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Effectiveness of ozonation with zirconium and tin tetrachloride for stabilized anaerobic landfill leachate treatment

Landfill leachate can threaten the environment and human life. Therefore, this study aims to investigate the efficiency of ozone (O3), O3 with zirconium tetrachloride (O3/ZrCl4), and O3 with tin tetrachloride (O3/SnCl4) in remediating the stabilized anaerobic landfill leachate (SAL) from Alor Pongsu...

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Main Authors: Siti Nor Farhana Zakaria, Hamidi Abdul Aziz, Motasem Y. D. Alazaiza
Format: Article
Language:English
English
Published: John Wiley & Sons, Inc 2021
Subjects:
QD1-999 Chemistry
TD783-812.5 Municipal refuse. Solid wastes
Online Access:https://eprints.ums.edu.my/id/eprint/33664/1/Effectiveness%20of%20ozonation%20with%20zirconium%20and%20tin%20tetrachloride%20for%20stabilised%20anaerobic%20landfill%20leachate%20treatment.ABSTRACT.pdf
https://eprints.ums.edu.my/id/eprint/33664/3/Effectiveness%20of%20ozonation%20with%20zirconium%20and%20tin%20tetrachloride%20for%20stabilized%20anaerobic%20landfill%20leachate%20treatment.pdf
https://eprints.ums.edu.my/id/eprint/33664/
https://onlinelibrary.wiley.com/doi/epdf/10.1002/wer.1672
https://doi-org.ezproxy.ums.edu.my/10.1002/wer.1672
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spelling my.ums.eprints.336642022-09-02T15:11:50Z https://eprints.ums.edu.my/id/eprint/33664/ Effectiveness of ozonation with zirconium and tin tetrachloride for stabilized anaerobic landfill leachate treatment Siti Nor Farhana Zakaria Hamidi Abdul Aziz Motasem Y. D. Alazaiza QD1-999 Chemistry TD783-812.5 Municipal refuse. Solid wastes Landfill leachate can threaten the environment and human life. Therefore, this study aims to investigate the efficiency of ozone (O3), O3 with zirconium tetrachloride (O3/ZrCl4), and O3 with tin tetrachloride (O3/SnCl4) in remediating the stabilized anaerobic landfill leachate (SAL) from Alor Pongsu, Perak. Hydroxyl radical (OH•) is an important oxidizing agent in the ozonation process. Its presence was tested using tert-butyl alcohol. Results showed that using ZrCl4 and SnCl4 in ozonation boosted the generation of hydroxyl radical, thereby enhancing the oxidation process and pollutant removal inside the sample. The O3/ZrCl4 mix at chemical oxygen demand (COD) to ZrCl4 ratio of 1:1.5, pH 8–9, and 90-min reaction time resulted in the highest reduction rates of COD and color at 91.9% and 99.6%, respectively. All results demonstrated that the optimum performance occurred at alkaline conditions (pH > 8), proving that OH radicals primarily oxidized the pollutants through an indirect reaction pathway. The biodegradability (biochemical oxygen demand/COD) ratio was also considerably improved from 0.02 (raw) to 0.37 using O3/ZrCl4, compared with using O3 alone and using O3/SnCl4, which only recorded 0.23 and 0.28, respectively, after the treatment. The study demonstrated that O3/ZrCl4 was the most efficient combination. John Wiley & Sons, Inc 2021-12-03 Article PeerReviewed text en https://eprints.ums.edu.my/id/eprint/33664/1/Effectiveness%20of%20ozonation%20with%20zirconium%20and%20tin%20tetrachloride%20for%20stabilised%20anaerobic%20landfill%20leachate%20treatment.ABSTRACT.pdf text en https://eprints.ums.edu.my/id/eprint/33664/3/Effectiveness%20of%20ozonation%20with%20zirconium%20and%20tin%20tetrachloride%20for%20stabilized%20anaerobic%20landfill%20leachate%20treatment.pdf Siti Nor Farhana Zakaria and Hamidi Abdul Aziz and Motasem Y. D. Alazaiza (2021) Effectiveness of ozonation with zirconium and tin tetrachloride for stabilized anaerobic landfill leachate treatment. Water Environment Federation, 94. pp. 1-14. ISSN 1554-7531 https://onlinelibrary.wiley.com/doi/epdf/10.1002/wer.1672 https://doi-org.ezproxy.ums.edu.my/10.1002/wer.1672
