Continuous adsorption of cationic dye (Basic Red 46): Kinetic and equilibrium studies

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Main Author: Liew, Kelly Kar Mee
Other Authors: Hairul Nazirah Abd Halim (Advisor)
Format: Learning Object
Language:English
Published: Universiti Malaysia Perlis 2011
Subjects:
Online Access:http://dspace.unimap.edu.my/xmlui/handle/123456789/13360
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spelling my.unimap-133602011-08-01T02:31:54Z Continuous adsorption of cationic dye (Basic Red 46): Kinetic and equilibrium studies Liew, Kelly Kar Mee Hairul Nazirah Abd Halim (Advisor) Basic Red (BR 46) Cationic dye Activated carbon Dye industries Textile industries Industrial wastes Access is limited to UniMAP community. A continuous fixed bed study was carried out to evaluate the adsorption of Basic Red (BR 46) on activated carbon as a function of bed height (20-100 mm), influent flow rate (30-90 mL/min), initial pH (pH 3-10) and influent concentration (50-250 mg/L). The results show that optimum adsorption occurs at pH 8 and bed height of 100 mm. Comprehensive breakthrough curve analysis was carried out to determine the effect of parameters on breakthrough time of the process. Results show that the breakthrough time increased with increasing bed height but decreased with the increase in influent concentration and flow rate. The experimental data was fitted to Langmuir and Freundlich isotherm models and was found to fit Freundlich isotherm model (R2=0.988), indicating heterogenous surface adsorption. The pseudo-first order and pseudo-second order kinetic models were applied to data collected to determine the characteristic parameters that are useful for process design of the column. The kinetic data was well fitted into the pseudo-second order kinetic model with an R2 value of 0.961. The results from the mathematical model were in good agreement with the experimental results, indicating the accuracy of the model in predicting column design. 2011-08-01T02:31:54Z 2011-08-01T02:31:54Z 2011-05 Learning Object http://hdl.handle.net/123456789/13360 en Universiti Malaysia Perlis School of Bioprocess Engineering
institution Universiti Malaysia Perlis
building UniMAP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Perlis
content_source UniMAP Library Digital Repository
url_provider http://dspace.unimap.edu.my/
language English
topic Basic Red (BR 46)
Cationic dye
Activated carbon
Dye industries
Textile industries
Industrial wastes
spellingShingle Basic Red (BR 46)
Cationic dye
Activated carbon
Dye industries
Textile industries
Industrial wastes
Liew, Kelly Kar Mee
Continuous adsorption of cationic dye (Basic Red 46): Kinetic and equilibrium studies
description Access is limited to UniMAP community.
author2 Hairul Nazirah Abd Halim (Advisor)
author_facet Hairul Nazirah Abd Halim (Advisor)
Liew, Kelly Kar Mee
format Learning Object
author Liew, Kelly Kar Mee
author_sort Liew, Kelly Kar Mee
title Continuous adsorption of cationic dye (Basic Red 46): Kinetic and equilibrium studies
title_short Continuous adsorption of cationic dye (Basic Red 46): Kinetic and equilibrium studies
title_full Continuous adsorption of cationic dye (Basic Red 46): Kinetic and equilibrium studies
title_fullStr Continuous adsorption of cationic dye (Basic Red 46): Kinetic and equilibrium studies
title_full_unstemmed Continuous adsorption of cationic dye (Basic Red 46): Kinetic and equilibrium studies
title_sort continuous adsorption of cationic dye (basic red 46): kinetic and equilibrium studies
publisher Universiti Malaysia Perlis
publishDate 2011
url http://dspace.unimap.edu.my/xmlui/handle/123456789/13360
_version_ 1643790818223325184
score 13.222552