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Properties and evaluation of functionalized mixed membrane adsorbents for the adsorption of vanillic acid from palm oil waste

Identifying factors that can improve the ability of mixed matrix membrane (MMM) adsorbents to isolate phenolic chemicals from palm oil waste is a major challenge. This study prepared a mixed matrix membrane with improved efficiency using a quaternary doping solution and a hydroxyapatite (HAp) filler...

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Main Authors: Zaharah, Abdul Rahman, Nora’aini, Ali, Sofiah, Hamzah, Syed Mohd Saufi, Tuan Chik, Norhafiza Ilyana, Yatim, Siti Solihah, Rasdei, Jan, Setiawan
Format: Article
Language:English
Published: Semarak Ilmu Publishing 2024
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/41123/1/Properties%20and%20Evaluation%20of%20Functionalized%20Mixed%20Membrane%20Adsorbents.pdf
http://umpir.ump.edu.my/id/eprint/41123/
https://doi.org/10.37934/araset.39.2.5371
https://doi.org/10.37934/araset.39.2.5371
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spelling my.ump.umpir.411232024-05-06T06:34:11Z http://umpir.ump.edu.my/id/eprint/41123/ Properties and evaluation of functionalized mixed membrane adsorbents for the adsorption of vanillic acid from palm oil waste Zaharah, Abdul Rahman Nora’aini, Ali Sofiah, Hamzah Syed Mohd Saufi, Tuan Chik Norhafiza Ilyana, Yatim Siti Solihah, Rasdei Jan, Setiawan TP Chemical technology Identifying factors that can improve the ability of mixed matrix membrane (MMM) adsorbents to isolate phenolic chemicals from palm oil waste is a major challenge. This study prepared a mixed matrix membrane with improved efficiency using a quaternary doping solution and a hydroxyapatite (HAp) filler and denoted as modified mixed matrix membrane (MMMHAp). Prior to use, HAp powder obtained from eggshells calcined at different temperatures was evaluated as an absorbent for the desired phenolic compounds. All the prepared HAp and MMMHAp powders were evaluated for their properties by Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM) and X-ray diffraction (XRD). For this study, vanillic acid was selected as a phenolic chemical because it is widely used in the pharmaceutical, biomedical and food industries. The optimal adsorption and vanillic acid isolation from crude palm oil samples by MMMHAp occurred using an acetate buffer solution with a pH of 8. The data from the equilibrium adsorption study were also in agreement with the Freundlich isotherm, as the R2 value was 0.9900 suggesting heterogeneous adsorption of vanillic acid on the surface of MMMHAp. The kinetic adsorption study clearly shows a pseudo-second-order fit (R2=0.9992), suggesting that chemisorption occurs between the adsorbed substance and the adsorbent. The modified membrane (MMMHAp) has characteristics of its finger-like structures is more elongated and connected to the porous layer, indicating that the incorporation of hydroxyapatite nanoparticles into the membrane enhances the adsorption of vanillic acid from real sample and has the highest adsorption capacity of 170.8 mg/g. These results show that this improved MMMHAp can be developed and used for waste utilization to obtain useful materials. Semarak Ilmu Publishing 2024-02-13 Article PeerReviewed pdf en cc_by_nc_4 http://umpir.ump.edu.my/id/eprint/41123/1/Properties%20and%20Evaluation%20of%20Functionalized%20Mixed%20Membrane%20Adsorbents.pdf Zaharah, Abdul Rahman and Nora’aini, Ali and Sofiah, Hamzah and Syed Mohd Saufi, Tuan Chik and Norhafiza Ilyana, Yatim and Siti Solihah, Rasdei and Jan, Setiawan (2024) Properties and evaluation of functionalized mixed membrane adsorbents for the adsorption of vanillic acid from palm oil waste. Journal of Advanced Research in Applied Sciences and Engineering Technology, 39 (2). pp. 53-71. ISSN 2462-1943. (Published) https://doi.org/10.37934/araset.39.2.5371 https://doi.org/10.37934/araset.39.2.5371
