Staff View: Unveiling high-power and high-safety lithium-ion battery separator based on interlayer of ZIF-67/cellulose nanofiber with electrospun poly(vinyl alcohol)/melamine nonwoven membranes

Unveiling high-power and high-safety lithium-ion battery separator based on interlayer of ZIF-67/cellulose nanofiber with electrospun poly(vinyl alcohol)/melamine nonwoven membranes

Due to the poor thermal stability of conventional separators, lithium-ion batteries require a suitable separator to maintain system safety for long-term cycling performance. It must have high porosity, superior electrolyte uptake ability, and good ion-conducting properties even at high temperatures....

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Main Authors:	Wu, Xiaowei, Karuppiah, Chelladurai, Wu, Yi–Shiuan, Zhang, Borong, Hsu, Lifan, Shih, Jengywan, James Li, Ying Jeng, Hung, Tai-Feng, Ramaraj, Sayee Kannan, Jose, Rajan, Yang, Chun Chen
Format:	Article
Language:	English English
Published:	Elsevier Ltd 2024
Subjects:	HD28 Management. Industrial Management Q Science (General) T Technology (General)
Online Access:	http://umpir.ump.edu.my/id/eprint/40079/1/Unveiling%20high-power%20and%20high-safety%20lithium-ion%20battery%20separator%20based.pdf http://umpir.ump.edu.my/id/eprint/40079/2/Unveiling%20high-power%20and%20high-safety%20lithium-ion%20battery%20separator%20based%20on%20interlayer%20of%20ZIF-67_cellulose%20nanofiber%20with%20electrospun%20poly%28vinyl%20alcohol%29_ABS.pdf http://umpir.ump.edu.my/id/eprint/40079/ https://doi.org/10.1016/j.jcis.2023.12.098 https://doi.org/10.1016/j.jcis.2023.12.098
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spelling	my.ump.umpir.400792024-01-18T03:46:56Z http://umpir.ump.edu.my/id/eprint/40079/ Unveiling high-power and high-safety lithium-ion battery separator based on interlayer of ZIF-67/cellulose nanofiber with electrospun poly(vinyl alcohol)/melamine nonwoven membranes Wu, Xiaowei Karuppiah, Chelladurai Wu, Yi–Shiuan Zhang, Borong Hsu, Lifan Shih, Jengywan James Li, Ying Jeng Hung, Tai-Feng Ramaraj, Sayee Kannan Jose, Rajan Yang, Chun Chen HD28 Management. Industrial Management Q Science (General) T Technology (General) Due to the poor thermal stability of conventional separators, lithium-ion batteries require a suitable separator to maintain system safety for long-term cycling performance. It must have high porosity, superior electrolyte uptake ability, and good ion-conducting properties even at high temperatures. In this work, we demonstrate a novel composite membrane based on sandwiching of zeolitic imidazole frameworks-67 decorated cellulose acetate nanofibers (ZIF-67@CA) with electrospun poly(vinyl alcohol)/melamine (denoted as PVAM) nonwoven membranes. The as-prepared sandwich-type membranes are called PVAM/x%ZIF-67@CA/PVAM. The middle layer of composite membranes is primarily filled with different weight percentages of ZIF-67 nanoparticles (x = 5, 15, and 25 wt%), which both reduces the non-uniform porous structure of CA and increases its thermal stability. Therefore, our sandwich-type PVAM/x%ZIF-67@CA/PVAM membrane exhibits a higher thermal shrinkage effect at 200 °C than the commercial polyethylene (PE) separator. Due to its high electrolyte uptake (646.8%) and porosity (85.2%), PVAM/15%ZIF-67@CA/PVAM membrane achieved high ionic conductivity of 1.46 × 10-3 S cm−1 at 70 °C, as compared to the commercial PE separator (ca. 6.01 × 10-4 S cm−1 at 70 °C). Besides, the cell with PVAM/15%ZIF-67@CA/PVAM membrane shows an excellent discharge capacity of about 167.5 mAh g−1after 100 cycles at a 1C rate with a capacity retention of 90.3%. The ZIF-67 fillers in our sandwich-type composite membrane strongly attract anions (PF6-) through Lewis' acid-base interaction, allowing uniform Li+ ion transport and suppressing Li dendrites. As a result, we found that the PVAM/15%ZIF-67@CA/PVAM composite nonwoven membrane is applicable to high-power, high-safety lithium-ion battery systems that can be used in electric vehicles (EVs). Elsevier Ltd 2024-03-15 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/40079/1/Unveiling%20high-power%20and%20high-safety%20lithium-ion%20battery%20separator%20based.pdf pdf en http://umpir.ump.edu.my/id/eprint/40079/2/Unveiling%20high-power%20and%20high-safety%20lithium-ion%20battery%20separator%20based%20on%20interlayer%20of%20ZIF-67_cellulose%20nanofiber%20with%20electrospun%20poly%28vinyl%20alcohol%29_ABS.pdf Wu, Xiaowei and Karuppiah, Chelladurai and Wu, Yi–Shiuan and Zhang, Borong and Hsu, Lifan and Shih, Jengywan and James Li, Ying Jeng and Hung, Tai-Feng and Ramaraj, Sayee Kannan and Jose, Rajan and Yang, Chun Chen (2024) Unveiling high-power and high-safety lithium-ion battery separator based on interlayer of ZIF-67/cellulose nanofiber with electrospun poly(vinyl alcohol)/melamine nonwoven membranes. Journal of Colloid and Interface Science, 658. pp. 699-713. ISSN 0021-9797. (Published) https://doi.org/10.1016/j.jcis.2023.12.098 https://doi.org/10.1016/j.jcis.2023.12.098
