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Multilayer hybrid solid-state electrolyte membrane for the high rate and long-life cycle performance of lithium-metal batteries

Hybrid solid-state electrolytes (HSEs) can be used to increase the electrochemical performance of lithium-metal batteries (LMBs), while also suppressing dendrite formation and preventing flammable behavior and electrolyte leakage, which are frequently present in conventional organic-liquid electroly...

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Main Authors: Nassir, Wollela Behja, Mengesha, Tadesu Hailu, Chang, Jengkuei, Jose, Rajan, Yang, Chunchen
Format: Article
Language:English
English
Published: Elsevier B.V. 2024
Subjects:
HD Industries. Land use. Labor
Q Science (General)
T Technology (General)
Online Access:http://umpir.ump.edu.my/id/eprint/41372/1/Multilayer%20hybrid%20solid-state%20electrolyte%20membrane%20for%20the%20high%20rate.pdf
http://umpir.ump.edu.my/id/eprint/41372/2/Multilayer%20hybrid%20solid-state%20electrolyte%20membrane%20for%20the%20high%20rate%20and%20long-life%20cycle%20performance%20of%20lithium-metal%20batteries_ABS.pdf
http://umpir.ump.edu.my/id/eprint/41372/
https://doi.org/10.1016/j.colsurfa.2024.133839
https://doi.org/10.1016/j.colsurfa.2024.133839
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spelling my.ump.umpir.413722024-07-01T01:13:20Z http://umpir.ump.edu.my/id/eprint/41372/ Multilayer hybrid solid-state electrolyte membrane for the high rate and long-life cycle performance of lithium-metal batteries Nassir, Wollela Behja Mengesha, Tadesu Hailu Chang, Jengkuei Jose, Rajan Yang, Chunchen HD Industries. Land use. Labor Q Science (General) T Technology (General) Hybrid solid-state electrolytes (HSEs) can be used to increase the electrochemical performance of lithium-metal batteries (LMBs), while also suppressing dendrite formation and preventing flammable behavior and electrolyte leakage, which are frequently present in conventional organic-liquid electrolytes. Notably, multilayer HSE membranes have received increasing emphasis since they can significantly ameliorate the interface contact toward electrodes and the mechanical strength. In this current work, we fabricated multilayer HSE membranes via a solution-casting technique that incorporated poly(vinylidene fluoride–co–hexafluoropropylene) (PVDF-HFP), polydopamine-modified Li6.28La3Zr2Al0.24O12 (PDA@LLZAO) filler, succinonitrile (SN) and lithium bis(trifluoromethane sulfonyl)imide (LiTFSI). The resulting HSE membrane exhibited a high ionic conductivity (2.49 ×10−4 S cm−1 at 30 ℃), transference number of 0.65, and excellent electrochemical window (4.80 V). The symmetrical cell featuring Li/HSE/Li was stable and cycled without short circuiting for 1000 h during the Li plating/stripping cycles. Furthermore, the coin-type cell assembled with LiFePO4/HSE/Li showed an initial discharge capacity of 134.7 mAh g–1 and exhibited superior retained capacity and average coulombic efficiency of 93.45% and 99.39%, respectively, after 687 cycles at 2 C and 30 ℃. Therefore, the as-prepared multilayer HSE is a promising SSE for next-generation LMBs. Elsevier B.V. 2024-06-20 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/41372/1/Multilayer%20hybrid%20solid-state%20electrolyte%20membrane%20for%20the%20high%20rate.pdf pdf en http://umpir.ump.edu.my/id/eprint/41372/2/Multilayer%20hybrid%20solid-state%20electrolyte%20membrane%20for%20the%20high%20rate%20and%20long-life%20cycle%20performance%20of%20lithium-metal%20batteries_ABS.pdf Nassir, Wollela Behja and Mengesha, Tadesu Hailu and Chang, Jengkuei and Jose, Rajan and Yang, Chunchen (2024) Multilayer hybrid solid-state electrolyte membrane for the high rate and long-life cycle performance of lithium-metal batteries. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 691 (133839). pp. 1-13. ISSN 0927-7757. (Published) https://doi.org/10.1016/j.colsurfa.2024.133839 https://doi.org/10.1016/j.colsurfa.2024.133839
