New U-shaped Liquid Crystals Azobenzene Derived from Catechol for Photoswitching Properties
A new series of liquid crystals whose molecular structure consists of a U-shaped unit as a central core and two rod-like azobenzenes as the peripheral units are synthesized. The mesomorphic properties were investigated by differential scanning calorimetry, polarizing optical microscopy and X-ray d...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2015
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| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/8118/1/New%20U-Shaped%20Liquid%20Crystals%20Azobenzene%20Derived%20From%20Catechol%20for%20Photoswitching%20Properties.pdf http://umpir.ump.edu.my/id/eprint/8118/ http://dx.doi.org/10.1016/j.molliq.2014.12.022 |
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| Summary: | A new series of liquid crystals whose molecular structure consists of a U-shaped unit as a central core and two
rod-like azobenzenes as the peripheral units are synthesized. The mesomorphic properties were investigated
by differential scanning calorimetry, polarizing optical microscopy and X-ray diffraction. The existence of nematic and smectic A phase was confirmed by textures and X-ray diffraction. The trans-form of azo compounds showed
a strong band in the UV region at ~365 nm for the π–π* transition, and a weak band in the visible region at
~450 nm due to the n–π* transition. These molecules exhibit a strong photoisomerization behavior in which
trans–cis take 50 and 55 s for compounds L4/5 and L4/6, respectively, whereas cis–trans take place almost 29
and 30 h, respectively. Long thermal back relaxation allows us to realize that optical storage devices with these materials which need longer periods. |
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