institution	Universiti Malaysia Pahang Al-Sultan Abdullah
building	UMPSA Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaysia Pahang Al-Sultan Abdullah
content_source	UMPSA Institutional Repository
url_provider	http://umpir.ump.edu.my/
language	English English
topic	HD28 Management. Industrial Management Q Science (General) T Technology (General)
spellingShingle	HD28 Management. Industrial Management Q Science (General) T Technology (General) Wu, Xiaowei Karuppiah, Chelladurai Wu, Yi–Shiuan Zhang, Borong Hsu, Lifan Shih, Jengywan James Li, Ying Jeng Hung, Tai-Feng Ramaraj, Sayee Kannan Jose, Rajan Yang, Chun Chen Unveiling high-power and high-safety lithium-ion battery separator based on interlayer of ZIF-67/cellulose nanofiber with electrospun poly(vinyl alcohol)/melamine nonwoven membranes
description	Due to the poor thermal stability of conventional separators, lithium-ion batteries require a suitable separator to maintain system safety for long-term cycling performance. It must have high porosity, superior electrolyte uptake ability, and good ion-conducting properties even at high temperatures. In this work, we demonstrate a novel composite membrane based on sandwiching of zeolitic imidazole frameworks-67 decorated cellulose acetate nanofibers (ZIF-67@CA) with electrospun poly(vinyl alcohol)/melamine (denoted as PVAM) nonwoven membranes. The as-prepared sandwich-type membranes are called PVAM/x%ZIF-67@CA/PVAM. The middle layer of composite membranes is primarily filled with different weight percentages of ZIF-67 nanoparticles (x = 5, 15, and 25 wt%), which both reduces the non-uniform porous structure of CA and increases its thermal stability. Therefore, our sandwich-type PVAM/x%ZIF-67@CA/PVAM membrane exhibits a higher thermal shrinkage effect at 200 °C than the commercial polyethylene (PE) separator. Due to its high electrolyte uptake (646.8%) and porosity (85.2%), PVAM/15%ZIF-67@CA/PVAM membrane achieved high ionic conductivity of 1.46 × 10-3 S cm−1 at 70 °C, as compared to the commercial PE separator (ca. 6.01 × 10-4 S cm−1 at 70 °C). Besides, the cell with PVAM/15%ZIF-67@CA/PVAM membrane shows an excellent discharge capacity of about 167.5 mAh g−1after 100 cycles at a 1C rate with a capacity retention of 90.3%. The ZIF-67 fillers in our sandwich-type composite membrane strongly attract anions (PF6-) through Lewis' acid-base interaction, allowing uniform Li+ ion transport and suppressing Li dendrites. As a result, we found that the PVAM/15%ZIF-67@CA/PVAM composite nonwoven membrane is applicable to high-power, high-safety lithium-ion battery systems that can be used in electric vehicles (EVs).
format	Article
author	Wu, Xiaowei Karuppiah, Chelladurai Wu, Yi–Shiuan Zhang, Borong Hsu, Lifan Shih, Jengywan James Li, Ying Jeng Hung, Tai-Feng Ramaraj, Sayee Kannan Jose, Rajan Yang, Chun Chen
author_facet	Wu, Xiaowei Karuppiah, Chelladurai Wu, Yi–Shiuan Zhang, Borong Hsu, Lifan Shih, Jengywan James Li, Ying Jeng Hung, Tai-Feng Ramaraj, Sayee Kannan Jose, Rajan Yang, Chun Chen
author_sort	Wu, Xiaowei
title	Unveiling high-power and high-safety lithium-ion battery separator based on interlayer of ZIF-67/cellulose nanofiber with electrospun poly(vinyl alcohol)/melamine nonwoven membranes
title_short	Unveiling high-power and high-safety lithium-ion battery separator based on interlayer of ZIF-67/cellulose nanofiber with electrospun poly(vinyl alcohol)/melamine nonwoven membranes
title_full	Unveiling high-power and high-safety lithium-ion battery separator based on interlayer of ZIF-67/cellulose nanofiber with electrospun poly(vinyl alcohol)/melamine nonwoven membranes
title_fullStr	Unveiling high-power and high-safety lithium-ion battery separator based on interlayer of ZIF-67/cellulose nanofiber with electrospun poly(vinyl alcohol)/melamine nonwoven membranes
title_full_unstemmed	Unveiling high-power and high-safety lithium-ion battery separator based on interlayer of ZIF-67/cellulose nanofiber with electrospun poly(vinyl alcohol)/melamine nonwoven membranes
title_sort	unveiling high-power and high-safety lithium-ion battery separator based on interlayer of zif-67/cellulose nanofiber with electrospun poly(vinyl alcohol)/melamine nonwoven membranes
publisher	Elsevier Ltd
publishDate	2024
url	http://umpir.ump.edu.my/id/eprint/40079/1/Unveiling%20high-power%20and%20high-safety%20lithium-ion%20battery%20separator%20based.pdf http://umpir.ump.edu.my/id/eprint/40079/2/Unveiling%20high-power%20and%20high-safety%20lithium-ion%20battery%20separator%20based%20on%20interlayer%20of%20ZIF-67_cellulose%20nanofiber%20with%20electrospun%20poly%28vinyl%20alcohol%29_ABS.pdf http://umpir.ump.edu.my/id/eprint/40079/ https://doi.org/10.1016/j.jcis.2023.12.098 https://doi.org/10.1016/j.jcis.2023.12.098
_version_	1822924094957420544
score	13.235362

Unveiling high-power and high-safety lithium-ion battery separator based on interlayer of ZIF-67/cellulose nanofiber with electrospun poly(vinyl alcohol)/melamine nonwoven membranes

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