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Applications of bio-resource based sustainable heterogeneous Pd-Nanocatalyst for Cross-Coupling and Michael addition reactions

The development of efficient and cost-effective catalysts from renewable sources is crucial for sustainable chemistry. Herein, we developed a bio-heterogeneous Pd-nanocatalyst (PdNc@PA) by incorporating palladium nanoparticles into biodegradable kenaf-cellulose modified with poly(amidoxime) ligands....

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Main Authors:	Islam, Md. Shaharul, Sarkar, Shaheen M., Rahman, Md Lutfor, Hasan, Kamrul, O’Reilly, Emmet J.
Format:	Article
Language:	English
Published:	Elsevier 2024
Subjects:	Q Science (General) TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/43091/1/Applications%20of%20bio-resource%20based%20sustainable%20heterogeneous%20Pd-Nanocatalyst.pdf http://umpir.ump.edu.my/id/eprint/43091/ https://doi.org/10.1016/j.cej.2024.149271 https://doi.org/10.1016/j.cej.2024.149271
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id	my.ump.umpir.43091
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spelling	my.ump.umpir.430912024-12-09T07:40:33Z http://umpir.ump.edu.my/id/eprint/43091/ Applications of bio-resource based sustainable heterogeneous Pd-Nanocatalyst for Cross-Coupling and Michael addition reactions Islam, Md. Shaharul Sarkar, Shaheen M. Rahman, Md Lutfor Hasan, Kamrul O’Reilly, Emmet J. Q Science (General) TP Chemical technology The development of efficient and cost-effective catalysts from renewable sources is crucial for sustainable chemistry. Herein, we developed a bio-heterogeneous Pd-nanocatalyst (PdNc@PA) by incorporating palladium nanoparticles into biodegradable kenaf-cellulose modified with poly(amidoxime) ligands. The catalyst has demonstrated remarkable stability and exceptional catalytic performance in a range of cross-coupling including Mizoroki-Heck, Suzuki-Miyaura, and Tamejiro-Hiyama reactions of inactivated aryl chlorides resulting in high yields of the desired coupling products. Additionally, PdNc@PA was also found to be effective in Michael addition reactions producing N, S, O-alkylated products in high yields. Furthermore, the PdNc@PA catalyst demonstrated robustness and recoverability allowing it to be reused across successive cycles without significant loss of catalytic activity. The incorporation of renewable resources in catalyst development offers an environmentally conscious alternative to traditional synthetic approaches. This research highlights the potential of utilizing biodegradable materials as catalyst supports, which could significantly diminish environmental impact and waste production. Moreover, this study demonstrates the versatility of PdNc@PA as a proficient and reusable catalyst for a diverse array of organic reactions. These discoveries provide an encouraging pathway towards the development of sustainable and economically viable catalysts suitable for industrial applications. Elsevier 2024-03-01 Article PeerReviewed pdf en cc_by_4 http://umpir.ump.edu.my/id/eprint/43091/1/Applications%20of%20bio-resource%20based%20sustainable%20heterogeneous%20Pd-Nanocatalyst.pdf Islam, Md. Shaharul and Sarkar, Shaheen M. and Rahman, Md Lutfor and Hasan, Kamrul and O’Reilly, Emmet J. (2024) Applications of bio-resource based sustainable heterogeneous Pd-Nanocatalyst for Cross-Coupling and Michael addition reactions. Chemical Engineering Journal, 483 (149271). pp. 1-14. ISSN 1385-8947. (Published) https://doi.org/10.1016/j.cej.2024.149271 https://doi.org/10.1016/j.cej.2024.149271
institution	Universiti Malaysia Pahang Al-Sultan Abdullah
building	UMPSA Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaysia Pahang Al-Sultan Abdullah
content_source	UMPSA Institutional Repository
url_provider	http://umpir.ump.edu.my/
language	English
topic	Q Science (General) TP Chemical technology
spellingShingle	Q Science (General) TP Chemical technology Islam, Md. Shaharul Sarkar, Shaheen M. Rahman, Md Lutfor Hasan, Kamrul O’Reilly, Emmet J. Applications of bio-resource based sustainable heterogeneous Pd-Nanocatalyst for Cross-Coupling and Michael addition reactions
description	The development of efficient and cost-effective catalysts from renewable sources is crucial for sustainable chemistry. Herein, we developed a bio-heterogeneous Pd-nanocatalyst (PdNc@PA) by incorporating palladium nanoparticles into biodegradable kenaf-cellulose modified with poly(amidoxime) ligands. The catalyst has demonstrated remarkable stability and exceptional catalytic performance in a range of cross-coupling including Mizoroki-Heck, Suzuki-Miyaura, and Tamejiro-Hiyama reactions of inactivated aryl chlorides resulting in high yields of the desired coupling products. Additionally, PdNc@PA was also found to be effective in Michael addition reactions producing N, S, O-alkylated products in high yields. Furthermore, the PdNc@PA catalyst demonstrated robustness and recoverability allowing it to be reused across successive cycles without significant loss of catalytic activity. The incorporation of renewable resources in catalyst development offers an environmentally conscious alternative to traditional synthetic approaches. This research highlights the potential of utilizing biodegradable materials as catalyst supports, which could significantly diminish environmental impact and waste production. Moreover, this study demonstrates the versatility of PdNc@PA as a proficient and reusable catalyst for a diverse array of organic reactions. These discoveries provide an encouraging pathway towards the development of sustainable and economically viable catalysts suitable for industrial applications.
format	Article
author	Islam, Md. Shaharul Sarkar, Shaheen M. Rahman, Md Lutfor Hasan, Kamrul O’Reilly, Emmet J.
author_facet	Islam, Md. Shaharul Sarkar, Shaheen M. Rahman, Md Lutfor Hasan, Kamrul O’Reilly, Emmet J.
author_sort	Islam, Md. Shaharul
title	Applications of bio-resource based sustainable heterogeneous Pd-Nanocatalyst for Cross-Coupling and Michael addition reactions
title_short	Applications of bio-resource based sustainable heterogeneous Pd-Nanocatalyst for Cross-Coupling and Michael addition reactions
title_full	Applications of bio-resource based sustainable heterogeneous Pd-Nanocatalyst for Cross-Coupling and Michael addition reactions
title_fullStr	Applications of bio-resource based sustainable heterogeneous Pd-Nanocatalyst for Cross-Coupling and Michael addition reactions
title_full_unstemmed	Applications of bio-resource based sustainable heterogeneous Pd-Nanocatalyst for Cross-Coupling and Michael addition reactions
title_sort	applications of bio-resource based sustainable heterogeneous pd-nanocatalyst for cross-coupling and michael addition reactions
publisher	Elsevier
publishDate	2024
url	http://umpir.ump.edu.my/id/eprint/43091/1/Applications%20of%20bio-resource%20based%20sustainable%20heterogeneous%20Pd-Nanocatalyst.pdf http://umpir.ump.edu.my/id/eprint/43091/ https://doi.org/10.1016/j.cej.2024.149271 https://doi.org/10.1016/j.cej.2024.149271
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score	13.235796

Applications of bio-resource based sustainable heterogeneous Pd-Nanocatalyst for Cross-Coupling and Michael addition reactions

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