The effects of electron beam irradiation on the thermal properties, fatigue life and natural weathering of styrene butadiene rubber/recycled acrylonitrile–butadiene rubber blends

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Main Authors: N. Z., Noriman, H., Ismail
Other Authors: nznriman@yahoo.com
Format: Article
Language:English
Published: Elsevier Ltd. 2011
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Online Access:http://dspace.unimap.edu.my/xmlui/handle/123456789/12164
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spelling my.unimap-121642011-05-31T03:50:05Z The effects of electron beam irradiation on the thermal properties, fatigue life and natural weathering of styrene butadiene rubber/recycled acrylonitrile–butadiene rubber blends N. Z., Noriman H., Ismail nznriman@yahoo.com hanafi@eng.usm.my Irradiation Thermal properties Fatigue Natural weathering Styrene Butadiene rubber Acrylonitrile butadiene rubber Link to publisher's homepage at www.elsevier.com/ The effects of electron beam (EB) irradiation on the thermal properties, fatigue life and natural weathering of styrene butadiene rubber/recycled acrylonitrile–butadiene rubber (SBR/NBRr) blends were investigated. The SBR/NBRr blends were prepared at 95/5, 85/15, 75/25, 65/35, or 50/50 blend ratios with and without the presence of a 3 part per hundred rubber (phr) of polyfunctional monomer, trimethylolpropane triacrylate (TMPTA). Results indicate that the crystallisation temperature (Tc) observed in polymeric blends is due to the alignment of polymer chains forming a semi-crystalline phase. Addition of TMPTA helps to align polymer chains through crosslinking. More crosslinking occurred between polymer blends with the help of TMPTA, upon irradiation. The improvement in fatigue life can also be associated with the stabilisation of SBR/NBRr blends upon irradiation and irradiation-induced crosslinking, which was accomplished with relatively low radiation-induced oxidative degradation in the presence of TMPTA. The tensile properties of both blends decreased over the periods of environmental exposure due to the effect of polymer degradation. After 6 months, the irradiated SBR/NBRr blends could not retain better retention [mainly with 25, 35 or 50 phr of recycled acrylonitrile–butadiene rubber (NBRr) particles] due to the samples becoming brittle over the long period of outdoor exposure. 2011-05-31T03:50:05Z 2011-05-31T03:50:05Z 2011-06 Article Materials and Design, vol. 32(6) , 2011, pages 3336-3346 3336–3346 http://www.sciencedirect.com/science/article/pii/S0261306911000987 http://hdl.handle.net/123456789/12164 en Elsevier Ltd.
institution Universiti Malaysia Perlis
building UniMAP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Perlis
content_source UniMAP Library Digital Repository
url_provider http://dspace.unimap.edu.my/
language English
topic Irradiation
Thermal properties
Fatigue
Natural weathering
Styrene
Butadiene rubber
Acrylonitrile butadiene rubber
spellingShingle Irradiation
Thermal properties
Fatigue
Natural weathering
Styrene
Butadiene rubber
Acrylonitrile butadiene rubber
N. Z., Noriman
H., Ismail
The effects of electron beam irradiation on the thermal properties, fatigue life and natural weathering of styrene butadiene rubber/recycled acrylonitrile–butadiene rubber blends
description Link to publisher's homepage at www.elsevier.com/
author2 nznriman@yahoo.com
author_facet nznriman@yahoo.com
N. Z., Noriman
H., Ismail
format Article
author N. Z., Noriman
H., Ismail
author_sort N. Z., Noriman
title The effects of electron beam irradiation on the thermal properties, fatigue life and natural weathering of styrene butadiene rubber/recycled acrylonitrile–butadiene rubber blends
title_short The effects of electron beam irradiation on the thermal properties, fatigue life and natural weathering of styrene butadiene rubber/recycled acrylonitrile–butadiene rubber blends
title_full The effects of electron beam irradiation on the thermal properties, fatigue life and natural weathering of styrene butadiene rubber/recycled acrylonitrile–butadiene rubber blends
title_fullStr The effects of electron beam irradiation on the thermal properties, fatigue life and natural weathering of styrene butadiene rubber/recycled acrylonitrile–butadiene rubber blends
title_full_unstemmed The effects of electron beam irradiation on the thermal properties, fatigue life and natural weathering of styrene butadiene rubber/recycled acrylonitrile–butadiene rubber blends
title_sort effects of electron beam irradiation on the thermal properties, fatigue life and natural weathering of styrene butadiene rubber/recycled acrylonitrile–butadiene rubber blends
publisher Elsevier Ltd.
publishDate 2011
url http://dspace.unimap.edu.my/xmlui/handle/123456789/12164
_version_ 1643790332050014208
score 13.222552