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Recent Advancement of Ullmann Condensation Coupling Reaction in the Formation of Aryl-Oxygen (C-O) Bonding by Copper-Mediated Catalyst

Transition metal-catalyzed chemical transformation of organic electrophiles and organometallic reagents belong to the most important cross coupling reaction in organic synthesis. The biaryl ether division is not only popular in natural products and synthetic pharmaceuticals but also widely found in...

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Main Authors: Choong Jian Fui, Mohd Sani Sarjadi, Shaheen M. Sarkar, Md Lutfor Rahman
Format: Article
Language:English
English
Published: Multidisciplinary Digital Publishing Institute (MDPI) 2020
Subjects:
Q Science (General)
QD Chemistry
Online Access:https://eprints.ums.edu.my/id/eprint/30164/1/Recent%20Advancement%20of%20Ullmann%20Condensation%20Coupling%20Reaction%20in%20the%20Formation%20of%20Aryl-Oxygen%20%28C-O%29%20Bonding%20by%20Copper-Mediated%20Catalyst.pdf
https://eprints.ums.edu.my/id/eprint/30164/2/Recent%20Advancement%20of%20Ullmann%20Condensation%20Coupling%20Reaction%20in%20the%20Formation%20of%20Aryl-Oxygen%20%28C-O%29%20Bonding%20by%20Copper-Mediated%20Catalyst1.pdf
https://eprints.ums.edu.my/id/eprint/30164/
https://www.mdpi.com/2073-4344/10/10/1103
http://dx.doi.org/10.3390/catal10101103
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spelling my.ums.eprints.301642021-07-31T01:24:08Z https://eprints.ums.edu.my/id/eprint/30164/ Recent Advancement of Ullmann Condensation Coupling Reaction in the Formation of Aryl-Oxygen (C-O) Bonding by Copper-Mediated Catalyst Choong Jian Fui Mohd Sani Sarjadi Shaheen M. Sarkar Md Lutfor Rahman Q Science (General) QD Chemistry Transition metal-catalyzed chemical transformation of organic electrophiles and organometallic reagents belong to the most important cross coupling reaction in organic synthesis. The biaryl ether division is not only popular in natural products and synthetic pharmaceuticals but also widely found in many pesticides, polymers, and ligands. Copper catalyst has received great attention owing to the low toxicity and low cost. However, traditional Ullmann-type couplings suffer from limited substrate scopes and harsh reaction conditions. The introduction of homogeneous copper catalyst with presence of bidentate ligands over the past two decades has totally changed this situation as these ligands enable the reaction promoted in mild condition. The reaction scope has also been greatly expanded, rendering this copper-based cross-coupling attractive for both academia and industry. In this review, we will highlight the latest progress in the development of useful homogeneous copper catalyst with presence of ligand and heterogeneous copper catalyst in Ullmann type C-O cross-coupling reaction. Additionally, the application of Ullmann type C-O cross coupling reaction will be discussed. Multidisciplinary Digital Publishing Institute (MDPI) 2020 Article PeerReviewed text en https://eprints.ums.edu.my/id/eprint/30164/1/Recent%20Advancement%20of%20Ullmann%20Condensation%20Coupling%20Reaction%20in%20the%20Formation%20of%20Aryl-Oxygen%20%28C-O%29%20Bonding%20by%20Copper-Mediated%20Catalyst.pdf text en https://eprints.ums.edu.my/id/eprint/30164/2/Recent%20Advancement%20of%20Ullmann%20Condensation%20Coupling%20Reaction%20in%20the%20Formation%20of%20Aryl-Oxygen%20%28C-O%29%20Bonding%20by%20Copper-Mediated%20Catalyst1.pdf Choong Jian Fui and Mohd Sani Sarjadi and Shaheen M. Sarkar and Md Lutfor Rahman (2020) Recent Advancement of Ullmann Condensation Coupling Reaction in the Formation of Aryl-Oxygen (C-O) Bonding by Copper-Mediated Catalyst. Catalysts, 10 (1103). pp. 1-50. ISSN 2073-4344 https://www.mdpi.com/2073-4344/10/10/1103 http://dx.doi.org/10.3390/catal10101103
