Improvement of Properties and Performances of Polyether sulfone Ultrafiltration Membrane by Blending with Bio-Based Dragonbloodin Resin

Polyethersulfone (PES) is the most commonly used polymer for membrane ultrafiltration because of its superior properties. However, it is hydrophobic, as such susceptible to fouling and low permeation rate. This study proposes a novel bio-based additive of dragonbloodin resin (DBR) for improving the...

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Main Authors: Aulia Chintia Ambarita, Sri Mulyati, Nasrul Arahman, Muhammad Roil Bilad, Norazanita Shamsuddin, Noor Maizura Ismail
Format: Article
Language:English
English
Published: MDPI 2021
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Online Access:https://eprints.ums.edu.my/id/eprint/32189/1/Improvement%20of%20Properties%20and%20Performances%20of%20Polyethersulfone%20Ultrafiltration%20Membrane%20by%20Blending%20with%20Bio-Based%20Dragonbloodin%20Resin.pdf
https://eprints.ums.edu.my/id/eprint/32189/2/Improvement%20of%20Properties%20and%20Performances%20of%20Polyethersulfone%20Ultrafiltration%20Membrane%20by%20Blending%20with%20Bio-Based%20Dragonbloodin%20Resin1.pdf
https://eprints.ums.edu.my/id/eprint/32189/
https://www.mdpi.com/2073-4360/13/24/4436
https://doi.org/10.3390/polym13244436
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spelling my.ums.eprints.321892022-04-01T07:44:03Z https://eprints.ums.edu.my/id/eprint/32189/ Improvement of Properties and Performances of Polyether sulfone Ultrafiltration Membrane by Blending with Bio-Based Dragonbloodin Resin Aulia Chintia Ambarita Sri Mulyati Nasrul Arahman Muhammad Roil Bilad Norazanita Shamsuddin Noor Maizura Ismail TA1-2040 Engineering (General). Civil engineering (General) TP1-1185 Chemical technology Polyethersulfone (PES) is the most commonly used polymer for membrane ultrafiltration because of its superior properties. However, it is hydrophobic, as such susceptible to fouling and low permeation rate. This study proposes a novel bio-based additive of dragonbloodin resin (DBR) for improving the properties and performance of PES-based membranes. Four flat sheet membranes were prepared by varying the concentration of DBR (0–3%) in the dope solutions using the phase inversion method. After fabrication, the membranes were thoroughly characterized and were tested for filtration of humic acid solution to investigate the effect of DBR loading. Results showed that the hydrophilicity, porosity, and water uptake increased along with the DBR loadings. The presence of DBR in the dope solution fastened the phase inversion, leading to a more porous microstructure, resulted in membranes with higher number and larger pore sizes. Those properties led to more superior hydraulic performances. The PES membranes loaded with DBR reached a clean water flux of 246.79 L/(m2 ·h), 25-folds higher than the pristine PES membrane at a loading of 3%. The flux of humic acid solution reached 154.5 ± 6.6 L/(m2 ·h), 30-folds higher than the pristine PES membrane with a slight decrease in rejection (71% vs. 60%). Moreover, DBR loaded membranes (2% and 3%) showed an almost complete flux recovery ratio over five cleaning cycles, demonstrating their excellent antifouling property. The hydraulic performance could possibly be enhanced by leaching the entrapped DBR to create more voids and pores for water permeation. MDPI 2021 Article PeerReviewed text en https://eprints.ums.edu.my/id/eprint/32189/1/Improvement%20of%20Properties%20and%20Performances%20of%20Polyethersulfone%20Ultrafiltration%20Membrane%20by%20Blending%20with%20Bio-Based%20Dragonbloodin%20Resin.pdf text en https://eprints.ums.edu.my/id/eprint/32189/2/Improvement%20of%20Properties%20and%20Performances%20of%20Polyethersulfone%20Ultrafiltration%20Membrane%20by%20Blending%20with%20Bio-Based%20Dragonbloodin%20Resin1.pdf Aulia Chintia Ambarita and Sri Mulyati and Nasrul Arahman and Muhammad Roil Bilad and Norazanita Shamsuddin and Noor Maizura Ismail (2021) Improvement of Properties and Performances of Polyether sulfone Ultrafiltration Membrane by Blending with Bio-Based Dragonbloodin Resin. Polymers, 13. pp. 1-13. ISSN 2073-4360 https://www.mdpi.com/2073-4360/13/24/4436 https://doi.org/10.3390/polym13244436
