Influencing of [EDIMP]TFSI in PMMA-PLA doped LiTFSI based hybrid gel polymer electrolyte on the variation in crystallinity phase and ionic conduction properties
In this study, we explored hybrid polymer complex-based gel polymer electrolytes (HGPEs) comprising poly (methyl methacrylate) (PMMA) and polylactic acid (PLA) as host polymers doped with LiTFSI, incorporating varying amounts of the ionic liquid ethyl-dimethyl-propylammonium bis(trifluoromethylsulfo...
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2023
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| Online Access: | http://umpir.ump.edu.my/id/eprint/39130/1/Influencing%20of%20%5BEDIMP%5DTFSI%20in%20PMMA-PLA%20doped%20LiTFSI%20based%20hybrid%20gel%20polymer%20electrolyte%20on%20the%20variation%20in%20crystallinity%20phase%20and%20ionic%20conduction%20properties.pdf http://umpir.ump.edu.my/id/eprint/39130/7/Influencing%20of%20%5BEDIMP%5D%20TFSI%20in%20PMMA-PLA%20doped%20LiTFSI.pdf http://umpir.ump.edu.my/id/eprint/39130/ https://doi.org/10.1016/j.jnoncrysol.2023.122634 |
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my.ump.umpir.391302023-11-01T06:51:02Z http://umpir.ump.edu.my/id/eprint/39130/ Influencing of [EDIMP]TFSI in PMMA-PLA doped LiTFSI based hybrid gel polymer electrolyte on the variation in crystallinity phase and ionic conduction properties Norfatihah, Mazuki Kufian, M. Z. Mohd Mawardi, Saari Ahmad Salihin, Samsudin Q Science (General) QC Physics QD Chemistry In this study, we explored hybrid polymer complex-based gel polymer electrolytes (HGPEs) comprising poly (methyl methacrylate) (PMMA) and polylactic acid (PLA) as host polymers doped with LiTFSI, incorporating varying amounts of the ionic liquid ethyl-dimethyl-propylammonium bis(trifluoromethylsulfonyl)imide ([EDIMP]TFSI). The structural properties of HGPEs has been assessed using FTIR, XRD, and DSC, observing changes in peak intensity, increased amorphous phases, and lowered glass transition temperatures (Tg) as [EDIMP]TFSI content increased. The room temperature ionic conductivity improved from 1.02 ×103 S cm1 to 3.90 ×103 S cm1 with [EDIMP]TFSI incorporation. The permittivity spectra were showed to follow the non- Debye characteristic. The Arof-Noor (A-N) method determined ionic mobility, charge carrier concentration, and diffusion coefficient to understand factors influencing ionic conductivity variation. The reduced interfacial resistance between HGPE and lithium metal enhanced contact with the electrode. Sample E-TFSI 20 reveals the tLi +and electrochemical potential window were respectively 0.79 ±0.005 and 5 ±0.5 V. Elsevier Ltd 2023-12-01 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/39130/1/Influencing%20of%20%5BEDIMP%5DTFSI%20in%20PMMA-PLA%20doped%20LiTFSI%20based%20hybrid%20gel%20polymer%20electrolyte%20on%20the%20variation%20in%20crystallinity%20phase%20and%20ionic%20conduction%20properties.pdf pdf en http://umpir.ump.edu.my/id/eprint/39130/7/Influencing%20of%20%5BEDIMP%5D%20TFSI%20in%20PMMA-PLA%20doped%20LiTFSI.pdf Norfatihah, Mazuki and Kufian, M. Z. and Mohd Mawardi, Saari and Ahmad Salihin, Samsudin (2023) Influencing of [EDIMP]TFSI in PMMA-PLA doped LiTFSI based hybrid gel polymer electrolyte on the variation in crystallinity phase and ionic conduction properties. Journal of Non-Crystalline Solids, 621. p. 122634. ISSN 0022-3093. (Published) https://doi.org/10.1016/j.jnoncrysol.2023.122634 10.1016/j.jnoncrysol.2023.122634 |