institution Universiti Malaysia Sabah
building UMS Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Sabah
content_source UMS Institutional Repository
url_provider http://eprints.ums.edu.my/
language English
English
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Choong Jian Fui
Mohd Sani Sarjadi
Shaheen M. Sarkar
Md Lutfor Rahman
Recent Advancement of Ullmann Condensation Coupling Reaction in the Formation of Aryl-Oxygen (C-O) Bonding by Copper-Mediated Catalyst
description Transition metal-catalyzed chemical transformation of organic electrophiles and organometallic reagents belong to the most important cross coupling reaction in organic synthesis. The biaryl ether division is not only popular in natural products and synthetic pharmaceuticals but also widely found in many pesticides, polymers, and ligands. Copper catalyst has received great attention owing to the low toxicity and low cost. However, traditional Ullmann-type couplings suffer from limited substrate scopes and harsh reaction conditions. The introduction of homogeneous copper catalyst with presence of bidentate ligands over the past two decades has totally changed this situation as these ligands enable the reaction promoted in mild condition. The reaction scope has also been greatly expanded, rendering this copper-based cross-coupling attractive for both academia and industry. In this review, we will highlight the latest progress in the development of useful homogeneous copper catalyst with presence of ligand and heterogeneous copper catalyst in Ullmann type C-O cross-coupling reaction. Additionally, the application of Ullmann type C-O cross coupling reaction will be discussed.
format Article
author Choong Jian Fui
Mohd Sani Sarjadi
Shaheen M. Sarkar
Md Lutfor Rahman
author_facet Choong Jian Fui
Mohd Sani Sarjadi
Shaheen M. Sarkar
Md Lutfor Rahman
author_sort Choong Jian Fui
title Recent Advancement of Ullmann Condensation Coupling Reaction in the Formation of Aryl-Oxygen (C-O) Bonding by Copper-Mediated Catalyst
title_short Recent Advancement of Ullmann Condensation Coupling Reaction in the Formation of Aryl-Oxygen (C-O) Bonding by Copper-Mediated Catalyst
title_full Recent Advancement of Ullmann Condensation Coupling Reaction in the Formation of Aryl-Oxygen (C-O) Bonding by Copper-Mediated Catalyst
title_fullStr Recent Advancement of Ullmann Condensation Coupling Reaction in the Formation of Aryl-Oxygen (C-O) Bonding by Copper-Mediated Catalyst
title_full_unstemmed Recent Advancement of Ullmann Condensation Coupling Reaction in the Formation of Aryl-Oxygen (C-O) Bonding by Copper-Mediated Catalyst
title_sort recent advancement of ullmann condensation coupling reaction in the formation of aryl-oxygen (c-o) bonding by copper-mediated catalyst
publisher Multidisciplinary Digital Publishing Institute (MDPI)
publishDate 2020
url https://eprints.ums.edu.my/id/eprint/30164/1/Recent%20Advancement%20of%20Ullmann%20Condensation%20Coupling%20Reaction%20in%20the%20Formation%20of%20Aryl-Oxygen%20%28C-O%29%20Bonding%20by%20Copper-Mediated%20Catalyst.pdf
https://eprints.ums.edu.my/id/eprint/30164/2/Recent%20Advancement%20of%20Ullmann%20Condensation%20Coupling%20Reaction%20in%20the%20Formation%20of%20Aryl-Oxygen%20%28C-O%29%20Bonding%20by%20Copper-Mediated%20Catalyst1.pdf
https://eprints.ums.edu.my/id/eprint/30164/
https://www.mdpi.com/2073-4344/10/10/1103
http://dx.doi.org/10.3390/catal10101103
_version_ 1760230726955958272
score 13.211869

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