institution Universiti Malaysia Sabah
building UMS Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Sabah
content_source UMS Institutional Repository
url_provider http://eprints.ums.edu.my/
language English
English
topic TA1-2040 Engineering (General). Civil engineering (General)
TP1-1185 Chemical technology
spellingShingle TA1-2040 Engineering (General). Civil engineering (General)
TP1-1185 Chemical technology
Aulia Chintia Ambarita
Sri Mulyati
Nasrul Arahman
Muhammad Roil Bilad
Norazanita Shamsuddin
Noor Maizura Ismail
Improvement of Properties and Performances of Polyether sulfone Ultrafiltration Membrane by Blending with Bio-Based Dragonbloodin Resin
description Polyethersulfone (PES) is the most commonly used polymer for membrane ultrafiltration because of its superior properties. However, it is hydrophobic, as such susceptible to fouling and low permeation rate. This study proposes a novel bio-based additive of dragonbloodin resin (DBR) for improving the properties and performance of PES-based membranes. Four flat sheet membranes were prepared by varying the concentration of DBR (0–3%) in the dope solutions using the phase inversion method. After fabrication, the membranes were thoroughly characterized and were tested for filtration of humic acid solution to investigate the effect of DBR loading. Results showed that the hydrophilicity, porosity, and water uptake increased along with the DBR loadings. The presence of DBR in the dope solution fastened the phase inversion, leading to a more porous microstructure, resulted in membranes with higher number and larger pore sizes. Those properties led to more superior hydraulic performances. The PES membranes loaded with DBR reached a clean water flux of 246.79 L/(m2 ·h), 25-folds higher than the pristine PES membrane at a loading of 3%. The flux of humic acid solution reached 154.5 ± 6.6 L/(m2 ·h), 30-folds higher than the pristine PES membrane with a slight decrease in rejection (71% vs. 60%). Moreover, DBR loaded membranes (2% and 3%) showed an almost complete flux recovery ratio over five cleaning cycles, demonstrating their excellent antifouling property. The hydraulic performance could possibly be enhanced by leaching the entrapped DBR to create more voids and pores for water permeation.
format Article
author Aulia Chintia Ambarita
Sri Mulyati
Nasrul Arahman
Muhammad Roil Bilad
Norazanita Shamsuddin
Noor Maizura Ismail
author_facet Aulia Chintia Ambarita
Sri Mulyati
Nasrul Arahman
Muhammad Roil Bilad
Norazanita Shamsuddin
Noor Maizura Ismail
author_sort Aulia Chintia Ambarita
title Improvement of Properties and Performances of Polyether sulfone Ultrafiltration Membrane by Blending with Bio-Based Dragonbloodin Resin
title_short Improvement of Properties and Performances of Polyether sulfone Ultrafiltration Membrane by Blending with Bio-Based Dragonbloodin Resin
title_full Improvement of Properties and Performances of Polyether sulfone Ultrafiltration Membrane by Blending with Bio-Based Dragonbloodin Resin
title_fullStr Improvement of Properties and Performances of Polyether sulfone Ultrafiltration Membrane by Blending with Bio-Based Dragonbloodin Resin
title_full_unstemmed Improvement of Properties and Performances of Polyether sulfone Ultrafiltration Membrane by Blending with Bio-Based Dragonbloodin Resin
title_sort improvement of properties and performances of polyether sulfone ultrafiltration membrane by blending with bio-based dragonbloodin resin
publisher MDPI
publishDate 2021
url https://eprints.ums.edu.my/id/eprint/32189/1/Improvement%20of%20Properties%20and%20Performances%20of%20Polyethersulfone%20Ultrafiltration%20Membrane%20by%20Blending%20with%20Bio-Based%20Dragonbloodin%20Resin.pdf
https://eprints.ums.edu.my/id/eprint/32189/2/Improvement%20of%20Properties%20and%20Performances%20of%20Polyethersulfone%20Ultrafiltration%20Membrane%20by%20Blending%20with%20Bio-Based%20Dragonbloodin%20Resin1.pdf
https://eprints.ums.edu.my/id/eprint/32189/
https://www.mdpi.com/2073-4360/13/24/4436
https://doi.org/10.3390/polym13244436
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score 13.211869