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Cobalt-based catalysts for hydrogen production by thermochemical valorization of glycerol: a review

Rising energy needs and the exhaustion of fossil fuels are calling for renewable fuels such as dihydrogen (H2), commonly named 'hydrogen.' Biomass treatment produces glycerol, which can be further used to generate dihydrogen or syngas. Here, actual challenges comprise the design of efficie...

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Main Authors: Mahadi B., Bahari, Che Rozid, Mamat, Aishah, Abdul Jalil, Siang, Tan Ji, Nurul Sahida, Hassan, Nur Farahain, Khusnun, Walid, Nabgan, Nurul Asmawati, Roslan, Sumaiya Zainal, Zainal Abidin, Herma Dina, Setiabudi, Vo, Dai Viet N.
Format: Article
Language:English
English
Published: Springer Science and Business Media Deutschland GmbH 2022
Subjects:
QD Chemistry
T Technology (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/39041/1/Cobalt-based%20catalysts%20for%20hydrogen%20production%20by%20thermochemical.pdf
http://umpir.ump.edu.my/id/eprint/39041/2/Cobalt-based%20catalysts%20for%20hydrogen%20production%20by%20thermochemical%20valorization%20of%20glycerol_%20A%20review_ABS.pdf
http://umpir.ump.edu.my/id/eprint/39041/
https://doi.org/10.1007/s10311-022-01423-y
https://doi.org/10.1007/s10311-022-01423-y
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spelling my.ump.umpir.390412023-11-14T03:10:58Z http://umpir.ump.edu.my/id/eprint/39041/ Cobalt-based catalysts for hydrogen production by thermochemical valorization of glycerol: a review Mahadi B., Bahari Che Rozid, Mamat Aishah, Abdul Jalil Siang, Tan Ji Nurul Sahida, Hassan Nur Farahain, Khusnun Walid, Nabgan Nurul Asmawati, Roslan Sumaiya Zainal, Zainal Abidin Herma Dina, Setiabudi Vo, Dai Viet N. QD Chemistry T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology Rising energy needs and the exhaustion of fossil fuels are calling for renewable fuels such as dihydrogen (H2), commonly named 'hydrogen.' Biomass treatment produces glycerol, which can be further used to generate dihydrogen or syngas. Here, actual challenges comprise the design of efficient and economically viable catalysts for attaining high hydrogen yield and minimizing coke deposition. Here, we review glycerol valorization routes for hydrogen or syngas generation, such as pyrolysis, steam reforming, aqueous phase, dry, supercritical water, partial oxidation, and autothermal reforming. We focus on cobalt-based catalysts due to their high availability, low cost, thermal stability, and coke resistance. The efficiency of cobalt-based catalysts can be improved by modifying textural properties, particle size and distribution, the strength of metal–support interaction, surface acidity and basicity, oxygen mobility, and reducibility. Such improvements have led to 100% glycerol conversion, 90% dihydrogen yield, and coke deposition of about 0.05%. Springer Science and Business Media Deutschland GmbH 2022-08 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/39041/1/Cobalt-based%20catalysts%20for%20hydrogen%20production%20by%20thermochemical.pdf pdf en http://umpir.ump.edu.my/id/eprint/39041/2/Cobalt-based%20catalysts%20for%20hydrogen%20production%20by%20thermochemical%20valorization%20of%20glycerol_%20A%20review_ABS.pdf Mahadi B., Bahari and Che Rozid, Mamat and Aishah, Abdul Jalil and Siang, Tan Ji and Nurul Sahida, Hassan and Nur Farahain, Khusnun and Walid, Nabgan and Nurul Asmawati, Roslan and Sumaiya Zainal, Zainal Abidin and Herma Dina, Setiabudi and Vo, Dai Viet N. (2022) Cobalt-based catalysts for hydrogen production by thermochemical valorization of glycerol: a review. Environmental Chemistry Letters, 20 (4). pp. 2361-2384. ISSN 1610-3653. (Published) https://doi.org/10.1007/s10311-022-01423-y https://doi.org/10.1007/s10311-022-01423-y