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Q Science (General) QC Physics QD Chemistry Norfatihah, Mazuki Kufian, M. Z. Mohd Mawardi, Saari Ahmad Salihin, Samsudin Influencing of [EDIMP]TFSI in PMMA-PLA doped LiTFSI based hybrid gel polymer electrolyte on the variation in crystallinity phase and ionic conduction properties |
| description |
In this study, we explored hybrid polymer complex-based gel polymer electrolytes (HGPEs) comprising poly (methyl methacrylate) (PMMA) and polylactic acid (PLA) as host polymers doped with LiTFSI, incorporating varying amounts of the ionic liquid ethyl-dimethyl-propylammonium bis(trifluoromethylsulfonyl)imide ([EDIMP]TFSI). The structural properties of HGPEs has been assessed using FTIR, XRD, and DSC, observing changes in peak intensity, increased amorphous phases, and lowered glass transition temperatures (Tg) as [EDIMP]TFSI content increased. The room temperature ionic conductivity improved from 1.02 ×103 S cm1 to 3.90 ×103 S cm1 with [EDIMP]TFSI incorporation. The permittivity spectra were showed to follow the non- Debye characteristic. The Arof-Noor (A-N) method determined ionic mobility, charge carrier concentration, and diffusion coefficient to understand factors influencing ionic conductivity variation. The reduced interfacial resistance between HGPE and lithium metal enhanced contact with the electrode. Sample E-TFSI 20 reveals the tLi +and electrochemical potential window were respectively 0.79 ±0.005 and 5 ±0.5 V. |
| format |
Article |
| author |
Norfatihah, Mazuki Kufian, M. Z. Mohd Mawardi, Saari Ahmad Salihin, Samsudin |
| author_facet |
Norfatihah, Mazuki Kufian, M. Z. Mohd Mawardi, Saari Ahmad Salihin, Samsudin |
| author_sort |
Norfatihah, Mazuki |
| title |
Influencing of [EDIMP]TFSI in PMMA-PLA doped LiTFSI based hybrid gel polymer electrolyte on the variation in crystallinity phase and ionic conduction properties |
| title_short |
Influencing of [EDIMP]TFSI in PMMA-PLA doped LiTFSI based hybrid gel polymer electrolyte on the variation in crystallinity phase and ionic conduction properties |
| title_full |
Influencing of [EDIMP]TFSI in PMMA-PLA doped LiTFSI based hybrid gel polymer electrolyte on the variation in crystallinity phase and ionic conduction properties |
| title_fullStr |
Influencing of [EDIMP]TFSI in PMMA-PLA doped LiTFSI based hybrid gel polymer electrolyte on the variation in crystallinity phase and ionic conduction properties |
| title_full_unstemmed |
Influencing of [EDIMP]TFSI in PMMA-PLA doped LiTFSI based hybrid gel polymer electrolyte on the variation in crystallinity phase and ionic conduction properties |
| title_sort |
influencing of [edimp]tfsi in pmma-pla doped litfsi based hybrid gel polymer electrolyte on the variation in crystallinity phase and ionic conduction properties |
| publisher |
Elsevier Ltd |
| publishDate |
2023 |
| url |
http://umpir.ump.edu.my/id/eprint/39130/1/Influencing%20of%20%5BEDIMP%5DTFSI%20in%20PMMA-PLA%20doped%20LiTFSI%20based%20hybrid%20gel%20polymer%20electrolyte%20on%20the%20variation%20in%20crystallinity%20phase%20and%20ionic%20conduction%20properties.pdf http://umpir.ump.edu.my/id/eprint/39130/7/Influencing%20of%20%5BEDIMP%5D%20TFSI%20in%20PMMA-PLA%20doped%20LiTFSI.pdf http://umpir.ump.edu.my/id/eprint/39130/ https://doi.org/10.1016/j.jnoncrysol.2023.122634 |
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13.232405 |