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Evaluation on electrochemical properties of lithium-ion battery–based PMMA-PLA blend incorporation of [EDIMP] TFSI hybrid gel polymer electrolyte

This study focuses on developing a novel hybrid gel polymer electrolyte (HGPE) for lithium-ion batteries. The HGPEs comprise a hybrid polymer of polymethyl methacrylate (PMMA) and polylactic acid (PLA), doped with 20 wt.% lithium bis (trifluoromethylsulfonyl) imide salt (LiTFSI) and incorporated wit...

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Main Authors: N. F., Mazuki, Kufian, Mohd Zieauddin, Ahmad Salihin, Samsudin
Format: Article
Language:English
English
English
Published: Springer Berlin Heidelberg 2024
Subjects:
Q Science (General)
QC Physics
QD Chemistry
Online Access:http://umpir.ump.edu.my/id/eprint/39767/1/10.1007/s11581-023-05253-y
http://umpir.ump.edu.my/id/eprint/39767/3/Evaluation%20on%20electrochemical%20properties%20of%20lithium-ion%20battery%E2%80%93based%20PMMA-PLA%20blend_FULL.pdf
http://umpir.ump.edu.my/id/eprint/39767/4/Evaluation%20on%20electrochemical%20properties%20of%20lithium-ion%20battery%E2%80%93based%20PMMA-PLA%20.pdf
http://umpir.ump.edu.my/id/eprint/39767/
https://doi.org/10.1007/s11581-023-05253-y
https://doi.org/10.1007/s11581-023-05253-y
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spelling my.ump.umpir.397672024-04-17T04:13:12Z http://umpir.ump.edu.my/id/eprint/39767/ Evaluation on electrochemical properties of lithium-ion battery–based PMMA-PLA blend incorporation of [EDIMP] TFSI hybrid gel polymer electrolyte N. F., Mazuki Kufian, Mohd Zieauddin Ahmad Salihin, Samsudin Q Science (General) QC Physics QD Chemistry This study focuses on developing a novel hybrid gel polymer electrolyte (HGPE) for lithium-ion batteries. The HGPEs comprise a hybrid polymer of polymethyl methacrylate (PMMA) and polylactic acid (PLA), doped with 20 wt.% lithium bis (trifluoromethylsulfonyl) imide salt (LiTFSI) and incorporated with various contents of ionic liquid, namely ethyl-dimethyl-propylammonium bis(trifluoromethylsulfonyl)imide ([EDIMP]TFSI) is successfully prepared, and the lithium-ion batteries performance was investigated. This work aims to investigate the influence of the ionic liquid on the electrical properties, cation transference number (tLi+), electrochemical stability window, and charge-discharge performance of the PMMA-PLA based HGPE systems. Among the different samples tested, the HGPE containing 20 wt.% [EDIMP]TFSI (E-TFSI 20) exhibited the most promising results. It achieved an optimum ionic conductivity of 3.90 × 10−3 S cm−1, an increased tLi+ from 0.63 to 0.79, and an extended electrochemical stability window from 4.3 to 5V. Temperature dependence studies revealed that all the HGPE systems followed the Arrhenius characteristic, and their activation energies were calculated. Dielectric studies revealed ionic behavior and suitable capacitance with varying frequencies of the HGPEs system. The most favorable electrolyte was selected based on the highest ionic conductivity observed in each HGPE systems. It was utilized in a Li metalǀHGPEsǀgraphite cell configuration. The discharge capacity of the cells using LiTFSI 20 and E-TFSI 20 electrolytes were measured as 152.06 mAh g−1 and 71.15 mAh g−1, respectively, at a current density of 3.72 A g−1. Springer Berlin Heidelberg 2024-01 Article PeerReviewed text en http://umpir.ump.edu.my/id/eprint/39767/1/10.1007/s11581-023-05253-y pdf en http://umpir.ump.edu.my/id/eprint/39767/3/Evaluation%20on%20electrochemical%20properties%20of%20lithium-ion%20battery%E2%80%93based%20PMMA-PLA%20blend_FULL.pdf pdf en http://umpir.ump.edu.my/id/eprint/39767/4/Evaluation%20on%20electrochemical%20properties%20of%20lithium-ion%20battery%E2%80%93based%20PMMA-PLA%20.pdf N. F., Mazuki and Kufian, Mohd Zieauddin and Ahmad Salihin, Samsudin (2024) Evaluation on electrochemical properties of lithium-ion battery–based PMMA-PLA blend incorporation of [EDIMP] TFSI hybrid gel polymer electrolyte. Ionics, 30 (1). 169 -182. ISSN 1862-0760. (Published) https://doi.org/10.1007/s11581-023-05253-y https://doi.org/10.1007/s11581-023-05253-y
