Fine-tuning zeolite pore structures with carbon coating for enhanced gas separation in polyimide-based mixed matrix membrane

Impregnated zeolite-carbon (IZC), also known as pore-modified zeolite, was used as a potential filler in a P84 co-polyimide-based hollow fiber mixed matrix membrane (HF MMM) to enhance gas separation. The presence of carbon structure on the zeolite framework pore was to avoid the trapped moisture th...

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Main Authors: Triyanda, Gunawan, Nurul Widiastuti, ., Alvin Rahmad, Widyanto, Hamzah, Fansuri, Syafsir, Akhlus, Wan Norharyati, Wan Salleh, Ahmad Fauzi, Ismail, Norazlianie, Sazali, Lin, Rijia, Motuzas, Julius, Smart, Simon
Format: Article
Language:English
English
Published: Elsevier Ltd 2024
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Online Access:http://umpir.ump.edu.my/id/eprint/42996/1/Fine-tuning%20zeolite%20pore%20structures%20with%20carbon%20coating_ABST.pdf
http://umpir.ump.edu.my/id/eprint/42996/2/Fine-tuning%20zeolite%20pore%20structures%20with%20carbon%20coating.pdf
http://umpir.ump.edu.my/id/eprint/42996/
https://doi.org/10.1016/j.cherd.2024.02.042
https://doi.org/10.1016/j.cherd.2024.02.042
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spelling my.ump.umpir.429962024-12-02T07:19:31Z http://umpir.ump.edu.my/id/eprint/42996/ Fine-tuning zeolite pore structures with carbon coating for enhanced gas separation in polyimide-based mixed matrix membrane Triyanda, Gunawan Nurul Widiastuti, . Alvin Rahmad, Widyanto Hamzah, Fansuri Syafsir, Akhlus Wan Norharyati, Wan Salleh Ahmad Fauzi, Ismail Norazlianie, Sazali Lin, Rijia Motuzas, Julius Smart, Simon TP Chemical technology Impregnated zeolite-carbon (IZC), also known as pore-modified zeolite, was used as a potential filler in a P84 co-polyimide-based hollow fiber mixed matrix membrane (HF MMM) to enhance gas separation. The presence of carbon structure on the zeolite framework pore was to avoid the trapped moisture that could lead to permeability reduction. This work seeks to investigate the impact of IZC addition (0.5, 1.0, and 1.5 wt%) to the P84 membrane and examine its permeability and separation performance. Adding IZC filler to the P84 membrane generates the enhancement of gas selectivity and permeability. The optimal enhancement was observed at 1 wt% of IZC loading, in which selectivity of CO2/CH4, CO2/N2, O2/N2, H2/N2, and H2/CH4 was enhanced by 50.506, 51.042, 5.693, 16.712, and 16.338%, respectively. On the other hand, H2, CO2, and O2 permeability at the loading were improved from 11.182 to 26.761, from 4.683 to 14.501, and from 1.637 to 3.546 Barrer, respectively. The improvement of gas selectivity was contributed by the presence of carbon in the zeolite framework, providing a molecular sieving effect while tuning carbon properties with pore regularity by templating in the zeolite framework enhances the gas permeability. Elsevier Ltd 2024-04 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/42996/1/Fine-tuning%20zeolite%20pore%20structures%20with%20carbon%20coating_ABST.pdf pdf en http://umpir.ump.edu.my/id/eprint/42996/2/Fine-tuning%20zeolite%20pore%20structures%20with%20carbon%20coating.pdf Triyanda, Gunawan and Nurul Widiastuti, . and Alvin Rahmad, Widyanto and Hamzah, Fansuri and Syafsir, Akhlus and Wan Norharyati, Wan Salleh and Ahmad Fauzi, Ismail and Norazlianie, Sazali and Lin, Rijia and Motuzas, Julius and Smart, Simon (2024) Fine-tuning zeolite pore structures with carbon coating for enhanced gas separation in polyimide-based mixed matrix membrane. Chemical Engineering Research and Design, 204. 556 -571. ISSN 0263-8762. (Published) https://doi.org/10.1016/j.cherd.2024.02.042 https://doi.org/10.1016/j.cherd.2024.02.042
institution Universiti Malaysia Pahang Al-Sultan Abdullah
building UMPSA Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang Al-Sultan Abdullah
content_source UMPSA Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
English
topic TP Chemical technology
spellingShingle TP Chemical technology
Triyanda, Gunawan
Nurul Widiastuti, .
