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Optimization of boron dispersion on fibrous-silica-nickel catalyst for enhanced CO2 hydrogenation to methane

There are numerous reports regarding boron-containing catalysts for hydrogen-related reactions from CO2 including dry reforming of methane and methanation. Besides enhancing the productivity, boron also improved nickel activity and stability. However, the detailed mechanistic study, particularly in...

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Main Authors: Nurul Sahida, Hassan, Aishah, Abdul Jalil, Nor Aiza, Abdul Fatah, Hussain, Ijaz, Rahman, A. F.A., Dolit, S. A.M., Kamarizan, Kidam, Rahimah, Jusoh, Muhammad Arif, Ab Aziz, Herma Dina, Setiabudi, Cheng, Chin Kui
Format: Article
Language:English
English
Published: Elsevier Ltd 2022
Subjects:
Q Science (General)
QA Mathematics
T Technology (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/40180/1/Optimization%20of%20boron%20dispersion%20on%20fibrous-silica-nickel%20catalyst.pdf
http://umpir.ump.edu.my/id/eprint/40180/2/Optimization%20of%20boron%20dispersion%20on%20%EF%AC%81brous-silica-nickel%20catalyst%20for%20enhanced%20CO2%20hydrogenation%20to%20methane_ABS.pdf
http://umpir.ump.edu.my/id/eprint/40180/
https://doi.org/10.1016/j.ijhydene.2022.02.126
https://doi.org/10.1016/j.ijhydene.2022.02.126
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spelling my.ump.umpir.401802024-02-08T00:52:53Z http://umpir.ump.edu.my/id/eprint/40180/ Optimization of boron dispersion on fibrous-silica-nickel catalyst for enhanced CO2 hydrogenation to methane Nurul Sahida, Hassan Aishah, Abdul Jalil Nor Aiza, Abdul Fatah Hussain, Ijaz Rahman, A. F.A. Dolit, S. A.M. Kamarizan, Kidam Rahimah, Jusoh Muhammad Arif, Ab Aziz Herma Dina, Setiabudi Cheng, Chin Kui Q Science (General) QA Mathematics T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology There are numerous reports regarding boron-containing catalysts for hydrogen-related reactions from CO2 including dry reforming of methane and methanation. Besides enhancing the productivity, boron also improved nickel activity and stability. However, the detailed mechanistic study, particularly in explaining the starring role of boron in the enhanced reactions, is still lacking. Thus, herein we loaded boron on fibrous-silica-nickel and investigated their physicochemical properties and mechanistic route by means of in-situ FTIR for enhanced CO2 methanation. It was found that the appropriate dispersion of boron surrounds the nickel particles is an important factor to improve the adsorption of CO2 before interacting with split hydrogen atom from the nickel sides to form intermediates which are subsequently dehydrated, and then serial hydrogenation gave the final product of methane. Boron also accelerated the methanation and restricted coke formation. A hybrid approach on optimization via a face-centered central composite design and a response surface methodology showed that reaction using H2/CO2 ratio of 6, GHSV of 10,500 mL g−1 h−1, at 500 °C gave the highest percentage of CH4 of 84.3%. To indicate the error, the predicted values were compared to the experimental values, yielding an accurately minimal error ranging from 0 to 11%. As a result, the empirical models generated for CO2 hydrogenation to methane were reasonably accurate, with all actual values for the confirmation runs fitting within the 94% prediction interval. Elsevier Ltd 2022-08-22 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/40180/1/Optimization%20of%20boron%20dispersion%20on%20fibrous-silica-nickel%20catalyst.pdf pdf en http://umpir.ump.edu.my/id/eprint/40180/2/Optimization%20of%20boron%20dispersion%20on%20%EF%AC%81brous-silica-nickel%20catalyst%20for%20enhanced%20CO2%20hydrogenation%20to%20methane_ABS.pdf Nurul Sahida, Hassan and Aishah, Abdul Jalil and Nor Aiza, Abdul Fatah and Hussain, Ijaz and Rahman, A. F.A. and Dolit, S. A.M. and Kamarizan, Kidam and Rahimah, Jusoh and Muhammad Arif, Ab Aziz and Herma Dina, Setiabudi and Cheng, Chin Kui (2022) Optimization of boron dispersion on fibrous-silica-nickel catalyst for enhanced CO2 hydrogenation to methane. International Journal of Hydrogen Energy, 47 (72). pp. 30896-30907. ISSN 0360-3199. (Published) https://doi.org/10.1016/j.ijhydene.2022.02.126 https://doi.org/10.1016/j.ijhydene.2022.02.126
