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Physical, structural, and Raman spectroscopic traits of neodymium-doped lead Oxyfluoride zinc phosphate glass

Nd3+ with composition of (60 - x) P2O5 - 10ZnO - 30PbF2 - (x) Nd2O3 where (0.0 ≤ x ≤ 2.0 mol %) was prepared using a melt-quenching approach to the development of transparent glasses. These glasses have been confirmed to be an amorphous structure through XRD analysis. The glass density, molar volume...

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Main Authors: N Y M Isa, ‪Ezza Syuhada Sazali, ‪Rosdiyana Hisam, S K Ghoshal, S K M Zain, N H Juma’in, S N S Yaacob, Z A S Mahraz, A N Harun, F M Noor, M R Sahar, K A Samah, M S Aziz, A A Salim, Asmahani Awang
Format: Proceedings
Language:English
English
Published: IOP Publishing Ltd. 2021
Subjects:
QD1-999 Chemistry
Online Access:https://eprints.ums.edu.my/id/eprint/31741/1/Physical%2C%20structural%2C%20and%20Raman%20spectroscopic%20traits%20of%20neodymium-doped%20lead%20Oxyfluoride%20zinc%20phosphate%20glass-ABSTRACT.pdf
https://eprints.ums.edu.my/id/eprint/31741/2/Physical%2C%20structural%2C%20and%20Raman%20spectroscopic%20traits%20of%20neodymium-doped%20lead%20Oxyfluoride%20zinc%20phosphate%20glass.pdf
https://eprints.ums.edu.my/id/eprint/31741/
https://iopscience.iop.org/article/10.1088/1742-6596/1892/1/012027
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spelling my.ums.eprints.317412022-02-24T08:27:56Z https://eprints.ums.edu.my/id/eprint/31741/ Physical, structural, and Raman spectroscopic traits of neodymium-doped lead Oxyfluoride zinc phosphate glass N Y M Isa ‪Ezza Syuhada Sazali ‪Rosdiyana Hisam S K Ghoshal S K M Zain N H Juma’in S N S Yaacob Z A S Mahraz A N Harun F M Noor M R Sahar K A Samah M S Aziz A A Salim Asmahani Awang QD1-999 Chemistry Nd3+ with composition of (60 - x) P2O5 - 10ZnO - 30PbF2 - (x) Nd2O3 where (0.0 ≤ x ≤ 2.0 mol %) was prepared using a melt-quenching approach to the development of transparent glasses. These glasses have been confirmed to be an amorphous structure through XRD analysis. The glass density, molar volume and ionic packing density were obtained in the range of 3.978- 4.157 g cm-3, 41.949 - 41.073 cm3 mol-1 and 0.614-0.624, respectively. Using Fourier Transform Infrared (FTIR) and Raman Spectroscopy, the chemical functional groups and biomolecules of samples were characterised. The FTIR spectra revealed six main bands assigned to P-O, P-O-P, P=O, (PO3)2- and hydroxyl groups (O-H), while Raman shift detected five symmetric and asymmetric bands attributed to P-O-P bonds in Q1 units, (PO4)3- bonds in Q0 units, (PO3)2- bonds in Q1 units, (PO2)- bonds in Q2 units and P=O bonds in Q3 units. It is believed that the proposed oxyfluoride glasses may be useful and suitable applicant to lasing materials and sensors sensitivity. IOP Publishing Ltd. 2021 Proceedings PeerReviewed text en https://eprints.ums.edu.my/id/eprint/31741/1/Physical%2C%20structural%2C%20and%20Raman%20spectroscopic%20traits%20of%20neodymium-doped%20lead%20Oxyfluoride%20zinc%20phosphate%20glass-ABSTRACT.pdf text en https://eprints.ums.edu.my/id/eprint/31741/2/Physical%2C%20structural%2C%20and%20Raman%20spectroscopic%20traits%20of%20neodymium-doped%20lead%20Oxyfluoride%20zinc%20phosphate%20glass.pdf N Y M Isa and ‪Ezza Syuhada Sazali and ‪Rosdiyana Hisam and S K Ghoshal and S K M Zain and N H Juma’in and S N S Yaacob and Z A S Mahraz and A N Harun and F M Noor and M R Sahar and K A Samah and M S Aziz and A A Salim and Asmahani Awang (2021) Physical, structural, and Raman spectroscopic traits of neodymium-doped lead Oxyfluoride zinc phosphate glass. https://iopscience.iop.org/article/10.1088/1742-6596/1892/1/012027