institution Universiti Malaysia Pahang Al-Sultan Abdullah
building UMPSA Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang Al-Sultan Abdullah
content_source UMPSA Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
English
English
topic Q Science (General)
QC Physics
QD Chemistry
spellingShingle Q Science (General)
QC Physics
QD Chemistry
N. F., Mazuki
Kufian, Mohd Zieauddin
Ahmad Salihin, Samsudin
Evaluation on electrochemical properties of lithium-ion battery–based PMMA-PLA blend incorporation of [EDIMP] TFSI hybrid gel polymer electrolyte
description This study focuses on developing a novel hybrid gel polymer electrolyte (HGPE) for lithium-ion batteries. The HGPEs comprise a hybrid polymer of polymethyl methacrylate (PMMA) and polylactic acid (PLA), doped with 20 wt.% lithium bis (trifluoromethylsulfonyl) imide salt (LiTFSI) and incorporated with various contents of ionic liquid, namely ethyl-dimethyl-propylammonium bis(trifluoromethylsulfonyl)imide ([EDIMP]TFSI) is successfully prepared, and the lithium-ion batteries performance was investigated. This work aims to investigate the influence of the ionic liquid on the electrical properties, cation transference number (tLi+), electrochemical stability window, and charge-discharge performance of the PMMA-PLA based HGPE systems. Among the different samples tested, the HGPE containing 20 wt.% [EDIMP]TFSI (E-TFSI 20) exhibited the most promising results. It achieved an optimum ionic conductivity of 3.90 × 10−3 S cm−1, an increased tLi+ from 0.63 to 0.79, and an extended electrochemical stability window from 4.3 to 5V. Temperature dependence studies revealed that all the HGPE systems followed the Arrhenius characteristic, and their activation energies were calculated. Dielectric studies revealed ionic behavior and suitable capacitance with varying frequencies of the HGPEs system. The most favorable electrolyte was selected based on the highest ionic conductivity observed in each HGPE systems. It was utilized in a Li metalǀHGPEsǀgraphite cell configuration. The discharge capacity of the cells using LiTFSI 20 and E-TFSI 20 electrolytes were measured as 152.06 mAh g−1 and 71.15 mAh g−1, respectively, at a current density of 3.72 A g−1.
format Article
author N. F., Mazuki
Kufian, Mohd Zieauddin
Ahmad Salihin, Samsudin
author_facet N. F., Mazuki
Kufian, Mohd Zieauddin
Ahmad Salihin, Samsudin
author_sort N. F., Mazuki
title Evaluation on electrochemical properties of lithium-ion battery–based PMMA-PLA blend incorporation of [EDIMP] TFSI hybrid gel polymer electrolyte
title_short Evaluation on electrochemical properties of lithium-ion battery–based PMMA-PLA blend incorporation of [EDIMP] TFSI hybrid gel polymer electrolyte
title_full Evaluation on electrochemical properties of lithium-ion battery–based PMMA-PLA blend incorporation of [EDIMP] TFSI hybrid gel polymer electrolyte
title_fullStr Evaluation on electrochemical properties of lithium-ion battery–based PMMA-PLA blend incorporation of [EDIMP] TFSI hybrid gel polymer electrolyte
title_full_unstemmed Evaluation on electrochemical properties of lithium-ion battery–based PMMA-PLA blend incorporation of [EDIMP] TFSI hybrid gel polymer electrolyte
title_sort evaluation on electrochemical properties of lithium-ion battery–based pmma-pla blend incorporation of [edimp] tfsi hybrid gel polymer electrolyte
publisher Springer Berlin Heidelberg
publishDate 2024
url http://umpir.ump.edu.my/id/eprint/39767/1/10.1007/s11581-023-05253-y
http://umpir.ump.edu.my/id/eprint/39767/3/Evaluation%20on%20electrochemical%20properties%20of%20lithium-ion%20battery%E2%80%93based%20PMMA-PLA%20blend_FULL.pdf
http://umpir.ump.edu.my/id/eprint/39767/4/Evaluation%20on%20electrochemical%20properties%20of%20lithium-ion%20battery%E2%80%93based%20PMMA-PLA%20.pdf
http://umpir.ump.edu.my/id/eprint/39767/
https://doi.org/10.1007/s11581-023-05253-y
https://doi.org/10.1007/s11581-023-05253-y
_version_ 1822924218077020160
score 13.232414

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