institution Universiti Malaysia Pahang Al-Sultan Abdullah
building UMPSA Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang Al-Sultan Abdullah
content_source UMPSA Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
English
topic QD Chemistry
T Technology (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
spellingShingle QD Chemistry
T Technology (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
Mahadi B., Bahari
Che Rozid, Mamat
Aishah, Abdul Jalil
Siang, Tan Ji
Nurul Sahida, Hassan
Nur Farahain, Khusnun
Walid, Nabgan
Nurul Asmawati, Roslan
Sumaiya Zainal, Zainal Abidin
Herma Dina, Setiabudi
Vo, Dai Viet N.
Cobalt-based catalysts for hydrogen production by thermochemical valorization of glycerol: a review
description Rising energy needs and the exhaustion of fossil fuels are calling for renewable fuels such as dihydrogen (H2), commonly named 'hydrogen.' Biomass treatment produces glycerol, which can be further used to generate dihydrogen or syngas. Here, actual challenges comprise the design of efficient and economically viable catalysts for attaining high hydrogen yield and minimizing coke deposition. Here, we review glycerol valorization routes for hydrogen or syngas generation, such as pyrolysis, steam reforming, aqueous phase, dry, supercritical water, partial oxidation, and autothermal reforming. We focus on cobalt-based catalysts due to their high availability, low cost, thermal stability, and coke resistance. The efficiency of cobalt-based catalysts can be improved by modifying textural properties, particle size and distribution, the strength of metal–support interaction, surface acidity and basicity, oxygen mobility, and reducibility. Such improvements have led to 100% glycerol conversion, 90% dihydrogen yield, and coke deposition of about 0.05%.
format Article
author Mahadi B., Bahari
Che Rozid, Mamat
Aishah, Abdul Jalil
Siang, Tan Ji
Nurul Sahida, Hassan
Nur Farahain, Khusnun
Walid, Nabgan
Nurul Asmawati, Roslan
Sumaiya Zainal, Zainal Abidin
Herma Dina, Setiabudi
Vo, Dai Viet N.
author_facet Mahadi B., Bahari
Che Rozid, Mamat
Aishah, Abdul Jalil
Siang, Tan Ji
Nurul Sahida, Hassan
Nur Farahain, Khusnun
Walid, Nabgan
Nurul Asmawati, Roslan
Sumaiya Zainal, Zainal Abidin
Herma Dina, Setiabudi
Vo, Dai Viet N.
author_sort Mahadi B., Bahari
title Cobalt-based catalysts for hydrogen production by thermochemical valorization of glycerol: a review
title_short Cobalt-based catalysts for hydrogen production by thermochemical valorization of glycerol: a review
title_full Cobalt-based catalysts for hydrogen production by thermochemical valorization of glycerol: a review
title_fullStr Cobalt-based catalysts for hydrogen production by thermochemical valorization of glycerol: a review
title_full_unstemmed Cobalt-based catalysts for hydrogen production by thermochemical valorization of glycerol: a review
title_sort cobalt-based catalysts for hydrogen production by thermochemical valorization of glycerol: a review
publisher Springer Science and Business Media Deutschland GmbH
publishDate 2022
url http://umpir.ump.edu.my/id/eprint/39041/1/Cobalt-based%20catalysts%20for%20hydrogen%20production%20by%20thermochemical.pdf
http://umpir.ump.edu.my/id/eprint/39041/2/Cobalt-based%20catalysts%20for%20hydrogen%20production%20by%20thermochemical%20valorization%20of%20glycerol_%20A%20review_ABS.pdf
http://umpir.ump.edu.my/id/eprint/39041/
https://doi.org/10.1007/s10311-022-01423-y
https://doi.org/10.1007/s10311-022-01423-y
_version_ 1822923814888013824
score 13.235796

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