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Improved rate capability and long cycle life of metal-organic framework derived TiO2 @V2O5 composite as an efficient cathode for sodium-ion batteries

Vanadium oxide on carbon nanoporous structure (V2O5/C) as a potential cathode material for sodium-ion batteries (SIBs) offers significant specific capacities in energy storage systems but suffers from slow ionic diffusivity upon long cycling at higher current rates, thereby generally resulting in su...

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Main Authors: Mehek, Rimsha, Iqbal, Naseem, Javed, Omama, Noor, Tayyaba, Liu, Wei
Format: Article
Language:English
English
Published: Elsevier Ltd 2024
Subjects:
T Technology (General)
TA Engineering (General). Civil engineering (General)
TJ Mechanical engineering and machinery
TK Electrical engineering. Electronics Nuclear engineering
TS Manufactures
Online Access:http://umpir.ump.edu.my/id/eprint/40024/1/Improved%20rate%20capability%20and%20long%20cycle%20life%20of%20metal-organic%20framework.pdf
http://umpir.ump.edu.my/id/eprint/40024/2/Improved%20rate%20capability%20and%20long%20cycle%20life%20of%20metal-organic%20framework%20derived%20TiO2%20%40V2O5%20composite%20as%20an%20efficient%20cathode%20for%20sodium-ion%20batteries_ABS.pdf
http://umpir.ump.edu.my/id/eprint/40024/
https://doi.org/10.1016/j.est.2023.109921
https://doi.org/10.1016/j.est.2023.109921
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spelling my.ump.umpir.400242024-01-16T03:25:04Z http://umpir.ump.edu.my/id/eprint/40024/ Improved rate capability and long cycle life of metal-organic framework derived TiO2 @V2O5 composite as an efficient cathode for sodium-ion batteries Mehek, Rimsha Iqbal, Naseem Javed, Omama Noor, Tayyaba Liu, Wei T Technology (General) TA Engineering (General). Civil engineering (General) TJ Mechanical engineering and machinery TK Electrical engineering. Electronics Nuclear engineering TS Manufactures Vanadium oxide on carbon nanoporous structure (V2O5/C) as a potential cathode material for sodium-ion batteries (SIBs) offers significant specific capacities in energy storage systems but suffers from slow ionic diffusivity upon long cycling at higher current rates, thereby generally resulting in substandard electrochemical performance. This study suggests a facile strategy to enhance the electrochemical performance of V2O5/C as a cathode in sodium-ion batteries via titanium (Ti) doping using the pre-synthesized Ti-doped vanadium-based metal-organic framework template (V-MIL-101) as the precursor, which can be converted into a sophisticated core-shell type structure in which titania nanoparticle-based shell surrounds the vanadium oxide with a porous carbon-based octahedral core. Structural characterization reveals that Ti-doping forms a protective layer around vanadium based MIL-101 octahedrons that, upon pyrolysis, preserves the octahedral geometry and transforms into a nanoporous core-shell structure. It also greatly enhances the electrochemical performance as a cathode for SIBs. The titania-doped vanadium oxide structures represent higher specific capacities than the undoped vanadium oxide cathode, whereas among all the titania-doped samples, the 3 wt% TiO2@V2O5/C exhibited a much higher reversible capacity of 276.2 mAh/g as compared to the other cathode samples at 0.1C current rate and was able to retain a capacity of 250.1 mAh/g with a high coulombic efficiency after 200 cycles. Titanium species induce the formation of oxygen vacancies and V+5 species, which enhance the electrode's electric conductivity and ion diffusion—the stable octahedrons with a porous structure and carbon hybridisation in 3 wt% TiO2@V2O5/C could facilitate ion/electron transfer through shortened diffusion pathways. Elsevier Ltd 2024-02-01 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/40024/1/Improved%20rate%20capability%20and%20long%20cycle%20life%20of%20metal-organic%20framework.pdf pdf en http://umpir.ump.edu.my/id/eprint/40024/2/Improved%20rate%20capability%20and%20long%20cycle%20life%20of%20metal-organic%20framework%20derived%20TiO2%20%40V2O5%20composite%20as%20an%20efficient%20cathode%20for%20sodium-ion%20batteries_ABS.pdf Mehek, Rimsha and Iqbal, Naseem and Javed, Omama and Noor, Tayyaba and Liu, Wei (2024) Improved rate capability and long cycle life of metal-organic framework derived TiO2 @V2O5 composite as an efficient cathode for sodium-ion batteries. Journal of Energy Storage, 78 (109921). pp. 1-15. ISSN 2352-152X. (Published) https://doi.org/10.1016/j.est.2023.109921 https://doi.org/10.1016/j.est.2023.109921
