Staff View: Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes

Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes

A solution casting technique was used to fabricate a bio-based polymer electrolytes (BBPEs) system in the form of a solid film that is composed of alginate as the host polymer network, glycolic acid (GA) as the charge carrier, and 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) ionic liquid (IL) as...

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Main Authors:	A. F., Fuzlin, N. F., Mazuki, Hasan, Md. Mahmudul, Nagao, Y., Ahmad Salihin, Samsudin
Format:	Article
Language:	English English
Published:	Elsevier Ltd 2024
Subjects:	Q Science (General) QD Chemistry TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/41368/1/Enhancement%20on%20H%2B%20carriers%20in%20conduction%20properties%20with%20addition%20of%201-butyl-3-Methylimidazolium.pdf http://umpir.ump.edu.my/id/eprint/41368/2/Enhancement%20on%20H%2B%20carriers%20in%20conduction%20properties%20with%20addition%20of%201-butyl-3-Methylimidazolium_ABST.pdf http://umpir.ump.edu.my/id/eprint/41368/ https://doi.org/10.1016/j.ijhydene.2024.02.154 https://doi.org/10.1016/j.ijhydene.2024.02.154
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spelling	my.ump.umpir.413682024-05-23T06:44:06Z http://umpir.ump.edu.my/id/eprint/41368/ Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes A. F., Fuzlin N. F., Mazuki Hasan, Md. Mahmudul Nagao, Y. Ahmad Salihin, Samsudin Q Science (General) QD Chemistry TP Chemical technology A solution casting technique was used to fabricate a bio-based polymer electrolytes (BBPEs) system in the form of a solid film that is composed of alginate as the host polymer network, glycolic acid (GA) as the charge carrier, and 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) ionic liquid (IL) as an additive. The peak changes in IR spectra revealed the complexation of adding ionic liquids with the enhancement of H+ carriers, while XRD and TGA studies revealed that adding IL suppressed the crystallinity and improved the thermal stability up to ∼100 °C. The free-standing BBPEs sample exhibited the highest ionic conductivity of 2.03 × 10−3 S cm−1 at 6 wt % [Bmim]Cl composition at ambient temperature and achieved an H+ transference number of 0.47. These results suggested that the addition of ILs as an additive into alginate-based BBPEs is a promising strategy for developing proton-conducting solid BBPEs for use in electrochemical devices. Elsevier Ltd 2024-03-22 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/41368/1/Enhancement%20on%20H%2B%20carriers%20in%20conduction%20properties%20with%20addition%20of%201-butyl-3-Methylimidazolium.pdf pdf en http://umpir.ump.edu.my/id/eprint/41368/2/Enhancement%20on%20H%2B%20carriers%20in%20conduction%20properties%20with%20addition%20of%201-butyl-3-Methylimidazolium_ABST.pdf A. F., Fuzlin and N. F., Mazuki and Hasan, Md. Mahmudul and Nagao, Y. and Ahmad Salihin, Samsudin (2024) Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes. International Journal of Hydrogen Energy, 60. 201 -211. ISSN 0360-3199. (Published) https://doi.org/10.1016/j.ijhydene.2024.02.154 https://doi.org/10.1016/j.ijhydene.2024.02.154
institution	Universiti Malaysia Pahang Al-Sultan Abdullah
building	UMPSA Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaysia Pahang Al-Sultan Abdullah
content_source	UMPSA Institutional Repository
url_provider	http://umpir.ump.edu.my/
language	English English
topic	Q Science (General) QD Chemistry TP Chemical technology
spellingShingle	Q Science (General) QD Chemistry TP Chemical technology A. F., Fuzlin N. F., Mazuki Hasan, Md. Mahmudul Nagao, Y. Ahmad Salihin, Samsudin Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes
description	A solution casting technique was used to fabricate a bio-based polymer electrolytes (BBPEs) system in the form of a solid film that is composed of alginate as the host polymer network, glycolic acid (GA) as the charge carrier, and 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) ionic liquid (IL) as an additive. The peak changes in IR spectra revealed the complexation of adding ionic liquids with the enhancement of H+ carriers, while XRD and TGA studies revealed that adding IL suppressed the crystallinity and improved the thermal stability up to ∼100 °C. The free-standing BBPEs sample exhibited the highest ionic conductivity of 2.03 × 10−3 S cm−1 at 6 wt % [Bmim]Cl composition at ambient temperature and achieved an H+ transference number of 0.47. These results suggested that the addition of ILs as an additive into alginate-based BBPEs is a promising strategy for developing proton-conducting solid BBPEs for use in electrochemical devices.
format	Article
author	A. F., Fuzlin N. F., Mazuki Hasan, Md. Mahmudul Nagao, Y. Ahmad Salihin, Samsudin
author_facet	A. F., Fuzlin N. F., Mazuki Hasan, Md. Mahmudul Nagao, Y. Ahmad Salihin, Samsudin
author_sort	A. F., Fuzlin
title	Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes
title_short	Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes
title_full	Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes
title_fullStr	Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes
title_full_unstemmed	Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes
title_sort	enhancement on h+ carriers in conduction properties with addition of 1-butyl-3-methylimidazolium chloride based alginate polymer electrolytes
publisher	Elsevier Ltd
publishDate	2024
url	http://umpir.ump.edu.my/id/eprint/41368/1/Enhancement%20on%20H%2B%20carriers%20in%20conduction%20properties%20with%20addition%20of%201-butyl-3-Methylimidazolium.pdf http://umpir.ump.edu.my/id/eprint/41368/2/Enhancement%20on%20H%2B%20carriers%20in%20conduction%20properties%20with%20addition%20of%201-butyl-3-Methylimidazolium_ABST.pdf http://umpir.ump.edu.my/id/eprint/41368/ https://doi.org/10.1016/j.ijhydene.2024.02.154 https://doi.org/10.1016/j.ijhydene.2024.02.154
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score	13.23648

Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes

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