institution Universiti Malaysia Pahang Al-Sultan Abdullah
building UMPSA Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang Al-Sultan Abdullah
content_source UMPSA Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Zaharah, Abdul Rahman
Nora’aini, Ali
Sofiah, Hamzah
Syed Mohd Saufi, Tuan Chik
Norhafiza Ilyana, Yatim
Siti Solihah, Rasdei
Jan, Setiawan
Properties and evaluation of functionalized mixed membrane adsorbents for the adsorption of vanillic acid from palm oil waste
description Identifying factors that can improve the ability of mixed matrix membrane (MMM) adsorbents to isolate phenolic chemicals from palm oil waste is a major challenge. This study prepared a mixed matrix membrane with improved efficiency using a quaternary doping solution and a hydroxyapatite (HAp) filler and denoted as modified mixed matrix membrane (MMMHAp). Prior to use, HAp powder obtained from eggshells calcined at different temperatures was evaluated as an absorbent for the desired phenolic compounds. All the prepared HAp and MMMHAp powders were evaluated for their properties by Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM) and X-ray diffraction (XRD). For this study, vanillic acid was selected as a phenolic chemical because it is widely used in the pharmaceutical, biomedical and food industries. The optimal adsorption and vanillic acid isolation from crude palm oil samples by MMMHAp occurred using an acetate buffer solution with a pH of 8. The data from the equilibrium adsorption study were also in agreement with the Freundlich isotherm, as the R2 value was 0.9900 suggesting heterogeneous adsorption of vanillic acid on the surface of MMMHAp. The kinetic adsorption study clearly shows a pseudo-second-order fit (R2=0.9992), suggesting that chemisorption occurs between the adsorbed substance and the adsorbent. The modified membrane (MMMHAp) has characteristics of its finger-like structures is more elongated and connected to the porous layer, indicating that the incorporation of hydroxyapatite nanoparticles into the membrane enhances the adsorption of vanillic acid from real sample and has the highest adsorption capacity of 170.8 mg/g. These results show that this improved MMMHAp can be developed and used for waste utilization to obtain useful materials.
format Article
author Zaharah, Abdul Rahman
Nora’aini, Ali
Sofiah, Hamzah
Syed Mohd Saufi, Tuan Chik
Norhafiza Ilyana, Yatim
Siti Solihah, Rasdei
Jan, Setiawan
author_facet Zaharah, Abdul Rahman
Nora’aini, Ali
Sofiah, Hamzah
Syed Mohd Saufi, Tuan Chik
Norhafiza Ilyana, Yatim
Siti Solihah, Rasdei
Jan, Setiawan
author_sort Zaharah, Abdul Rahman
title Properties and evaluation of functionalized mixed membrane adsorbents for the adsorption of vanillic acid from palm oil waste
title_short Properties and evaluation of functionalized mixed membrane adsorbents for the adsorption of vanillic acid from palm oil waste
title_full Properties and evaluation of functionalized mixed membrane adsorbents for the adsorption of vanillic acid from palm oil waste
title_fullStr Properties and evaluation of functionalized mixed membrane adsorbents for the adsorption of vanillic acid from palm oil waste
title_full_unstemmed Properties and evaluation of functionalized mixed membrane adsorbents for the adsorption of vanillic acid from palm oil waste
title_sort properties and evaluation of functionalized mixed membrane adsorbents for the adsorption of vanillic acid from palm oil waste
publisher Semarak Ilmu Publishing
publishDate 2024
url http://umpir.ump.edu.my/id/eprint/41123/1/Properties%20and%20Evaluation%20of%20Functionalized%20Mixed%20Membrane%20Adsorbents.pdf
http://umpir.ump.edu.my/id/eprint/41123/
https://doi.org/10.37934/araset.39.2.5371
https://doi.org/10.37934/araset.39.2.5371
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score 13.23648

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