Exploring the potential of seaweed derivatives for the development of biodegradable plastics: A comparative study

Biodegradable films made from biopolymer materials have the potential to replace conventional plastics, which can reduce waste disposal problems. This study aims to explore the potential of different seaweed derivate films consisting of 2% (w/w) of kappaphycus alverezi (KA), kappa carrageenan (KC),...

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Main Authors: Wan Amnin, Wan Yahaya, Nurul Aini, Mohd Azman, Fatmawati, Adam, Sarmilaah Dewi, Subramaniam, Khadijah Husna, Abd Hamid, Almajano, María Pilar
Format: Article
Language:English
Published: MDPI 2023
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Online Access:http://umpir.ump.edu.my/id/eprint/37929/1/Exploring%20the%20Potential%20of%20Seaweed%20Derivatives%20for%20the%20development.pdf
http://umpir.ump.edu.my/id/eprint/37929/
https://doi.org/10.3390/polym15132884
https://doi.org/10.3390/polym15132884
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spelling my.ump.umpir.379292023-07-05T01:32:03Z http://umpir.ump.edu.my/id/eprint/37929/ Exploring the potential of seaweed derivatives for the development of biodegradable plastics: A comparative study Wan Amnin, Wan Yahaya Nurul Aini, Mohd Azman Fatmawati, Adam Sarmilaah Dewi, Subramaniam Khadijah Husna, Abd Hamid Almajano, María Pilar TP Chemical technology Biodegradable films made from biopolymer materials have the potential to replace conventional plastics, which can reduce waste disposal problems. This study aims to explore the potential of different seaweed derivate films consisting of 2% (w/w) of kappaphycus alverezi (KA), kappa carrageenan (KC), refined carrageenan (RC) and semi-refined carrageenan (SRC) as bio-based materials with 0.9% (w/w) glycerol (G), and reinforced with different concentrations of cellulose nanofibers (CNFs) derived from palm waste. A characterization of the glycerol-plasticized seaweed derivatives containing 0, 5, 10, and 15% (v/w) cellulose nanofiber is carried out. The CNFs were studied based on their mechanical, physical and thermal properties including mechanical properties, thickness, moisture content, opacity, water solubility, water vapor permeability and thermal stability. The hydrogen bonding was determined using the DFT calculation generated by Gauss view software version 9.6. The KA + G + 10%CNF film exhibited a surface with slight cracks, roughness, and larger lumps and dents, resulting in inferior mechanical properties (18.50 Mpa), making it unsuitable for biofilm production. The KC + G + 10%CNF film exhibited mechanical properties 24.97 Mpa and water vapor permeability of 1.42311 × 10−11 g s−1 m−1 Pa−1. The RC/G/10%CNF film displayed the highest TS (48.23 MPa) and water vapor permeability (1.4168 × 10−11 g s−1 m−1 Pa−1), but it also had higher solubility in water (66%). In contrast, the SRC + G + 10%CNF film demonstrated excellent mechanical properties (45.98 MPa), low water solubility (42.59%), low water vapor permeability (1.3719 × 10−11 g s−1 m−1 Pa−1), and a high decomposition temperature (250.62 °C) compared to KA, KC and RC. These attributes develop films suitable for various applications, including food packaging with enhanced properties and stability. MDPI 2023-06 Article PeerReviewed pdf en cc_by_4 http://umpir.ump.edu.my/id/eprint/37929/1/Exploring%20the%20Potential%20of%20Seaweed%20Derivatives%20for%20the%20development.pdf Wan Amnin, Wan Yahaya and Nurul Aini, Mohd Azman and Fatmawati, Adam and Sarmilaah Dewi, Subramaniam and Khadijah Husna, Abd Hamid and Almajano, María Pilar (2023) Exploring the potential of seaweed derivatives for the development of biodegradable plastics: A comparative study. Polymers, 15 (13). pp. 1-18. ISSN 2073-4360 https://doi.org/10.3390/polym15132884 https://doi.org/10.3390/polym15132884
institution Universiti Malaysia Pahang
building UMP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang
content_source UMP Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Wan Amnin, Wan Yahaya
Nurul Aini, Mohd Azman
Fatmawati, Adam
Sarmilaah Dewi, Subramaniam
Khadijah Husna, Abd Hamid
Almajano, María Pilar
Exploring the potential of seaweed derivatives for the development of biodegradable plastics: A comparative study
description Biodegradable films made from biopolymer materials have the potential to replace conventional plastics, which can reduce waste disposal problems. This study aims to explore the potential of different seaweed derivate films consisting of 2% (w/w) of kappaphycus alverezi (KA), kappa carrageenan (KC), refined carrageenan (RC) and semi-refined carrageenan (SRC) as bio-based materials with 0.9% (w/w) glycerol (G), and reinforced with different concentrations of cellulose nanofibers (CNFs) derived from palm waste. A characterization of the glycerol-plasticized seaweed derivatives containing 0, 5, 10, and 15% (v/w) cellulose nanofiber is carried out. The CNFs were studied based on their mechanical, physical and thermal properties including mechanical properties, thickness, moisture content, opacity, water solubility, water vapor permeability and thermal stability. The hydrogen bonding was determined using the DFT calculation generated by Gauss view software version 9.6. The KA + G + 10%CNF film exhibited a surface with slight cracks, roughness, and larger lumps and dents, resulting in inferior mechanical properties (18.50 Mpa), making it unsuitable for biofilm production. The KC + G + 10%CNF film exhibited mechanical properties 24.97 Mpa and water vapor permeability of 1.42311 × 10−11 g s−1 m−1 Pa−1. The RC/G/10%CNF film displayed the highest TS (48.23 MPa) and water vapor permeability (1.4168 × 10−11 g s−1 m−1 Pa−1), but it also had higher solubility in water (66%). In contrast, the SRC + G + 10%CNF film demonstrated excellent mechanical properties (45.98 MPa), low water solubility (42.59%), low water vapor permeability (1.3719 × 10−11 g s−1 m−1 Pa−1), and a high decomposition temperature (250.62 °C) compared to KA, KC and RC. These attributes develop films suitable for various applications, including food packaging with enhanced properties and stability.
format Article
author Wan Amnin, Wan Yahaya
Nurul Aini, Mohd Azman
Fatmawati, Adam
Sarmilaah Dewi, Subramaniam
Khadijah Husna, Abd Hamid
Almajano, María Pilar
author_facet Wan Amnin, Wan Yahaya
Nurul Aini, Mohd Azman
Fatmawati, Adam
Sarmilaah Dewi, Subramaniam
Khadijah Husna, Abd Hamid
Almajano, María Pilar
author_sort Wan Amnin, Wan Yahaya
title Exploring the potential of seaweed derivatives for the development of biodegradable plastics: A comparative study
title_short Exploring the potential of seaweed derivatives for the development of biodegradable plastics: A comparative study
title_full Exploring the potential of seaweed derivatives for the development of biodegradable plastics: A comparative study
title_fullStr Exploring the potential of seaweed derivatives for the development of biodegradable plastics: A comparative study
title_full_unstemmed Exploring the potential of seaweed derivatives for the development of biodegradable plastics: A comparative study
title_sort exploring the potential of seaweed derivatives for the development of biodegradable plastics: a comparative study
publisher MDPI
publishDate 2023
url http://umpir.ump.edu.my/id/eprint/37929/1/Exploring%20the%20Potential%20of%20Seaweed%20Derivatives%20for%20the%20development.pdf
http://umpir.ump.edu.my/id/eprint/37929/
https://doi.org/10.3390/polym15132884
https://doi.org/10.3390/polym15132884
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score 13.211869