PP/EPDM matrix has been improved. The dynamic vulcanized composites also exhibit better thermal stability and higher crystallinity. 2010-10-19T04:05:12Z 2010-10-19T04:05:12Z 2009 Thesis http://hdl.handle.net/123456789/9884 en Universiti Malaysia Perlis School of Materials Engineering
institution	Universiti Malaysia Perlis
building	UniMAP Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaysia Perlis
content_source	UniMAP Library Digital Repository
url_provider	http://dspace.unimap.edu.my/
language	English
topic	Ethylene propylene diene terpolymer (EPDM) Polypropylene (PP) Polymer Calcium carbonate (CaCO3) Dynamic vulcanization (DV) composites Composite materials
spellingShingle	Ethylene propylene diene terpolymer (EPDM) Polypropylene (PP) Polymer Calcium carbonate (CaCO3) Dynamic vulcanization (DV) composites Composite materials Siti Rohana, Ahmad Characterization and properties of calcium carbonate filled polypropylene (PP) / ethylene propylene diene terpolymer (EPDM) composites
description	Composites of thermoplastic elastomer blend of polypropylene (PP) and ethylene propylene diene terpolymer (EPDM) reinforced calcium carbonate (CaCO3) was investigated. All the composites were prepared by using Z-blade mixer at 180oC and rotor speed 50 rpm. The effect of filler loading of calcium carbonate filled PP/EPDM composites on mechanical properties, water absorption, morphology and thermal properties were studied. In general, increased of calcium carbonate loading have increased the value of modulus of elasticity, water absorption, thermal stability, whereas tensile strength, elongation at break and crystallinity of composites reduced. A compatibilizer, (MAPP) or coupling agent, (3-APE) was used to improve the mechanical properties of composites. The presence of MAPP or 3-APE improved the tensile strength, modulus of elasticity, thermal stability and crystallinity composites, whereas elongation at break and water absorption reduced. Results from scanning electron microscope (SEM) show that fillermatrix interaction was improved with incorporation of MAPP or 3-APE. The effect chemical modification of calcium carbonate with acrylic acid (AA) in PP/EPDM composites increased the tensile strength, elongation at break, modulus of elasticity, thermal stability and crystallinity composite but water absorption reduced. The micrograph SEM showed the treated composites with acrylic acid has better dispersion in PP/EPDM matrix. Effects of dynamic vulcanization on the properties of PP/EPDM/CaCO3 composites exhibit higher tensile strength, elongation at break and modulus of elasticity but lower water absorption. The SEM study of tensile fracture surface of dynamic vulcanized composites show interfacial interaction between calcium carbonate and PP/EPDM matrix has been improved. The dynamic vulcanized composites also exhibit better thermal stability and higher crystallinity.
format	Thesis
author	Siti Rohana, Ahmad
author_facet	Siti Rohana, Ahmad
author_sort	Siti Rohana, Ahmad
title	Characterization and properties of calcium carbonate filled polypropylene (PP) / ethylene propylene diene terpolymer (EPDM) composites
title_short	Characterization and properties of calcium carbonate filled polypropylene (PP) / ethylene propylene diene terpolymer (EPDM) composites
title_full	Characterization and properties of calcium carbonate filled polypropylene (PP) / ethylene propylene diene terpolymer (EPDM) composites
title_fullStr	Characterization and properties of calcium carbonate filled polypropylene (PP) / ethylene propylene diene terpolymer (EPDM) composites
title_full_unstemmed	Characterization and properties of calcium carbonate filled polypropylene (PP) / ethylene propylene diene terpolymer (EPDM) composites
title_sort	characterization and properties of calcium carbonate filled polypropylene (pp) / ethylene propylene diene terpolymer (epdm) composites
publisher	Universiti Malaysia Perlis
publishDate	2010
url	http://dspace.unimap.edu.my/xmlui/handle/123456789/9884
_version_	1643789611573444608
score	13.222552

Characterization and properties of calcium carbonate filled polypropylene (PP) / ethylene propylene diene terpolymer (EPDM) composites

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