institution Universiti Malaysia Pahang Al-Sultan Abdullah
building UMPSA Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang Al-Sultan Abdullah
content_source UMPSA Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
English
topic HD Industries. Land use. Labor
Q Science (General)
T Technology (General)
spellingShingle HD Industries. Land use. Labor
Q Science (General)
T Technology (General)
Nassir, Wollela Behja
Mengesha, Tadesu Hailu
Chang, Jengkuei
Jose, Rajan
Yang, Chunchen
Multilayer hybrid solid-state electrolyte membrane for the high rate and long-life cycle performance of lithium-metal batteries
description Hybrid solid-state electrolytes (HSEs) can be used to increase the electrochemical performance of lithium-metal batteries (LMBs), while also suppressing dendrite formation and preventing flammable behavior and electrolyte leakage, which are frequently present in conventional organic-liquid electrolytes. Notably, multilayer HSE membranes have received increasing emphasis since they can significantly ameliorate the interface contact toward electrodes and the mechanical strength. In this current work, we fabricated multilayer HSE membranes via a solution-casting technique that incorporated poly(vinylidene fluoride–co–hexafluoropropylene) (PVDF-HFP), polydopamine-modified Li6.28La3Zr2Al0.24O12 (PDA@LLZAO) filler, succinonitrile (SN) and lithium bis(trifluoromethane sulfonyl)imide (LiTFSI). The resulting HSE membrane exhibited a high ionic conductivity (2.49 ×10−4 S cm−1 at 30 ℃), transference number of 0.65, and excellent electrochemical window (4.80 V). The symmetrical cell featuring Li/HSE/Li was stable and cycled without short circuiting for 1000 h during the Li plating/stripping cycles. Furthermore, the coin-type cell assembled with LiFePO4/HSE/Li showed an initial discharge capacity of 134.7 mAh g–1 and exhibited superior retained capacity and average coulombic efficiency of 93.45% and 99.39%, respectively, after 687 cycles at 2 C and 30 ℃. Therefore, the as-prepared multilayer HSE is a promising SSE for next-generation LMBs.
format Article
author Nassir, Wollela Behja
Mengesha, Tadesu Hailu
Chang, Jengkuei
Jose, Rajan
Yang, Chunchen
author_facet Nassir, Wollela Behja
Mengesha, Tadesu Hailu
Chang, Jengkuei
Jose, Rajan
Yang, Chunchen
author_sort Nassir, Wollela Behja
title Multilayer hybrid solid-state electrolyte membrane for the high rate and long-life cycle performance of lithium-metal batteries
title_short Multilayer hybrid solid-state electrolyte membrane for the high rate and long-life cycle performance of lithium-metal batteries
title_full Multilayer hybrid solid-state electrolyte membrane for the high rate and long-life cycle performance of lithium-metal batteries
title_fullStr Multilayer hybrid solid-state electrolyte membrane for the high rate and long-life cycle performance of lithium-metal batteries
title_full_unstemmed Multilayer hybrid solid-state electrolyte membrane for the high rate and long-life cycle performance of lithium-metal batteries
title_sort multilayer hybrid solid-state electrolyte membrane for the high rate and long-life cycle performance of lithium-metal batteries
publisher Elsevier B.V.
publishDate 2024
url http://umpir.ump.edu.my/id/eprint/41372/1/Multilayer%20hybrid%20solid-state%20electrolyte%20membrane%20for%20the%20high%20rate.pdf
http://umpir.ump.edu.my/id/eprint/41372/2/Multilayer%20hybrid%20solid-state%20electrolyte%20membrane%20for%20the%20high%20rate%20and%20long-life%20cycle%20performance%20of%20lithium-metal%20batteries_ABS.pdf
http://umpir.ump.edu.my/id/eprint/41372/
https://doi.org/10.1016/j.colsurfa.2024.133839
https://doi.org/10.1016/j.colsurfa.2024.133839
_version_ 1822924427923292160
score 13.235362

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