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Biosorption of anionic and cationic azo dye onto red macro alga : Determination of the significant variables using resolution V fractional factorial design

Naturally inspired biosorbent from macro algae species are favored because of its excellent biosorptive capability and low cost. The present investigation reports the potential of red macro-alga, E. spinosum as a biosorbent to remove both anionic and cationic azo dyes, namely Acid Yellow 17 (AY17) a...

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Main Authors: Nadiah, Mokhtar, Edriyana, Aziz, Azmi, Aris, Hafiza, Shukor, Syazwani, Mohd Zaki
Format: Article
Language:English
English
Published: Elsevier Ltd 2024
Subjects:
T Technology (General)
TA Engineering (General). Civil engineering (General)
Online Access:http://umpir.ump.edu.my/id/eprint/41399/1/Biosorption%20of%20anionic%20and%20cationic%20azo%20dye%20onto%20red%20macro%20alga.pdf
http://umpir.ump.edu.my/id/eprint/41399/2/Biosorption%20of%20anionic%20and%20cationic%20azo%20dye%20onto%20red%20macro%20alga_Determination%20of%20the%20significant%20variables%20using%20resolution%20V%20fractional%20factorial%20design_ABS.pdf
http://umpir.ump.edu.my/id/eprint/41399/
https://doi.org/10.1016/j.pce.2024.103593
https://doi.org/10.1016/j.pce.2024.103593
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spelling my.ump.umpir.413992024-07-01T01:26:11Z http://umpir.ump.edu.my/id/eprint/41399/ Biosorption of anionic and cationic azo dye onto red macro alga : Determination of the significant variables using resolution V fractional factorial design Nadiah, Mokhtar Edriyana, Aziz Azmi, Aris Hafiza, Shukor Syazwani, Mohd Zaki T Technology (General) TA Engineering (General). Civil engineering (General) Naturally inspired biosorbent from macro algae species are favored because of its excellent biosorptive capability and low cost. The present investigation reports the potential of red macro-alga, E. spinosum as a biosorbent to remove both anionic and cationic azo dyes, namely Acid Yellow 17 (AY17) and Methylene Blue (MB) from aqueous solution. A resolution V fractional factorial design (2v5-1) analysis was employed to study the main effects and interaction of variables on the biosorption process. Factorial matrix with five variables; pH (2–12), dosage (0.4–2 g/L), initial concentration (50–200 mg/L), contact time (5–120 min) and temperature (30-50 °C) at two levels were conducted in batch study. Pareto charts and ANOVA (within 95% confidence level) were applied to examine the relationship and significance between independent variables and their interactions. A regression model with R2AY17 = 0.9998 and R2MB = 0.9995 was implemented to fit the experimental data. The results obtained indicated that the most significant variables that affected biosorption process were initial concentration and the dosage of the dyes. Experimental screenings are crucial in optimization studies. The remarkable performance of E. spinosum as biosorbent to absorb both dyes shows a great potential to be implemented for local marine macro alga as an alternative. Resource for biosorption process. Elsevier Ltd 2024-06 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/41399/1/Biosorption%20of%20anionic%20and%20cationic%20azo%20dye%20onto%20red%20macro%20alga.pdf pdf en http://umpir.ump.edu.my/id/eprint/41399/2/Biosorption%20of%20anionic%20and%20cationic%20azo%20dye%20onto%20red%20macro%20alga_Determination%20of%20the%20significant%20variables%20using%20resolution%20V%20fractional%20factorial%20design_ABS.pdf Nadiah, Mokhtar and Edriyana, Aziz and Azmi, Aris and Hafiza, Shukor and Syazwani, Mohd Zaki (2024) Biosorption of anionic and cationic azo dye onto red macro alga : Determination of the significant variables using resolution V fractional factorial design. Physics and Chemistry of the Earth, 134 (103593). pp. 1-12. ISSN 1474-7065. (Published) https://doi.org/10.1016/j.pce.2024.103593 https://doi.org/10.1016/j.pce.2024.103593
institution Universiti Malaysia Pahang Al-Sultan Abdullah
building UMPSA Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang Al-Sultan Abdullah
content_source UMPSA Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
English
topic T Technology (General)
TA Engineering (General). Civil engineering (General)
spellingShingle T Technology (General)
TA Engineering (General). Civil engineering (General)
Nadiah, Mokhtar
Edriyana, Aziz
Azmi, Aris
Hafiza, Shukor
Syazwani, Mohd Zaki
Biosorption of anionic and cationic azo dye onto red macro alga : Determination of the significant variables using resolution V fractional factorial design
description Naturally inspired biosorbent from macro algae species are favored because of its excellent biosorptive capability and low cost. The present investigation reports the potential of red macro-alga, E. spinosum as a biosorbent to remove both anionic and cationic azo dyes, namely Acid Yellow 17 (AY17) and Methylene Blue (MB) from aqueous solution. A resolution V fractional factorial design (2v5-1) analysis was employed to study the main effects and interaction of variables on the biosorption process. Factorial matrix with five variables; pH (2–12), dosage (0.4–2 g/L), initial concentration (50–200 mg/L), contact time (5–120 min) and temperature (30-50 °C) at two levels were conducted in batch study. Pareto charts and ANOVA (within 95% confidence level) were applied to examine the relationship and significance between independent variables and their interactions. A regression model with R2AY17 = 0.9998 and R2MB = 0.9995 was implemented to fit the experimental data. The results obtained indicated that the most significant variables that affected biosorption process were initial concentration and the dosage of the dyes. Experimental screenings are crucial in optimization studies. The remarkable performance of E. spinosum as biosorbent to absorb both dyes shows a great potential to be implemented for local marine macro alga as an alternative. Resource for biosorption process.
format Article
author Nadiah, Mokhtar
Edriyana, Aziz
Azmi, Aris
Hafiza, Shukor
Syazwani, Mohd Zaki
author_facet Nadiah, Mokhtar
Edriyana, Aziz
Azmi, Aris
Hafiza, Shukor
Syazwani, Mohd Zaki
author_sort Nadiah, Mokhtar
title Biosorption of anionic and cationic azo dye onto red macro alga : Determination of the significant variables using resolution V fractional factorial design
title_short Biosorption of anionic and cationic azo dye onto red macro alga : Determination of the significant variables using resolution V fractional factorial design
title_full Biosorption of anionic and cationic azo dye onto red macro alga : Determination of the significant variables using resolution V fractional factorial design
title_fullStr Biosorption of anionic and cationic azo dye onto red macro alga : Determination of the significant variables using resolution V fractional factorial design
title_full_unstemmed Biosorption of anionic and cationic azo dye onto red macro alga : Determination of the significant variables using resolution V fractional factorial design
title_sort biosorption of anionic and cationic azo dye onto red macro alga : determination of the significant variables using resolution v fractional factorial design
publisher Elsevier Ltd
publishDate 2024
url http://umpir.ump.edu.my/id/eprint/41399/1/Biosorption%20of%20anionic%20and%20cationic%20azo%20dye%20onto%20red%20macro%20alga.pdf
http://umpir.ump.edu.my/id/eprint/41399/2/Biosorption%20of%20anionic%20and%20cationic%20azo%20dye%20onto%20red%20macro%20alga_Determination%20of%20the%20significant%20variables%20using%20resolution%20V%20fractional%20factorial%20design_ABS.pdf
http://umpir.ump.edu.my/id/eprint/41399/
https://doi.org/10.1016/j.pce.2024.103593
https://doi.org/10.1016/j.pce.2024.103593
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score 13.23648

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