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Glycerol dry reforming over Ni supported on fibrous ZSM5 and ZY: Correlation of structural properties on H2 production

This study investigates fibrous ZSM5 (FZSM5) and Zeolite Y (FZY) as supports for producing hydrogen via glycerol dry reforming. The fibrous ZSM5 and ZY were synthesized hydrothermally with microemulsion and impregnated with 10 wt% Ni via a sonication method. The catalytic test was conducted via a ve...

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Main Authors: Nornasuha, Abdullah, Nurul Aini, Razali, Nor Shuhada Solehah, Hanafi, Herma Dina, Setiabudi, Chin, Sim Yee, Abdul Rahman, Mohamed, Aishah, Abdul Jalil
Format: Article
Language:English
English
Published: Elsevier Ltd 2024
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/42318/7/Glycerol%20dry%20reforming%20over%20Ni%20supported%20on%20fibrous%20ZSM5%20and%20ZY.pdf
http://umpir.ump.edu.my/id/eprint/42318/8/Glycerol%20dry%20reforming%20over%20Ni%20supported%20on%20fibrous%20ZSM5%20and%20ZY_ABST.pdf
http://umpir.ump.edu.my/id/eprint/42318/
https://doi.org/10.1016/j.cherd.2024.08.012
https://doi.org/10.1016/j.cherd.2024.08.012
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spelling my.ump.umpir.423182024-08-21T07:58:29Z http://umpir.ump.edu.my/id/eprint/42318/ Glycerol dry reforming over Ni supported on fibrous ZSM5 and ZY: Correlation of structural properties on H2 production Nornasuha, Abdullah Nurul Aini, Razali Nor Shuhada Solehah, Hanafi Herma Dina, Setiabudi Chin, Sim Yee Abdul Rahman, Mohamed Aishah, Abdul Jalil TP Chemical technology This study investigates fibrous ZSM5 (FZSM5) and Zeolite Y (FZY) as supports for producing hydrogen via glycerol dry reforming. The fibrous ZSM5 and ZY were synthesized hydrothermally with microemulsion and impregnated with 10 wt% Ni via a sonication method. The catalytic test was conducted via a vertical stainless steel fixed-bed rig, at 800°C with a glycerol/CO2 ratio of 1. XRD and N2 sorption revealed the reduced surface area and crystallinity in Ni/FZSM5 compared to Ni/FZY. Ni/FZY catalyst displayed a larger surface area (264 m2/g) and aperture width (6.70 nm) in comparison to Ni/FZSM5, which had a surface area of 238 m2/g and an aperture width of 3.90 nm. Ni/FZY also had a smaller NiO crystallite size (8.73 nm) than Ni/FZSM5 (9.79 nm), suggesting well-dispersed Ni species on the wrinkle fiber of FZY’s surface. Ni/FZY outperformed Ni/FZSM5 with 52.49% glycerol conversion, 44.87% H2 yield, 71.31% CO yield, and only 14.4% carbon formation, attributed to robust Ni-O-Si contact and larger pore diameter. The discovery highlights the catalytic efficiency of the Ni-loaded fibrous zeolite in GDR, offering versatility for application in energy storage and catalysis. Elsevier Ltd 2024-09 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/42318/7/Glycerol%20dry%20reforming%20over%20Ni%20supported%20on%20fibrous%20ZSM5%20and%20ZY.pdf pdf en http://umpir.ump.edu.my/id/eprint/42318/8/Glycerol%20dry%20reforming%20over%20Ni%20supported%20on%20fibrous%20ZSM5%20and%20ZY_ABST.pdf Nornasuha, Abdullah and Nurul Aini, Razali and Nor Shuhada Solehah, Hanafi and Herma Dina, Setiabudi and Chin, Sim Yee and Abdul Rahman, Mohamed and Aishah, Abdul Jalil (2024) Glycerol dry reforming over Ni supported on fibrous ZSM5 and ZY: Correlation of structural properties on H2 production. Chemical Engineering Research and Design, 209. pp. 358-366. ISSN 0263-8762. (Published) https://doi.org/10.1016/j.cherd.2024.08.012 https://doi.org/10.1016/j.cherd.2024.08.012
