Parametric sensitivity analysis of the separation process for n-butanol production

n-butanol and iso-butanol are commonly produced by the hydrogenation of n-butyraldehyde and iso-butyraldehyde employing the patented copper catalyst accommodated in the reactors in series. The main cause of the lower n-butanol and iso-butanol yield was due to the catalyst blockage rendering a pressu...

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Main Authors: Z. J., Johan, T. Z., Tuan Muda, Chin, Sim Yee
Format: Conference or Workshop Item
Language:English
Published: IOP Publishing Ltd 2020
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/37380/1/Parametric%20sensitivity%20analysis%20of%20the%20separation%20process%20for%20N-butanol%20production.pdf
http://umpir.ump.edu.my/id/eprint/37380/
https://doi.org/10.1088/1757-899X/991/1/012120
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spelling my.ump.umpir.373802023-05-29T07:54:01Z http://umpir.ump.edu.my/id/eprint/37380/ Parametric sensitivity analysis of the separation process for n-butanol production Z. J., Johan T. Z., Tuan Muda Chin, Sim Yee QD Chemistry T Technology (General) TP Chemical technology n-butanol and iso-butanol are commonly produced by the hydrogenation of n-butyraldehyde and iso-butyraldehyde employing the patented copper catalyst accommodated in the reactors in series. The main cause of the lower n-butanol and iso-butanol yield was due to the catalyst blockage rendering a pressure build-up that could lead to a plant shut down. Bypassing the last reactor from the series could be a potential solution to continue running the plant until the next shutdown plan to replace catalyst. The study adopted simulation approach using Aspen Plus V10 to investigate the effect of bypassing the last reactor in the series to the product purity of the downstream separation processes. The iso-butanol and n-butanol with the desired purity were produced from the distillate and bottom product when the column was operated at the RR of 8.03 and DF of 0.328. The reaction conversion of R-102 was varied from 0.1-0.995 but the variation did not significantly change the composition of the main product. Hence, the present study affirmed that the bypassing of third reactor from the reactor train would not affect the product purity of the main product, n-butanol. IOP Publishing Ltd 2020-12-22 Conference or Workshop Item PeerReviewed pdf en cc_by http://umpir.ump.edu.my/id/eprint/37380/1/Parametric%20sensitivity%20analysis%20of%20the%20separation%20process%20for%20N-butanol%20production.pdf Z. J., Johan and T. Z., Tuan Muda and Chin, Sim Yee (2020) Parametric sensitivity analysis of the separation process for n-butanol production. In: IOP Conference Series: Materials Science and Engineering; 5th International Conference of Chemical Engineering and Industrial Biotechnology, ICCEIB 2020, 9 - 11 August 2020 , Kuala Lumpur. pp. 1-12., 991 (012120). ISSN 1757-8981 https://doi.org/10.1088/1757-899X/991/1/012120
institution Universiti Malaysia Pahang
building UMP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang
content_source UMP Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
topic QD Chemistry
T Technology (General)
TP Chemical technology
spellingShingle QD Chemistry
T Technology (General)
TP Chemical technology
Z. J., Johan
T. Z., Tuan Muda
Chin, Sim Yee
Parametric sensitivity analysis of the separation process for n-butanol production
description n-butanol and iso-butanol are commonly produced by the hydrogenation of n-butyraldehyde and iso-butyraldehyde employing the patented copper catalyst accommodated in the reactors in series. The main cause of the lower n-butanol and iso-butanol yield was due to the catalyst blockage rendering a pressure build-up that could lead to a plant shut down. Bypassing the last reactor from the series could be a potential solution to continue running the plant until the next shutdown plan to replace catalyst. The study adopted simulation approach using Aspen Plus V10 to investigate the effect of bypassing the last reactor in the series to the product purity of the downstream separation processes. The iso-butanol and n-butanol with the desired purity were produced from the distillate and bottom product when the column was operated at the RR of 8.03 and DF of 0.328. The reaction conversion of R-102 was varied from 0.1-0.995 but the variation did not significantly change the composition of the main product. Hence, the present study affirmed that the bypassing of third reactor from the reactor train would not affect the product purity of the main product, n-butanol.
format Conference or Workshop Item
author Z. J., Johan
T. Z., Tuan Muda
Chin, Sim Yee
author_facet Z. J., Johan
T. Z., Tuan Muda
Chin, Sim Yee
author_sort Z. J., Johan
title Parametric sensitivity analysis of the separation process for n-butanol production
title_short Parametric sensitivity analysis of the separation process for n-butanol production
title_full Parametric sensitivity analysis of the separation process for n-butanol production
title_fullStr Parametric sensitivity analysis of the separation process for n-butanol production
title_full_unstemmed Parametric sensitivity analysis of the separation process for n-butanol production
title_sort parametric sensitivity analysis of the separation process for n-butanol production
publisher IOP Publishing Ltd
publishDate 2020
url http://umpir.ump.edu.my/id/eprint/37380/1/Parametric%20sensitivity%20analysis%20of%20the%20separation%20process%20for%20N-butanol%20production.pdf
http://umpir.ump.edu.my/id/eprint/37380/
https://doi.org/10.1088/1757-899X/991/1/012120
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score 13.211869