Metal coordinated macrocyclic complexes in different chemical transformations

Macrocyclic ligand chemistry is seen by a growing number of scientists as a tool for designing new molecules with inherently selective properties. Metal coordinated macrocyclic rings are featured with exceptionally stable π-conjugated cyclic systems containing the metal ion in the central cavity. Th...

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Main Authors: Thakur, Maheshwar S., Singh, Neha, Sharma, Arti, Rana, Rohit, Abdul Syukor, Abd Razak, Naushad, Mu, Kumar, Sunil, Kumar, Manish Anil, Singh, Lakhveer
Format: Article
Language:English
English
Published: Coordination Chemistry Reviews 2022
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/39039/1/Metal%20coordinated%20macrocyclic%20complexes%20in%20different%20chemical%20transformations.pdf
http://umpir.ump.edu.my/id/eprint/39039/2/Metal%20coordinated%20macrocyclic%20complexes%20in%20different%20chemical%20transformations_ABS.pdf
http://umpir.ump.edu.my/id/eprint/39039/
https://doi.org/10.1016/j.ccr.2022.214739
https://doi.org/10.1016/j.ccr.2022.214739
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spelling my.ump.umpir.390392023-10-27T02:56:54Z http://umpir.ump.edu.my/id/eprint/39039/ Metal coordinated macrocyclic complexes in different chemical transformations Thakur, Maheshwar S. Singh, Neha Sharma, Arti Rana, Rohit Abdul Syukor, Abd Razak Naushad, Mu Kumar, Sunil Kumar, Manish Anil Singh, Lakhveer T Technology (General) TA Engineering (General). Civil engineering (General) TN Mining engineering. Metallurgy Macrocyclic ligand chemistry is seen by a growing number of scientists as a tool for designing new molecules with inherently selective properties. Metal coordinated macrocyclic rings are featured with exceptionally stable π-conjugated cyclic systems containing the metal ion in the central cavity. The cyclic tetra dentate framework of the four central nitrogen atoms makes these macrocyclic rings system unique chelating agents, in addition, these conjugated double bonds impart a vital effect in electrons transportation. Because of inimitable characteristics, these metal coordinated macrocyclic compounds have been effectively applied as catalysts in various important organic transformations. Hence, this review portrays the overview of metal coordinated macrocyclic molecules, classifications, and their catalytic application in redox reactions. This comprehensive and up-to-date review is particularly aligned toward the catalytic applications of four types of metal-coordinated macrocyclic rings, i.e., porphyrin, porphyrazine, corrole, and corrolazines, in different organic transformations. The different synthetic approaches for the preparation of metal coordinated macrocyclic rings and their UV spectrums are also outlined in this review. Coordination Chemistry Reviews 2022-11-15 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/39039/1/Metal%20coordinated%20macrocyclic%20complexes%20in%20different%20chemical%20transformations.pdf pdf en http://umpir.ump.edu.my/id/eprint/39039/2/Metal%20coordinated%20macrocyclic%20complexes%20in%20different%20chemical%20transformations_ABS.pdf Thakur, Maheshwar S. and Singh, Neha and Sharma, Arti and Rana, Rohit and Abdul Syukor, Abd Razak and Naushad, Mu and Kumar, Sunil and Kumar, Manish Anil and Singh, Lakhveer (2022) Metal coordinated macrocyclic complexes in different chemical transformations. Coordination Chemistry Reviews, 471 (214739). pp. 1-24. ISSN 0010-8545. (Published) https://doi.org/10.1016/j.ccr.2022.214739 https://doi.org/10.1016/j.ccr.2022.214739
institution Universiti Malaysia Pahang Al-Sultan Abdullah
building UMPSA Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang Al-Sultan Abdullah
content_source UMPSA Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
English
topic T Technology (General)
TA Engineering (General). Civil engineering (General)
TN Mining engineering. Metallurgy
spellingShingle T Technology (General)
TA Engineering (General). Civil engineering (General)
TN Mining engineering. Metallurgy
Thakur, Maheshwar S.
Singh, Neha
Sharma, Arti
Rana, Rohit
Abdul Syukor, Abd Razak
Naushad, Mu
Kumar, Sunil
Kumar, Manish Anil
Singh, Lakhveer
Metal coordinated macrocyclic complexes in different chemical transformations
description Macrocyclic ligand chemistry is seen by a growing number of scientists as a tool for designing new molecules with inherently selective properties. Metal coordinated macrocyclic rings are featured with exceptionally stable π-conjugated cyclic systems containing the metal ion in the central cavity. The cyclic tetra dentate framework of the four central nitrogen atoms makes these macrocyclic rings system unique chelating agents, in addition, these conjugated double bonds impart a vital effect in electrons transportation. Because of inimitable characteristics, these metal coordinated macrocyclic compounds have been effectively applied as catalysts in various important organic transformations. Hence, this review portrays the overview of metal coordinated macrocyclic molecules, classifications, and their catalytic application in redox reactions. This comprehensive and up-to-date review is particularly aligned toward the catalytic applications of four types of metal-coordinated macrocyclic rings, i.e., porphyrin, porphyrazine, corrole, and corrolazines, in different organic transformations. The different synthetic approaches for the preparation of metal coordinated macrocyclic rings and their UV spectrums are also outlined in this review.
format Article
author Thakur, Maheshwar S.
Singh, Neha
Sharma, Arti
Rana, Rohit
Abdul Syukor, Abd Razak
Naushad, Mu
Kumar, Sunil
Kumar, Manish Anil
Singh, Lakhveer
author_facet Thakur, Maheshwar S.
Singh, Neha
Sharma, Arti
Rana, Rohit
Abdul Syukor, Abd Razak
Naushad, Mu
Kumar, Sunil
Kumar, Manish Anil
Singh, Lakhveer
author_sort Thakur, Maheshwar S.
title Metal coordinated macrocyclic complexes in different chemical transformations
title_short Metal coordinated macrocyclic complexes in different chemical transformations
title_full Metal coordinated macrocyclic complexes in different chemical transformations
title_fullStr Metal coordinated macrocyclic complexes in different chemical transformations
title_full_unstemmed Metal coordinated macrocyclic complexes in different chemical transformations
title_sort metal coordinated macrocyclic complexes in different chemical transformations
publisher Coordination Chemistry Reviews
publishDate 2022
url http://umpir.ump.edu.my/id/eprint/39039/1/Metal%20coordinated%20macrocyclic%20complexes%20in%20different%20chemical%20transformations.pdf
http://umpir.ump.edu.my/id/eprint/39039/2/Metal%20coordinated%20macrocyclic%20complexes%20in%20different%20chemical%20transformations_ABS.pdf
http://umpir.ump.edu.my/id/eprint/39039/
https://doi.org/10.1016/j.ccr.2022.214739
https://doi.org/10.1016/j.ccr.2022.214739
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