Functional novel ligand based palladium(II) separation and recovery from e-waste using solvent-ligand approach
The global e-waste generation is projected to leap tremendously over the following years due to the fast urbanization and increasing population. Inadequate management and uncontrolled disposal may impact significantly to the health and environment. E-waste could become a significant source of precio...
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2021
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Online Access: | https://eprints.ums.edu.my/id/eprint/31825/1/Functional%20novel%20ligand%20based%20palladium%28II%29%20separation%20and%20recovery%20from%20e-waste%20using%20solvent-ligand%20approach%20.ABSTRACT.pdf https://eprints.ums.edu.my/id/eprint/31825/2/Functional%20novel%20ligand%20based%20palladium%28II%29%20separation%20and%20recovery%20from.pdf https://eprints.ums.edu.my/id/eprint/31825/ https://www.sciencedirect.com/science/article/abs/pii/S0927775721016368 https://doi.org/10.1016/j.colsurfa.2021.127767 |
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my.ums.eprints.318252022-03-04T07:36:08Z https://eprints.ums.edu.my/id/eprint/31825/ Functional novel ligand based palladium(II) separation and recovery from e-waste using solvent-ligand approach Aminul Islam Srimonta Roy Teo, Siow Hwa Shahjalal Khandaker Yap, Taufiq Yun Hin Azrina Abd Aziz Minhaj Uddin Monir Umer Rashid Dai-Viet N. Vo Mohd Lokman Ibrahim Hussein Znad Md. Rabiul Awual QD1-999 Chemistry The global e-waste generation is projected to leap tremendously over the following years due to the fast urbanization and increasing population. Inadequate management and uncontrolled disposal may impact significantly to the health and environment. E-waste could become a significant source of precious metals at the end of e-waste life. The recovery of precious metals from e-waste provides a sustainable solution; however, conventional hydrometallurgical approach bears a greater fraction of environmental concerns and energy utilization. In this study, effort has been given to recover palladium (Pd(II)) from ceramic capacitor using solvent-ligand process with a focus on environmental sustainability. The use of 3–(((5–ethoxybenzenethiol)imino)methyl)–salicylic acid as a ligand to recover Pd(II) from ceramic capacitor was investigated. The effects of different variables such as, contact time and reaction temperature, leaching kinetics as well as the environmental assessment of synthesis process were examined. The high purity of Pd(II)was recovered from ceramic capacitor under optimized condition, as evident from XRD and XPS analysis. The formation of [Pd(II)-ligand]n+ complexes was attributed to the recovery of pure metallic Pd(II). The environmental assessment measured from Biwer and Heinzle Method (BHM) indicated that the solvent-legend approach for recovering Pd(II)is associated with the lower impact on the environment compared with the other process. The results open up a sustainable recovery of precious metals contributing to the circular economy. Elsevier 2021-10-22 Article PeerReviewed text en https://eprints.ums.edu.my/id/eprint/31825/1/Functional%20novel%20ligand%20based%20palladium%28II%29%20separation%20and%20recovery%20from%20e-waste%20using%20solvent-ligand%20approach%20.ABSTRACT.pdf text en https://eprints.ums.edu.my/id/eprint/31825/2/Functional%20novel%20ligand%20based%20palladium%28II%29%20separation%20and%20recovery%20from.pdf Aminul Islam and Srimonta Roy and Teo, Siow Hwa and Shahjalal Khandaker and Yap, Taufiq Yun Hin and Azrina Abd Aziz and Minhaj Uddin Monir and Umer Rashid and Dai-Viet N. Vo and Mohd Lokman Ibrahim and Hussein Znad and Md. Rabiul Awual (2021) Functional novel ligand based palladium(II) separation and recovery from e-waste using solvent-ligand approach. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 632. ISSN 0927-7757 https://www.sciencedirect.com/science/article/abs/pii/S0927775721016368 https://doi.org/10.1016/j.colsurfa.2021.127767 |