institution Universiti Malaysia Pahang Al-Sultan Abdullah
building UMPSA Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang Al-Sultan Abdullah
content_source UMPSA Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
English
topic TP Chemical technology
spellingShingle TP Chemical technology
Nornasuha, Abdullah
Nurul Aini, Razali
Nor Shuhada Solehah, Hanafi
Herma Dina, Setiabudi
Chin, Sim Yee
Abdul Rahman, Mohamed
Aishah, Abdul Jalil
Glycerol dry reforming over Ni supported on fibrous ZSM5 and ZY: Correlation of structural properties on H2 production
description This study investigates fibrous ZSM5 (FZSM5) and Zeolite Y (FZY) as supports for producing hydrogen via glycerol dry reforming. The fibrous ZSM5 and ZY were synthesized hydrothermally with microemulsion and impregnated with 10 wt% Ni via a sonication method. The catalytic test was conducted via a vertical stainless steel fixed-bed rig, at 800°C with a glycerol/CO2 ratio of 1. XRD and N2 sorption revealed the reduced surface area and crystallinity in Ni/FZSM5 compared to Ni/FZY. Ni/FZY catalyst displayed a larger surface area (264 m2/g) and aperture width (6.70 nm) in comparison to Ni/FZSM5, which had a surface area of 238 m2/g and an aperture width of 3.90 nm. Ni/FZY also had a smaller NiO crystallite size (8.73 nm) than Ni/FZSM5 (9.79 nm), suggesting well-dispersed Ni species on the wrinkle fiber of FZY’s surface. Ni/FZY outperformed Ni/FZSM5 with 52.49% glycerol conversion, 44.87% H2 yield, 71.31% CO yield, and only 14.4% carbon formation, attributed to robust Ni-O-Si contact and larger pore diameter. The discovery highlights the catalytic efficiency of the Ni-loaded fibrous zeolite in GDR, offering versatility for application in energy storage and catalysis.
format Article
author Nornasuha, Abdullah
Nurul Aini, Razali
Nor Shuhada Solehah, Hanafi
Herma Dina, Setiabudi
Chin, Sim Yee
Abdul Rahman, Mohamed
Aishah, Abdul Jalil
author_facet Nornasuha, Abdullah
Nurul Aini, Razali
Nor Shuhada Solehah, Hanafi
Herma Dina, Setiabudi
Chin, Sim Yee
Abdul Rahman, Mohamed
Aishah, Abdul Jalil
author_sort Nornasuha, Abdullah
title Glycerol dry reforming over Ni supported on fibrous ZSM5 and ZY: Correlation of structural properties on H2 production
title_short Glycerol dry reforming over Ni supported on fibrous ZSM5 and ZY: Correlation of structural properties on H2 production
title_full Glycerol dry reforming over Ni supported on fibrous ZSM5 and ZY: Correlation of structural properties on H2 production
title_fullStr Glycerol dry reforming over Ni supported on fibrous ZSM5 and ZY: Correlation of structural properties on H2 production
title_full_unstemmed Glycerol dry reforming over Ni supported on fibrous ZSM5 and ZY: Correlation of structural properties on H2 production
title_sort glycerol dry reforming over ni supported on fibrous zsm5 and zy: correlation of structural properties on h2 production
publisher Elsevier Ltd
publishDate 2024
url http://umpir.ump.edu.my/id/eprint/42318/7/Glycerol%20dry%20reforming%20over%20Ni%20supported%20on%20fibrous%20ZSM5%20and%20ZY.pdf
http://umpir.ump.edu.my/id/eprint/42318/8/Glycerol%20dry%20reforming%20over%20Ni%20supported%20on%20fibrous%20ZSM5%20and%20ZY_ABST.pdf
http://umpir.ump.edu.my/id/eprint/42318/
https://doi.org/10.1016/j.cherd.2024.08.012
https://doi.org/10.1016/j.cherd.2024.08.012
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score 13.235796

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