Efficient reaction for biodiesel manufacturing using bi-functional oxide catalyst

The search for biofuel in order to complement the future shortage of fuels and mitigate the poisonous air and water pollution has become so considerate in the last few decades. The choice of feedstock and catalyst system for biofuel production has been very difficult considering many drawbacks from...

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Main Authors: Nasar Mansir, Siow Hwa Teo, Nurul-Asikin Mijan, Yun Hin Taufiq-Yap
Format: Article
Language:English
English
Published: Elsevier BV 2020
Subjects:
Online Access:https://eprints.ums.edu.my/id/eprint/26778/1/Efficient%20reaction%20for%20biodiesel%20manufacturing%20using%20bi-functional%20oxide%20catalyst.pdf
https://eprints.ums.edu.my/id/eprint/26778/2/Efficient%20reaction%20for%20biodiesel%20manufacturing%20using%20bi-functional.pdf
https://eprints.ums.edu.my/id/eprint/26778/
https://doi.org/10.1016/j.catcom.2020.106201
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spelling my.ums.eprints.267782021-04-19T03:25:04Z https://eprints.ums.edu.my/id/eprint/26778/ Efficient reaction for biodiesel manufacturing using bi-functional oxide catalyst Nasar Mansir Siow Hwa Teo Nurul-Asikin Mijan Yun Hin Taufiq-Yap QD Chemistry The search for biofuel in order to complement the future shortage of fuels and mitigate the poisonous air and water pollution has become so considerate in the last few decades. The choice of feedstock and catalyst system for biofuel production has been very difficult considering many drawbacks from food-fuel competition to catalyst separation and water washing after the reaction. To address these issues, acid-base bi-functional catalysts and waste based vegetable oil were considered for the sustainable production of biofuels. Bifunctional catalyst has the capacity to successfully transform waste based vegetable oil into useful biofuel under mild reaction pa rameters. In this work, a newly developed bimetallic tungsten- zirconia (W–Zr) modified waste shell catalyst samples were employed for the simultaneous esterification and transesterification of unrefined palm-derived waste oil (PDWO) to biodiesel in one-pot reaction. These catalysts were successfully synthesized using simple wet impregnation technique and characterized by SEM, BET, XRD, and TPD characterization techniques. The catalyst was able to achieved the maximum biodiesel yield of 94.1% in 1 h under optimized reaction parameters. Elsevier BV 2020-10-20 Article PeerReviewed text en https://eprints.ums.edu.my/id/eprint/26778/1/Efficient%20reaction%20for%20biodiesel%20manufacturing%20using%20bi-functional%20oxide%20catalyst.pdf text en https://eprints.ums.edu.my/id/eprint/26778/2/Efficient%20reaction%20for%20biodiesel%20manufacturing%20using%20bi-functional.pdf Nasar Mansir and Siow Hwa Teo and Nurul-Asikin Mijan and Yun Hin Taufiq-Yap (2020) Efficient reaction for biodiesel manufacturing using bi-functional oxide catalyst. Catalysis Communications, 149. https://doi.org/10.1016/j.catcom.2020.106201
institution Universiti Malaysia Sabah
building UMS Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Sabah
content_source UMS Institutional Repository
url_provider http://eprints.ums.edu.my/
language English
English
topic QD Chemistry
spellingShingle QD Chemistry
Nasar Mansir
Siow Hwa Teo
Nurul-Asikin Mijan
Yun Hin Taufiq-Yap
Efficient reaction for biodiesel manufacturing using bi-functional oxide catalyst
description The search for biofuel in order to complement the future shortage of fuels and mitigate the poisonous air and water pollution has become so considerate in the last few decades. The choice of feedstock and catalyst system for biofuel production has been very difficult considering many drawbacks from food-fuel competition to catalyst separation and water washing after the reaction. To address these issues, acid-base bi-functional catalysts and waste based vegetable oil were considered for the sustainable production of biofuels. Bifunctional catalyst has the capacity to successfully transform waste based vegetable oil into useful biofuel under mild reaction pa rameters. In this work, a newly developed bimetallic tungsten- zirconia (W–Zr) modified waste shell catalyst samples were employed for the simultaneous esterification and transesterification of unrefined palm-derived waste oil (PDWO) to biodiesel in one-pot reaction. These catalysts were successfully synthesized using simple wet impregnation technique and characterized by SEM, BET, XRD, and TPD characterization techniques. The catalyst was able to achieved the maximum biodiesel yield of 94.1% in 1 h under optimized reaction parameters.
format Article
author Nasar Mansir
Siow Hwa Teo
Nurul-Asikin Mijan
Yun Hin Taufiq-Yap
author_facet Nasar Mansir
Siow Hwa Teo
Nurul-Asikin Mijan
Yun Hin Taufiq-Yap
author_sort Nasar Mansir
title Efficient reaction for biodiesel manufacturing using bi-functional oxide catalyst
title_short Efficient reaction for biodiesel manufacturing using bi-functional oxide catalyst
title_full Efficient reaction for biodiesel manufacturing using bi-functional oxide catalyst
title_fullStr Efficient reaction for biodiesel manufacturing using bi-functional oxide catalyst
title_full_unstemmed Efficient reaction for biodiesel manufacturing using bi-functional oxide catalyst
title_sort efficient reaction for biodiesel manufacturing using bi-functional oxide catalyst
publisher Elsevier BV
publishDate 2020
url https://eprints.ums.edu.my/id/eprint/26778/1/Efficient%20reaction%20for%20biodiesel%20manufacturing%20using%20bi-functional%20oxide%20catalyst.pdf
https://eprints.ums.edu.my/id/eprint/26778/2/Efficient%20reaction%20for%20biodiesel%20manufacturing%20using%20bi-functional.pdf
https://eprints.ums.edu.my/id/eprint/26778/
https://doi.org/10.1016/j.catcom.2020.106201
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