Staff View: Synthesis and characterization of metal oxide promoted alumina catalyst for biofuel production

Synthesis and characterization of metal oxide promoted alumina catalyst for biofuel production

Alumina has been widely used as a support in catalysis process which owing to its extremely thermal and mechanical stability, high surface area, large pore size and pore volume. The aim of this study was to synthesize calcium oxide-supported basic alumina catalysts (CaO/Al2O3) by impregnation method...

Full description

Saved in:

Bibliographic Details
Main Authors:	S. M. Anisuzzaman, Duduku Krishnaiah, Awang Bono, S Abang, M Sundang, Emma Suali, Farhana Abd Lahin, A Shaik Alawodeen
Format:	Conference or Workshop Item
Language:	English
Published:	2016
Subjects:	TA Engineering (General). Civil engineering (General)
Online Access:	https://eprints.ums.edu.my/id/eprint/18777/1/Synthesis%20and%20characterization%20of%20metal%20oxide%20promoted%20alumina%20catalyst%20for%20biofuel%20production.pdf https://eprints.ums.edu.my/id/eprint/18777/
Tags:	Add Tag No Tags, Be the first to tag this record!

id	my.ums.eprints.18777
record_format	eprints
spelling	my.ums.eprints.187772018-02-28T01:24:29Z https://eprints.ums.edu.my/id/eprint/18777/ Synthesis and characterization of metal oxide promoted alumina catalyst for biofuel production S. M. Anisuzzaman Duduku Krishnaiah Awang Bono S Abang M Sundang Emma Suali Farhana Abd Lahin A Shaik Alawodeen TA Engineering (General). Civil engineering (General) Alumina has been widely used as a support in catalysis process which owing to its extremely thermal and mechanical stability, high surface area, large pore size and pore volume. The aim of this study was to synthesize calcium oxide-supported basic alumina catalysts (CaO/Al2O3) by impregnation method and to characterize the properties of the catalyst based on its surface area and porosity, functional group, surface morphology and particle size. Impregnation method was chosen for the synthesization of catalyst which involved contacting the support with the impregnating solution for a particular period of time, drying the support to remove the imbibed liquid and calcination process. In the preparation of catalyst, catalytic performance of CaO/Al2O3 catalyst was measured at different calcined temperatures (650°C, 750°C and 800°C). Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), Mercury intrusion porosimetry (MIP), and particle size analyzer (Zetasizer) was used to characterize the catalyst. The highest total specific area and the total porosity of the catalyst was obtained at 750oC. FTIR analysis basically studied on the functional groups present in each catalyst synthesized, while SEM analysis was observed to have pores on its surface. Moreover, CaO/Al2O3 catalysts at 650°C produced the smallest particle size (396.1 mn), while at 750°C produced the largest particle size (712.4 mn). Thus it can be concluded that CaO/Al2O3 catalysts has great potential coimnercialization since CaO has attracted many attentions compared to other alkali earth metal oxides especially on the transesterification reaction. 2016 Conference or Workshop Item PeerReviewed text en https://eprints.ums.edu.my/id/eprint/18777/1/Synthesis%20and%20characterization%20of%20metal%20oxide%20promoted%20alumina%20catalyst%20for%20biofuel%20production.pdf S. M. Anisuzzaman and Duduku Krishnaiah and Awang Bono and S Abang and M Sundang and Emma Suali and Farhana Abd Lahin and A Shaik Alawodeen (2016) Synthesis and characterization of metal oxide promoted alumina catalyst for biofuel production. In: IOP Conference Series: Earth and Environmental Science.
institution	Universiti Malaysia Sabah
building	UMS Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaysia Sabah
content_source	UMS Institutional Repository
url_provider	http://eprints.ums.edu.my/
language	English
topic	TA Engineering (General). Civil engineering (General)
spellingShingle	TA Engineering (General). Civil engineering (General) S. M. Anisuzzaman Duduku Krishnaiah Awang Bono S Abang M Sundang Emma Suali Farhana Abd Lahin A Shaik Alawodeen Synthesis and characterization of metal oxide promoted alumina catalyst for biofuel production
description	Alumina has been widely used as a support in catalysis process which owing to its extremely thermal and mechanical stability, high surface area, large pore size and pore volume. The aim of this study was to synthesize calcium oxide-supported basic alumina catalysts (CaO/Al2O3) by impregnation method and to characterize the properties of the catalyst based on its surface area and porosity, functional group, surface morphology and particle size. Impregnation method was chosen for the synthesization of catalyst which involved contacting the support with the impregnating solution for a particular period of time, drying the support to remove the imbibed liquid and calcination process. In the preparation of catalyst, catalytic performance of CaO/Al2O3 catalyst was measured at different calcined temperatures (650°C, 750°C and 800°C). Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), Mercury intrusion porosimetry (MIP), and particle size analyzer (Zetasizer) was used to characterize the catalyst. The highest total specific area and the total porosity of the catalyst was obtained at 750oC. FTIR analysis basically studied on the functional groups present in each catalyst synthesized, while SEM analysis was observed to have pores on its surface. Moreover, CaO/Al2O3 catalysts at 650°C produced the smallest particle size (396.1 mn), while at 750°C produced the largest particle size (712.4 mn). Thus it can be concluded that CaO/Al2O3 catalysts has great potential coimnercialization since CaO has attracted many attentions compared to other alkali earth metal oxides especially on the transesterification reaction.
format	Conference or Workshop Item
author	S. M. Anisuzzaman Duduku Krishnaiah Awang Bono S Abang M Sundang Emma Suali Farhana Abd Lahin A Shaik Alawodeen
author_facet	S. M. Anisuzzaman Duduku Krishnaiah Awang Bono S Abang M Sundang Emma Suali Farhana Abd Lahin A Shaik Alawodeen
author_sort	S. M. Anisuzzaman
title	Synthesis and characterization of metal oxide promoted alumina catalyst for biofuel production
title_short	Synthesis and characterization of metal oxide promoted alumina catalyst for biofuel production
title_full	Synthesis and characterization of metal oxide promoted alumina catalyst for biofuel production
title_fullStr	Synthesis and characterization of metal oxide promoted alumina catalyst for biofuel production
title_full_unstemmed	Synthesis and characterization of metal oxide promoted alumina catalyst for biofuel production
title_sort	synthesis and characterization of metal oxide promoted alumina catalyst for biofuel production
publishDate	2016
url	https://eprints.ums.edu.my/id/eprint/18777/1/Synthesis%20and%20characterization%20of%20metal%20oxide%20promoted%20alumina%20catalyst%20for%20biofuel%20production.pdf https://eprints.ums.edu.my/id/eprint/18777/
_version_	1760229491831996416
score	13.211869

Synthesis and characterization of metal oxide promoted alumina catalyst for biofuel production

Similar Items