institution Universiti Malaysia Sabah
building UMS Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Sabah
content_source UMS Institutional Repository
url_provider http://eprints.ums.edu.my/
language English
English
topic QD1-999 Chemistry
TD783-812.5 Municipal refuse. Solid wastes
spellingShingle QD1-999 Chemistry
TD783-812.5 Municipal refuse. Solid wastes
Siti Nor Farhana Zakaria
Hamidi Abdul Aziz
Motasem Y. D. Alazaiza
Effectiveness of ozonation with zirconium and tin tetrachloride for stabilized anaerobic landfill leachate treatment
description Landfill leachate can threaten the environment and human life. Therefore, this study aims to investigate the efficiency of ozone (O3), O3 with zirconium tetrachloride (O3/ZrCl4), and O3 with tin tetrachloride (O3/SnCl4) in remediating the stabilized anaerobic landfill leachate (SAL) from Alor Pongsu, Perak. Hydroxyl radical (OH•) is an important oxidizing agent in the ozonation process. Its presence was tested using tert-butyl alcohol. Results showed that using ZrCl4 and SnCl4 in ozonation boosted the generation of hydroxyl radical, thereby enhancing the oxidation process and pollutant removal inside the sample. The O3/ZrCl4 mix at chemical oxygen demand (COD) to ZrCl4 ratio of 1:1.5, pH 8–9, and 90-min reaction time resulted in the highest reduction rates of COD and color at 91.9% and 99.6%, respectively. All results demonstrated that the optimum performance occurred at alkaline conditions (pH > 8), proving that OH radicals primarily oxidized the pollutants through an indirect reaction pathway. The biodegradability (biochemical oxygen demand/COD) ratio was also considerably improved from 0.02 (raw) to 0.37 using O3/ZrCl4, compared with using O3 alone and using O3/SnCl4, which only recorded 0.23 and 0.28, respectively, after the treatment. The study demonstrated that O3/ZrCl4 was the most efficient combination.
format Article
author Siti Nor Farhana Zakaria
Hamidi Abdul Aziz
Motasem Y. D. Alazaiza
author_facet Siti Nor Farhana Zakaria
Hamidi Abdul Aziz
Motasem Y. D. Alazaiza
author_sort Siti Nor Farhana Zakaria
title Effectiveness of ozonation with zirconium and tin tetrachloride for stabilized anaerobic landfill leachate treatment
title_short Effectiveness of ozonation with zirconium and tin tetrachloride for stabilized anaerobic landfill leachate treatment
title_full Effectiveness of ozonation with zirconium and tin tetrachloride for stabilized anaerobic landfill leachate treatment
title_fullStr Effectiveness of ozonation with zirconium and tin tetrachloride for stabilized anaerobic landfill leachate treatment
title_full_unstemmed Effectiveness of ozonation with zirconium and tin tetrachloride for stabilized anaerobic landfill leachate treatment
title_sort effectiveness of ozonation with zirconium and tin tetrachloride for stabilized anaerobic landfill leachate treatment
publisher John Wiley & Sons, Inc
publishDate 2021
url https://eprints.ums.edu.my/id/eprint/33664/1/Effectiveness%20of%20ozonation%20with%20zirconium%20and%20tin%20tetrachloride%20for%20stabilised%20anaerobic%20landfill%20leachate%20treatment.ABSTRACT.pdf
https://eprints.ums.edu.my/id/eprint/33664/3/Effectiveness%20of%20ozonation%20with%20zirconium%20and%20tin%20tetrachloride%20for%20stabilized%20anaerobic%20landfill%20leachate%20treatment.pdf
https://eprints.ums.edu.my/id/eprint/33664/
https://onlinelibrary.wiley.com/doi/epdf/10.1002/wer.1672
https://doi-org.ezproxy.ums.edu.my/10.1002/wer.1672
_version_ 1760231192776409088
score 13.211869

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