tudy on optimum condition of empty fruit bunch-graft-acrylic acid superabsorbent polymer composites

Oil palm empty fruit bunch graft (acrylic acid) superabsorbent composite (OPEFB-g-AA SPC) was synthesized by graft copolymerization of the acrylic acid (AA) comonomer onto OPEFB fibre using ammonium persulfate (APS) and N,N-methylene bisacarylamide (MBA) as an initiator and crosslinker. Systematical...

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Bibliographic Details
Main Author: Mohammad Amar, Mohammad Ali
Format: Undergraduates Project Papers
Language:English
Published: 2013
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/7141/1/Study_on_optimum_condition_of_empty_fruit.pdf
http://umpir.ump.edu.my/id/eprint/7141/
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Summary:Oil palm empty fruit bunch graft (acrylic acid) superabsorbent composite (OPEFB-g-AA SPC) was synthesized by graft copolymerization of the acrylic acid (AA) comonomer onto OPEFB fibre using ammonium persulfate (APS) and N,N-methylene bisacarylamide (MBA) as an initiator and crosslinker. Systematically, variables that affect the swelling behaviors of OPEFB-g-AA SPC were optimized. The effects of initiator, crosslinker and filler concentration as well as solvent quantity and the degree of neutralization on water absorbency of OPEFB-g-AA SPC were studied. Maximum absorbency of OPEFB-g-AA SAPC was achieved in the range at 200 g/g – 250 g/g when the amount of APS and MBA were 0.8 wt.% and 1.0 wt.%, respectively, and the OPEFB loading was at 10 wt.%. The chemical structure of the OPEFB-g-AA SPC was characterized by means of Fourier transform infrared (FTIR) spectroscopy and Thermogravimetric Analysis (TGA) were carried out to confirm the chemical structure and thermal properties of the synthesized superabsorbent.