institution Universiti Malaysia Sabah
building UMS Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Sabah
content_source UMS Institutional Repository
url_provider http://eprints.ums.edu.my/
language English
English
topic QD1-999 Chemistry
spellingShingle QD1-999 Chemistry
N Y M Isa
‪Ezza Syuhada Sazali
‪Rosdiyana Hisam
S K Ghoshal
S K M Zain
N H Juma’in
S N S Yaacob
Z A S Mahraz
A N Harun
F M Noor
M R Sahar
K A Samah
M S Aziz
A A Salim
Asmahani Awang
Physical, structural, and Raman spectroscopic traits of neodymium-doped lead Oxyfluoride zinc phosphate glass
description Nd3+ with composition of (60 - x) P2O5 - 10ZnO - 30PbF2 - (x) Nd2O3 where (0.0 ≤ x ≤ 2.0 mol %) was prepared using a melt-quenching approach to the development of transparent glasses. These glasses have been confirmed to be an amorphous structure through XRD analysis. The glass density, molar volume and ionic packing density were obtained in the range of 3.978- 4.157 g cm-3, 41.949 - 41.073 cm3 mol-1 and 0.614-0.624, respectively. Using Fourier Transform Infrared (FTIR) and Raman Spectroscopy, the chemical functional groups and biomolecules of samples were characterised. The FTIR spectra revealed six main bands assigned to P-O, P-O-P, P=O, (PO3)2- and hydroxyl groups (O-H), while Raman shift detected five symmetric and asymmetric bands attributed to P-O-P bonds in Q1 units, (PO4)3- bonds in Q0 units, (PO3)2- bonds in Q1 units, (PO2)- bonds in Q2 units and P=O bonds in Q3 units. It is believed that the proposed oxyfluoride glasses may be useful and suitable applicant to lasing materials and sensors sensitivity.
format Proceedings
author N Y M Isa
‪Ezza Syuhada Sazali
‪Rosdiyana Hisam
S K Ghoshal
S K M Zain
N H Juma’in
S N S Yaacob
Z A S Mahraz
A N Harun
F M Noor
M R Sahar
K A Samah
M S Aziz
A A Salim
Asmahani Awang
author_facet N Y M Isa
‪Ezza Syuhada Sazali
‪Rosdiyana Hisam
S K Ghoshal
S K M Zain
N H Juma’in
S N S Yaacob
Z A S Mahraz
A N Harun
F M Noor
M R Sahar
K A Samah
M S Aziz
A A Salim
Asmahani Awang
author_sort N Y M Isa
title Physical, structural, and Raman spectroscopic traits of neodymium-doped lead Oxyfluoride zinc phosphate glass
title_short Physical, structural, and Raman spectroscopic traits of neodymium-doped lead Oxyfluoride zinc phosphate glass
title_full Physical, structural, and Raman spectroscopic traits of neodymium-doped lead Oxyfluoride zinc phosphate glass
title_fullStr Physical, structural, and Raman spectroscopic traits of neodymium-doped lead Oxyfluoride zinc phosphate glass
title_full_unstemmed Physical, structural, and Raman spectroscopic traits of neodymium-doped lead Oxyfluoride zinc phosphate glass
title_sort physical, structural, and raman spectroscopic traits of neodymium-doped lead oxyfluoride zinc phosphate glass
publisher IOP Publishing Ltd.
publishDate 2021
url https://eprints.ums.edu.my/id/eprint/31741/1/Physical%2C%20structural%2C%20and%20Raman%20spectroscopic%20traits%20of%20neodymium-doped%20lead%20Oxyfluoride%20zinc%20phosphate%20glass-ABSTRACT.pdf
https://eprints.ums.edu.my/id/eprint/31741/2/Physical%2C%20structural%2C%20and%20Raman%20spectroscopic%20traits%20of%20neodymium-doped%20lead%20Oxyfluoride%20zinc%20phosphate%20glass.pdf
https://eprints.ums.edu.my/id/eprint/31741/
https://iopscience.iop.org/article/10.1088/1742-6596/1892/1/012027
_version_ 1760230932499922944
score 13.211869

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