Alvin Rahmad, Widyanto
Hamzah, Fansuri
Syafsir, Akhlus
Wan Norharyati, Wan Salleh
Ahmad Fauzi, Ismail
Norazlianie, Sazali
Lin, Rijia
Motuzas, Julius
Smart, Simon
Fine-tuning zeolite pore structures with carbon coating for enhanced gas separation in polyimide-based mixed matrix membrane
description Impregnated zeolite-carbon (IZC), also known as pore-modified zeolite, was used as a potential filler in a P84 co-polyimide-based hollow fiber mixed matrix membrane (HF MMM) to enhance gas separation. The presence of carbon structure on the zeolite framework pore was to avoid the trapped moisture that could lead to permeability reduction. This work seeks to investigate the impact of IZC addition (0.5, 1.0, and 1.5 wt%) to the P84 membrane and examine its permeability and separation performance. Adding IZC filler to the P84 membrane generates the enhancement of gas selectivity and permeability. The optimal enhancement was observed at 1 wt% of IZC loading, in which selectivity of CO2/CH4, CO2/N2, O2/N2, H2/N2, and H2/CH4 was enhanced by 50.506, 51.042, 5.693, 16.712, and 16.338%, respectively. On the other hand, H2, CO2, and O2 permeability at the loading were improved from 11.182 to 26.761, from 4.683 to 14.501, and from 1.637 to 3.546 Barrer, respectively. The improvement of gas selectivity was contributed by the presence of carbon in the zeolite framework, providing a molecular sieving effect while tuning carbon properties with pore regularity by templating in the zeolite framework enhances the gas permeability.
format Article
author Triyanda, Gunawan
Nurul Widiastuti, .
Alvin Rahmad, Widyanto
Hamzah, Fansuri
Syafsir, Akhlus
Wan Norharyati, Wan Salleh
Ahmad Fauzi, Ismail
Norazlianie, Sazali
Lin, Rijia
Motuzas, Julius
Smart, Simon
author_facet Triyanda, Gunawan
Nurul Widiastuti, .
Alvin Rahmad, Widyanto
Hamzah, Fansuri
Syafsir, Akhlus
Wan Norharyati, Wan Salleh
Ahmad Fauzi, Ismail
Norazlianie, Sazali
Lin, Rijia
Motuzas, Julius
Smart, Simon
author_sort Triyanda, Gunawan
title Fine-tuning zeolite pore structures with carbon coating for enhanced gas separation in polyimide-based mixed matrix membrane
title_short Fine-tuning zeolite pore structures with carbon coating for enhanced gas separation in polyimide-based mixed matrix membrane
title_full Fine-tuning zeolite pore structures with carbon coating for enhanced gas separation in polyimide-based mixed matrix membrane
title_fullStr Fine-tuning zeolite pore structures with carbon coating for enhanced gas separation in polyimide-based mixed matrix membrane
title_full_unstemmed Fine-tuning zeolite pore structures with carbon coating for enhanced gas separation in polyimide-based mixed matrix membrane
title_sort fine-tuning zeolite pore structures with carbon coating for enhanced gas separation in polyimide-based mixed matrix membrane
publisher Elsevier Ltd
publishDate 2024
url http://umpir.ump.edu.my/id/eprint/42996/1/Fine-tuning%20zeolite%20pore%20structures%20with%20carbon%20coating_ABST.pdf
http://umpir.ump.edu.my/id/eprint/42996/2/Fine-tuning%20zeolite%20pore%20structures%20with%20carbon%20coating.pdf
http://umpir.ump.edu.my/id/eprint/42996/
https://doi.org/10.1016/j.cherd.2024.02.042
https://doi.org/10.1016/j.cherd.2024.02.042
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