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QD1-999 Chemistry Aminul Islam Srimonta Roy Teo, Siow Hwa Shahjalal Khandaker Yap, Taufiq Yun Hin Azrina Abd Aziz Minhaj Uddin Monir Umer Rashid Dai-Viet N. Vo Mohd Lokman Ibrahim Hussein Znad Md. Rabiul Awual Functional novel ligand based palladium(II) separation and recovery from e-waste using solvent-ligand approach |
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The global e-waste generation is projected to leap tremendously over the following years due to the fast urbanization and increasing population. Inadequate management and uncontrolled disposal may impact significantly to the health and environment. E-waste could become a significant source of precious metals at the end of e-waste life. The recovery of precious metals from e-waste provides a sustainable solution; however, conventional hydrometallurgical approach bears a greater fraction of environmental concerns and energy utilization. In this study, effort has been given to recover palladium (Pd(II)) from ceramic capacitor using solvent-ligand process with a focus on environmental sustainability. The use of 3–(((5–ethoxybenzenethiol)imino)methyl)–salicylic acid as a ligand to recover Pd(II) from ceramic capacitor was investigated. The effects of different variables such as, contact time and reaction temperature, leaching kinetics as well as the environmental assessment of synthesis process were examined. The high purity of Pd(II)was recovered from ceramic capacitor under optimized condition, as evident from XRD and XPS analysis. The formation of [Pd(II)-ligand]n+ complexes was attributed to the recovery of pure metallic Pd(II). The environmental assessment measured from Biwer and Heinzle Method (BHM) indicated that the solvent-legend approach for recovering Pd(II)is associated with the lower impact on the environment compared with the other process. The results open up a sustainable recovery of precious metals contributing to the circular economy. |
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Article |
author |
Aminul Islam Srimonta Roy Teo, Siow Hwa Shahjalal Khandaker Yap, Taufiq Yun Hin Azrina Abd Aziz Minhaj Uddin Monir Umer Rashid Dai-Viet N. Vo Mohd Lokman Ibrahim Hussein Znad Md. Rabiul Awual |
author_facet |
Aminul Islam Srimonta Roy Teo, Siow Hwa Shahjalal Khandaker Yap, Taufiq Yun Hin Azrina Abd Aziz Minhaj Uddin Monir Umer Rashid Dai-Viet N. Vo Mohd Lokman Ibrahim Hussein Znad Md. Rabiul Awual |
author_sort |
Aminul Islam |
title |
Functional novel ligand based palladium(II) separation and recovery from e-waste using solvent-ligand approach |
title_short |
Functional novel ligand based palladium(II) separation and recovery from e-waste using solvent-ligand approach |
title_full |
Functional novel ligand based palladium(II) separation and recovery from e-waste using solvent-ligand approach |
title_fullStr |
Functional novel ligand based palladium(II) separation and recovery from e-waste using solvent-ligand approach |
title_full_unstemmed |
Functional novel ligand based palladium(II) separation and recovery from e-waste using solvent-ligand approach |
title_sort |
functional novel ligand based palladium(ii) separation and recovery from e-waste using solvent-ligand approach |
publisher |
Elsevier |
publishDate |
2021 |
url |
https://eprints.ums.edu.my/id/eprint/31825/1/Functional%20novel%20ligand%20based%20palladium%28II%29%20separation%20and%20recovery%20from%20e-waste%20using%20solvent-ligand%20approach%20.ABSTRACT.pdf https://eprints.ums.edu.my/id/eprint/31825/2/Functional%20novel%20ligand%20based%20palladium%28II%29%20separation%20and%20recovery%20from.pdf https://eprints.ums.edu.my/id/eprint/31825/ https://www.sciencedirect.com/science/article/abs/pii/S0927775721016368 https://doi.org/10.1016/j.colsurfa.2021.127767 |
_version_ |
1760230943728074752 |
score |
13.211869 |