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Investigating Thin-Film Composite Membranes Prepared by Interaction between Trimesoyl Chloride with M-Phenylenediamine and Piperazine on Nylon 66 and Performance in Isopropanol Dehydration

FESEM result shows that fabricated TFC membranes employed the dense layer as the active layer. The best water selectivity result from this study was shown by TFC-MPD5 which has ridge-and-valley structure that indicates the best and strong formation (33,150 N m−2) of a complete aromatic PA (in the ra...

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Main Authors: Wan Zulaisa Amira, Wan Jusoh, Sunarti, Abdul Rahman, Abdul Latif, Ahmad, Nadzirah, Mohd Mokhtar, Hasrinah, .Hasbullah
Format: Book Section
Language:English
Published: CRC Press 2022
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/37299/1/35.Investigating%20Thin%20Film%20Composite%20Membranes%20Prepared%20by%20Interaction%20between%20Trimesoyl%20Chloride%20with%20M%20Phenylenediamine.pdf
http://umpir.ump.edu.my/id/eprint/37299/
https://doi.org/10.1201/9781003167327
https://doi.org/10.1201/9781003167327
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spelling my.ump.umpir.372992023-03-27T07:56:34Z http://umpir.ump.edu.my/id/eprint/37299/ Investigating Thin-Film Composite Membranes Prepared by Interaction between Trimesoyl Chloride with M-Phenylenediamine and Piperazine on Nylon 66 and Performance in Isopropanol Dehydration Wan Zulaisa Amira, Wan Jusoh Sunarti, Abdul Rahman Abdul Latif, Ahmad Nadzirah, Mohd Mokhtar Hasrinah, .Hasbullah TP Chemical technology FESEM result shows that fabricated TFC membranes employed the dense layer as the active layer. The best water selectivity result from this study was shown by TFC-MPD5 which has ridge-and-valley structure that indicates the best and strong formation (33,150 N m−2) of a complete aromatic PA (in the range of 1,302–1,305 cm−1) on the N66 substrate which is promising for IPA-water separation. Increasing immersion time in amine solution will also increase the crosslinking rate to PA formation that contributed to the increase in thickness of final TFC membranes. In general, the membrane produced by TMC-MPD has better properties and performance than TMC-PIP. TFC membranes prepared by MPD show selectivity of 17.6 and 114.621 for preparing in 3 and 5 minutes in amine solutions, respectively. Meanwhile, TFC prepared by PIP amine solutions shows relatively lower selectivity of 17.6 and 108.5 for TFC-PIP3 and TFC-PIP5, respectively. CRC Press 2022 Book Section PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/37299/1/35.Investigating%20Thin%20Film%20Composite%20Membranes%20Prepared%20by%20Interaction%20between%20Trimesoyl%20Chloride%20with%20M%20Phenylenediamine.pdf Wan Zulaisa Amira, Wan Jusoh and Sunarti, Abdul Rahman and Abdul Latif, Ahmad and Nadzirah, Mohd Mokhtar and Hasrinah, .Hasbullah (2022) Investigating Thin-Film Composite Membranes Prepared by Interaction between Trimesoyl Chloride with M-Phenylenediamine and Piperazine on Nylon 66 and Performance in Isopropanol Dehydration. In: Advanced Materials for Wastewater Treatment and Desalination. CRC Press, Boca Raton, pp. 80-99. ISBN 9781003167327(Online) https://doi.org/10.1201/9781003167327 https://doi.org/10.1201/9781003167327
institution Universiti Malaysia Pahang
building UMP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang
content_source UMP Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Wan Zulaisa Amira, Wan Jusoh
Sunarti, Abdul Rahman
Abdul Latif, Ahmad
Nadzirah, Mohd Mokhtar
Hasrinah, .Hasbullah
Investigating Thin-Film Composite Membranes Prepared by Interaction between Trimesoyl Chloride with M-Phenylenediamine and Piperazine on Nylon 66 and Performance in Isopropanol Dehydration
description FESEM result shows that fabricated TFC membranes employed the dense layer as the active layer. The best water selectivity result from this study was shown by TFC-MPD5 which has ridge-and-valley structure that indicates the best and strong formation (33,150 N m−2) of a complete aromatic PA (in the range of 1,302–1,305 cm−1) on the N66 substrate which is promising for IPA-water separation. Increasing immersion time in amine solution will also increase the crosslinking rate to PA formation that contributed to the increase in thickness of final TFC membranes. In general, the membrane produced by TMC-MPD has better properties and performance than TMC-PIP. TFC membranes prepared by MPD show selectivity of 17.6 and 114.621 for preparing in 3 and 5 minutes in amine solutions, respectively. Meanwhile, TFC prepared by PIP amine solutions shows relatively lower selectivity of 17.6 and 108.5 for TFC-PIP3 and TFC-PIP5, respectively.
format Book Section
author Wan Zulaisa Amira, Wan Jusoh
Sunarti, Abdul Rahman
Abdul Latif, Ahmad
Nadzirah, Mohd Mokhtar
Hasrinah, .Hasbullah
author_facet Wan Zulaisa Amira, Wan Jusoh
Sunarti, Abdul Rahman
Abdul Latif, Ahmad
Nadzirah, Mohd Mokhtar
Hasrinah, .Hasbullah
author_sort Wan Zulaisa Amira, Wan Jusoh
title Investigating Thin-Film Composite Membranes Prepared by Interaction between Trimesoyl Chloride with M-Phenylenediamine and Piperazine on Nylon 66 and Performance in Isopropanol Dehydration
title_short Investigating Thin-Film Composite Membranes Prepared by Interaction between Trimesoyl Chloride with M-Phenylenediamine and Piperazine on Nylon 66 and Performance in Isopropanol Dehydration
title_full Investigating Thin-Film Composite Membranes Prepared by Interaction between Trimesoyl Chloride with M-Phenylenediamine and Piperazine on Nylon 66 and Performance in Isopropanol Dehydration
title_fullStr Investigating Thin-Film Composite Membranes Prepared by Interaction between Trimesoyl Chloride with M-Phenylenediamine and Piperazine on Nylon 66 and Performance in Isopropanol Dehydration
title_full_unstemmed Investigating Thin-Film Composite Membranes Prepared by Interaction between Trimesoyl Chloride with M-Phenylenediamine and Piperazine on Nylon 66 and Performance in Isopropanol Dehydration
title_sort investigating thin-film composite membranes prepared by interaction between trimesoyl chloride with m-phenylenediamine and piperazine on nylon 66 and performance in isopropanol dehydration
publisher CRC Press
publishDate 2022
url http://umpir.ump.edu.my/id/eprint/37299/1/35.Investigating%20Thin%20Film%20Composite%20Membranes%20Prepared%20by%20Interaction%20between%20Trimesoyl%20Chloride%20with%20M%20Phenylenediamine.pdf
http://umpir.ump.edu.my/id/eprint/37299/
https://doi.org/10.1201/9781003167327
https://doi.org/10.1201/9781003167327
_version_ 1761616639422365696
score 13.211869

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