institution Universiti Malaysia Pahang Al-Sultan Abdullah
building UMPSA Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang Al-Sultan Abdullah
content_source UMPSA Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
English
topic Q Science (General)
QA Mathematics
T Technology (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
spellingShingle Q Science (General)
QA Mathematics
T Technology (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
Nurul Sahida, Hassan
Aishah, Abdul Jalil
Nor Aiza, Abdul Fatah
Hussain, Ijaz
Rahman, A. F.A.
Dolit, S. A.M.
Kamarizan, Kidam
Rahimah, Jusoh
Muhammad Arif, Ab Aziz
Herma Dina, Setiabudi
Cheng, Chin Kui
Optimization of boron dispersion on fibrous-silica-nickel catalyst for enhanced CO2 hydrogenation to methane
description There are numerous reports regarding boron-containing catalysts for hydrogen-related reactions from CO2 including dry reforming of methane and methanation. Besides enhancing the productivity, boron also improved nickel activity and stability. However, the detailed mechanistic study, particularly in explaining the starring role of boron in the enhanced reactions, is still lacking. Thus, herein we loaded boron on fibrous-silica-nickel and investigated their physicochemical properties and mechanistic route by means of in-situ FTIR for enhanced CO2 methanation. It was found that the appropriate dispersion of boron surrounds the nickel particles is an important factor to improve the adsorption of CO2 before interacting with split hydrogen atom from the nickel sides to form intermediates which are subsequently dehydrated, and then serial hydrogenation gave the final product of methane. Boron also accelerated the methanation and restricted coke formation. A hybrid approach on optimization via a face-centered central composite design and a response surface methodology showed that reaction using H2/CO2 ratio of 6, GHSV of 10,500 mL g−1 h−1, at 500 °C gave the highest percentage of CH4 of 84.3%. To indicate the error, the predicted values were compared to the experimental values, yielding an accurately minimal error ranging from 0 to 11%. As a result, the empirical models generated for CO2 hydrogenation to methane were reasonably accurate, with all actual values for the confirmation runs fitting within the 94% prediction interval.
format Article
author Nurul Sahida, Hassan
Aishah, Abdul Jalil
Nor Aiza, Abdul Fatah
Hussain, Ijaz
Rahman, A. F.A.
Dolit, S. A.M.
Kamarizan, Kidam
Rahimah, Jusoh
Muhammad Arif, Ab Aziz
Herma Dina, Setiabudi
Cheng, Chin Kui
author_facet Nurul Sahida, Hassan
Aishah, Abdul Jalil
Nor Aiza, Abdul Fatah
Hussain, Ijaz
Rahman, A. F.A.
Dolit, S. A.M.
Kamarizan, Kidam
Rahimah, Jusoh
Muhammad Arif, Ab Aziz
Herma Dina, Setiabudi
Cheng, Chin Kui
author_sort Nurul Sahida, Hassan
title Optimization of boron dispersion on fibrous-silica-nickel catalyst for enhanced CO2 hydrogenation to methane
title_short Optimization of boron dispersion on fibrous-silica-nickel catalyst for enhanced CO2 hydrogenation to methane
title_full Optimization of boron dispersion on fibrous-silica-nickel catalyst for enhanced CO2 hydrogenation to methane
title_fullStr Optimization of boron dispersion on fibrous-silica-nickel catalyst for enhanced CO2 hydrogenation to methane
title_full_unstemmed Optimization of boron dispersion on fibrous-silica-nickel catalyst for enhanced CO2 hydrogenation to methane
title_sort optimization of boron dispersion on fibrous-silica-nickel catalyst for enhanced co2 hydrogenation to methane
publisher Elsevier Ltd
publishDate 2022
url http://umpir.ump.edu.my/id/eprint/40180/1/Optimization%20of%20boron%20dispersion%20on%20fibrous-silica-nickel%20catalyst.pdf
http://umpir.ump.edu.my/id/eprint/40180/2/Optimization%20of%20boron%20dispersion%20on%20%EF%AC%81brous-silica-nickel%20catalyst%20for%20enhanced%20CO2%20hydrogenation%20to%20methane_ABS.pdf
http://umpir.ump.edu.my/id/eprint/40180/
https://doi.org/10.1016/j.ijhydene.2022.02.126
https://doi.org/10.1016/j.ijhydene.2022.02.126
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score 13.235796

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