institution Universiti Malaysia Pahang Al-Sultan Abdullah
building UMPSA Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang Al-Sultan Abdullah
content_source UMPSA Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
English
topic T Technology (General)
TA Engineering (General). Civil engineering (General)
TJ Mechanical engineering and machinery
TK Electrical engineering. Electronics Nuclear engineering
TS Manufactures
spellingShingle T Technology (General)
TA Engineering (General). Civil engineering (General)
TJ Mechanical engineering and machinery
TK Electrical engineering. Electronics Nuclear engineering
TS Manufactures
Mehek, Rimsha
Iqbal, Naseem
Javed, Omama
Noor, Tayyaba
Liu, Wei
Improved rate capability and long cycle life of metal-organic framework derived TiO2 @V2O5 composite as an efficient cathode for sodium-ion batteries
description Vanadium oxide on carbon nanoporous structure (V2O5/C) as a potential cathode material for sodium-ion batteries (SIBs) offers significant specific capacities in energy storage systems but suffers from slow ionic diffusivity upon long cycling at higher current rates, thereby generally resulting in substandard electrochemical performance. This study suggests a facile strategy to enhance the electrochemical performance of V2O5/C as a cathode in sodium-ion batteries via titanium (Ti) doping using the pre-synthesized Ti-doped vanadium-based metal-organic framework template (V-MIL-101) as the precursor, which can be converted into a sophisticated core-shell type structure in which titania nanoparticle-based shell surrounds the vanadium oxide with a porous carbon-based octahedral core. Structural characterization reveals that Ti-doping forms a protective layer around vanadium based MIL-101 octahedrons that, upon pyrolysis, preserves the octahedral geometry and transforms into a nanoporous core-shell structure. It also greatly enhances the electrochemical performance as a cathode for SIBs. The titania-doped vanadium oxide structures represent higher specific capacities than the undoped vanadium oxide cathode, whereas among all the titania-doped samples, the 3 wt% TiO2@V2O5/C exhibited a much higher reversible capacity of 276.2 mAh/g as compared to the other cathode samples at 0.1C current rate and was able to retain a capacity of 250.1 mAh/g with a high coulombic efficiency after 200 cycles. Titanium species induce the formation of oxygen vacancies and V+5 species, which enhance the electrode's electric conductivity and ion diffusion—the stable octahedrons with a porous structure and carbon hybridisation in 3 wt% TiO2@V2O5/C could facilitate ion/electron transfer through shortened diffusion pathways.
format Article
author Mehek, Rimsha
Iqbal, Naseem
Javed, Omama
Noor, Tayyaba
Liu, Wei
author_facet Mehek, Rimsha
Iqbal, Naseem
Javed, Omama
Noor, Tayyaba
Liu, Wei
author_sort Mehek, Rimsha
title Improved rate capability and long cycle life of metal-organic framework derived TiO2 @V2O5 composite as an efficient cathode for sodium-ion batteries
title_short Improved rate capability and long cycle life of metal-organic framework derived TiO2 @V2O5 composite as an efficient cathode for sodium-ion batteries
title_full Improved rate capability and long cycle life of metal-organic framework derived TiO2 @V2O5 composite as an efficient cathode for sodium-ion batteries
title_fullStr Improved rate capability and long cycle life of metal-organic framework derived TiO2 @V2O5 composite as an efficient cathode for sodium-ion batteries
title_full_unstemmed Improved rate capability and long cycle life of metal-organic framework derived TiO2 @V2O5 composite as an efficient cathode for sodium-ion batteries
title_sort improved rate capability and long cycle life of metal-organic framework derived tio2 @v2o5 composite as an efficient cathode for sodium-ion batteries
publisher Elsevier Ltd
publishDate 2024
url http://umpir.ump.edu.my/id/eprint/40024/1/Improved%20rate%20capability%20and%20long%20cycle%20life%20of%20metal-organic%20framework.pdf
http://umpir.ump.edu.my/id/eprint/40024/2/Improved%20rate%20capability%20and%20long%20cycle%20life%20of%20metal-organic%20framework%20derived%20TiO2%20%40V2O5%20composite%20as%20an%20efficient%20cathode%20for%20sodium-ion%20batteries_ABS.pdf
http://umpir.ump.edu.my/id/eprint/40024/
https://doi.org/10.1016/j.est.2023.109921
https://doi.org/10.1016/j.est.2023.109921
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score 13.244413

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